Literature DB >> 25068174

Ni-catalyzed carboxylation of unactivated primary alkyl bromides and sulfonates with CO2.

Yu Liu1, Josep Cornella, Ruben Martin.   

Abstract

A Ni-catalyzed carboxylation of unactivated primary alkyl bromides and sulfonates with CO2 at atmospheric pressure is described. The method is characterized by its mild conditions and remarkably wide scope without the need for air- or moisture-sensitive reagents, which make it a user-friendly and operationally simple protocol en route to carboxylic acids.

Entities:  

Year:  2014        PMID： 25068174     DOI： 10.1021/ja5064586

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  18 in total

1.  Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide.

Authors:  Francisco Juliá-Hernández; Toni Moragas; Josep Cornella; Ruben Martin
Journal:  Nature       Date:  2017-05-03       Impact factor: 49.962

2.  Synthesis of Tetrasubstituted Alkenes by Tandem Metallacycle Formation/Cross-Electrophile Coupling.

Authors:  Kirk W Shimkin; John Montgomery
Journal:  J Am Chem Soc       Date:  2018-05-31       Impact factor: 15.419

3.  Cobalt-Catalyzed Silylcarbonylation of Unactivated Secondary Alkyl Tosylates at Low Pressure.

Authors:  Joan E Roque Peña; Erik J Alexanian
Journal:  Org Lett       Date:  2017-08-11       Impact factor: 6.005

4.  Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp2 )-C(sp3 )Coupling Reactions.

Authors:  Megan Mohadjer Beromi; Gary W Brudvig; Nilay Hazari; Hannah M C Lant; Brandon Q Mercado
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-27       Impact factor: 15.336

5.  Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies.

Authors:  David J Charboneau; Gary W Brudvig; Nilay Hazari; Hannah M C Lant; Andrew K Saydjari
Journal:  ACS Catal       Date:  2019-03-14       Impact factor: 13.084

6.  Direct Carbon Isotope Exchange through Decarboxylative Carboxylation.

Authors:  Cian Kingston; Michael A Wallace; Alban J Allentoff; Justine N deGruyter; Jason S Chen; Sharon X Gong; Samuel Bonacorsi; Phil S Baran
Journal:  J Am Chem Soc       Date:  2019-01-03       Impact factor: 15.419

7.  Palladium-Catalyzed Alkoxycarbonylation of Unactivated Secondary Alkyl Bromides at Low Pressure.

Authors:  Brendon T Sargent; Erik J Alexanian
Journal:  J Am Chem Soc       Date:  2016-06-10       Impact factor: 15.419

8.  Insertion of CO2 Mediated by a (Xantphos)NiI -Alkyl Species.

Authors:  Justin B Diccianni; Chunhua T Hu; Tianning Diao
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-14       Impact factor: 15.336

9.  Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp3)-H bonds.

Authors:  José A Fernández-Salas; Enrico Marelli; Steven P Nolan
Journal:  Chem Sci       Date:  2015-06-22       Impact factor: 9.825

Review 10.  Metal-Catalyzed Carboxylation of Organic (Pseudo)halides with CO2.

Authors:  Marino Börjesson; Toni Moragas; Daniel Gallego; Ruben Martin
Journal:  ACS Catal       Date:  2016-08-30       Impact factor: 13.084
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