Literature DB >> 25087720

Cu(II)-mediated ortho C-H alkynylation of (hetero)arenes with terminal alkynes.

Ming Shang1, Hong-Li Wang, Shang-Zheng Sun, Hui-Xiong Dai, Jin-Quan Yu.   

Abstract

Cu(II)-promoted ortho alkynylation of arenes and heteroarenes with terminal alkynes has been developed to prepare aryl alkynes. A variety of arenes and terminal alkynes bearing different substituents are compatible with this reaction, thus providing an alternative disconnection to Sonogashira coupling.

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Year:  2014        PMID： 25087720     DOI： 10.1021/ja507704b

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

Review 1.  Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations.

Authors:  Rachel Trammell; Khashayar Rajabimoghadam; Isaac Garcia-Bosch
Journal:  Chem Rev       Date:  2019-01-30       Impact factor: 60.622

2.  Ligand-Enabled Alkynylation of C(sp3 )-H Bonds with Palladium(II) Catalysts.

Authors:  Haiyan Fu; Peng-Xiang Shen; Jian He; Fanglin Zhang; Suhua Li; Peng Wang; Tao Liu; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2017-01-12       Impact factor: 15.336

3.  Ligand-Promoted meta-C-H Amination and Alkynylation.

Authors:  Peng Wang; Gen-Cheng Li; Pankaj Jain; Marcus E Farmer; Jian He; Peng-Xiang Shen; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2016-10-13       Impact factor: 15.419

4.  Recent Advances in the C-H-Functionalization of the Distal Positions in Pyridines and Quinolines.

Authors:  David E Stephens; Oleg V Larionov
Journal:  Tetrahedron       Date:  2015-08-19       Impact factor: 2.457

5.  Asymmetric C-H functionalization of cyclopropanes using an isoleucine-NH2 bidentate directing group.

Authors:  Jinhee Kim; Mikyung Sim; Namhoon Kim; Sungwoo Hong
Journal:  Chem Sci       Date:  2015-04-16       Impact factor: 9.825

6.  Multimetallic catalysed radical oxidative C(sp(3))-H/C(sp)-H cross-coupling between unactivated alkanes and terminal alkynes.

Authors:  Shan Tang; Pan Wang; Haoran Li; Aiwen Lei
Journal:  Nat Commun       Date:  2016-06-24       Impact factor: 14.919

7.  The facile construction of the phthalazin-1(2H)-one scaffold via copper-mediated C-H(sp(2))/C-H(sp) coupling under mild conditions.

Authors:  Wei Zhu; Bao Wang; Shengbin Zhou; Hong Liu
Journal:  Beilstein J Org Chem       Date:  2015-09-14       Impact factor: 2.883

Review 8.  Collective Approach to Advancing C-H Functionalization.

Authors:  Huw M L Davies; Daniel Morton
Journal:  ACS Cent Sci       Date:  2017-09-11       Impact factor: 14.553

9.  Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction.

Authors:  Soham Maity; Pravas Dolui; Rajesh Kancherla; Debabrata Maiti
Journal:  Chem Sci       Date:  2017-05-16       Impact factor: 9.825

10.  Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination.

Authors:  Ming Shang; Qian Shao; Shang-Zheng Sun; Yan-Qiao Chen; Hui Xu; Hui-Xiong Dai; Jin-Quan Yu
Journal:  Chem Sci       Date:  2016-09-26       Impact factor: 9.825
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