Literature DB >> 25076461

Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1'-bi-2-naphthol.

Shigang Wan1, Li-Rong Lin, Lili Zeng, Yiji Lin, Hui Zhang.   

Abstract

In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe4L6](4-) was successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by (R)-/(S)-1,1'-bi-2-naphthol. The enantiomeric excess of the resolved Fe(II) cage was 99%.

Entities:  

Year:  2014        PMID: 25076461     DOI: 10.1039/c4cc04145c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Solvent Drives Switching between Λ and Δ Metal Center Stereochemistry of M8L6 Cubic Cages.

Authors:  Weichao Xue; Tanya K Ronson; Zifei Lu; Jonathan R Nitschke
Journal:  J Am Chem Soc       Date:  2022-04-01       Impact factor: 16.383

2.  Discrimination of supramolecular chirality using a protein nanopore.

Authors:  James A Cooper; Stefan Borsley; Paul J Lusby; Scott L Cockroft
Journal:  Chem Sci       Date:  2017-05-11       Impact factor: 9.825

  2 in total

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