Literature DB >> 25053211

Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction.

Satoshi Horike1, Wenqian Chen, Tomoya Itakura, Munehiro Inukai, Daiki Umeyama, Hiroyuki Asakura, Susumu Kitagawa.   

Abstract

We observed an ordered-to-disordered structural transformation in a Cu(2+) coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 °C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.

Entities:  

Year:  2014        PMID： 25053211     DOI： 10.1039/c4cc04370g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  A 3D open-framework iron hydrogenophosphate showing high proton conductance under water and aqua-ammonia vapor.

Authors:  Hai-Rong Zhao; Yin Jia; Yi Gu; Feng-Yun He; Kai-Ming Zhang; Zheng-Fang Tian; Jian-Lan Liu
Journal:  RSC Adv       Date:  2020-03-02       Impact factor: 4.036

2.  Ni(II)-Based Metallosupramolecular Polymer with Carboxylic Acid Groups: A Stable Platform for Smooth Imidazole Loading and the Anhydrous Proton Channel Formation.

Authors:  Yemineni S L V Narayana; Takefumi Yoshida; Manas Kumar Bera; Sanjoy Mondal; Masayoshi Higuchi
Journal:  ACS Omega       Date:  2020-06-12

Review 3.  Properties and Applications of Metal Phosphates and Pyrophosphates as Proton Conductors.

Authors:  Rosario M P Colodrero; Pascual Olivera-Pastor; Aurelio Cabeza; Montse Bazaga-García
Journal:  Materials (Basel)       Date:  2022-02-09       Impact factor: 3.623

4.  1000-fold enhancement in proton conductivity of a MOF using post-synthetically anchored proton transporters.

Authors:  Sorout Shalini; Vishal M Dhavale; Kavalakal M Eldho; Sreekumar Kurungot; Thallaseril G Ajithkumar; Ramanathan Vaidhyanathan
Journal:  Sci Rep       Date:  2016-08-31       Impact factor: 4.379

5.  Three-dimensional protonic conductivity in porous organic cage solids.

Authors:  Ming Liu; Linjiang Chen; Scott Lewis; Samantha Y Chong; Marc A Little; Tom Hasell; Iain M Aldous; Craig M Brown; Martin W Smith; Carole A Morrison; Laurence J Hardwick; Andrew I Cooper
Journal:  Nat Commun       Date:  2016-09-13       Impact factor: 14.919
  5 in total

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