Literature DB >> 25084486

Enantioselective carbonyl-ene reactions catalyzed by chiral cationic dirhodium(II,III) carboxamidates.

Xichen Xu1, Xiaochen Wang, Yuxiao Liu, Michael P Doyle.   

Abstract

An enantioselective carbonyl-ene reaction of glyoxylate esters with 1,1-disubstituted alkenes catalyzed by chiral cationic dirhodium(II,III) carboxamidates is described. The paddlewheel dirhodium(II,III) carboxamidates having one open coordination site at each rhodium smoothly catalyze the carbonyl-ene reaction to afford homoallylic alcohol products in good isolated yields with high enantioselectivities.

Entities:  

Year:  2014        PMID： 25084486     DOI： 10.1021/jo5013674

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  2 in total

1.  Cooperative Hydrogen-Bond-Donor Catalysis with Hydrogen Chloride Enables Highly Enantioselective Prins Cyclization Reactions.

Authors:  Dennis A Kutateladze; Eric N Jacobsen
Journal:  J Am Chem Soc       Date:  2021-11-23       Impact factor: 15.419

2.  F10BINOL-derived chiral phosphoric acid-catalyzed enantioselective carbonyl-ene reaction: theoretical elucidation of stereochemical outcomes.

Authors:  Jun Kikuchi; Hiromu Aramaki; Hiroshi Okamoto; Masahiro Terada
Journal:  Chem Sci       Date:  2018-11-19       Impact factor: 9.825
  2 in total

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