Literature DB >> 25069061

Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer.

Frederick Schwab1, Natascha Weidler, Martin Lucas, Peter Claus.   

Abstract

A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst and supported colloidal-based Pd as well.

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Year:  2014        PMID： 25069061     DOI： 10.1039/c4cc04183f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  The conversion of α-pinene to cis-pinane using a nickel catalyst supported on a discarded fluid catalytic cracking catalyst with an ionic liquid layer.

Authors:  Shunyou Hu; Linlin Wang; Xiaopeng Chen; Xiaojie Wei; Zhangfa Tong; Lijiang Yin
Journal:  RSC Adv       Date:  2019-02-18       Impact factor: 3.361

2.  On-Surface Metathesis of an Ionic Liquid on Ag(111).

Authors:  Stephen Massicot; Tomoya Sasaki; Matthias Lexow; Florian Maier; Susumu Kuwabata; Hans-Peter Steinrück
Journal:  Chemistry       Date:  2022-04-05       Impact factor: 5.020

3.  Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids.

Authors:  Ilka Simon; Julius Hornung; Juri Barthel; Jörg Thomas; Maik Finze; Roland A Fischer; Christoph Janiak
Journal:  Beilstein J Nanotechnol       Date:  2019-08-21       Impact factor: 3.649
  3 in total

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