Literature DB >> 25082894

Deprotonation of coordinated ethylene may start Phillips catalysis.

Klaus H Theopold1.   

Abstract

Entities:  

Year:  2014        PMID： 25082894      PMCID： PMC4136573          DOI： 10.1073/pnas.1411822111

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN： 0027-8424            Impact factor:   11.205


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  5 in total

1.  Homogeneous and heterogeneous catalysis: bridging the gap through surface organometallic chemistry.

Authors:  Christophe Copéret; Mathieu Chabanas; Romain Petroff Saint-Arroman; Jean-Marie Basset
Journal:  Angew Chem Int Ed Engl       Date:  2003-01-13       Impact factor: 15.336

Review 2.  The structure of active centers and the ethylene polymerization mechanism on the Cr/SiO2 catalyst: a frontier for the characterization methods.

Authors:  E Groppo; C Lamberti; S Bordiga; G Spoto; A Zecchina
Journal:  Chem Rev       Date:  2005-01       Impact factor: 60.622

3.  Polymerization of ethylene by silica-supported dinuclear Cr(III) sites through an initiation step involving C-H bond activation.

Authors:  Matthew P Conley; Murielle F Delley; Georges Siddiqi; Giuseppe Lapadula; Sébastien Norsic; Vincent Monteil; Olga V Safonova; Christophe Copéret
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-21       Impact factor: 15.336

4.  A chromium catalyst for the polymerization of ethylene as a homogeneous model for the phillips catalyst.

Authors:  Leonard A MacAdams; Gerald P Buffone; Christopher D Incarvito; Arnold L Rheingold; Klaus H Theopold
Journal:  J Am Chem Soc       Date:  2005-02-02       Impact factor: 15.419

5.  Proton transfers are key elementary steps in ethylene polymerization on isolated chromium(III) silicates.

Authors:  Murielle F Delley; Francisco Núñez-Zarur; Matthew P Conley; Aleix Comas-Vives; Georges Siddiqi; Sébastien Norsic; Vincent Monteil; Olga V Safonova; Christophe Copéret
Journal:  Proc Natl Acad Sci U S A       Date:  2014-07-07       Impact factor: 11.205
  5 in total

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