Literature DB >> 25051013

Frustrated Lewis pair-mediated C-O or C-H bond activation of ethers.

Michael H Holthausen1, Tayseer Mahdi, Christoph Schlepphorst, Lindsay J Hounjet, Jan J Weigand, Douglas W Stephan.   

Abstract

Protocols for the FLP-mediated transformation of ethers are presented. Distinct reaction pathways involving either C-O or C-H bond activation occur depending on the application of oxophilic B(C6F5)3 or hydridophilic tritylium ions as the Lewis acid.

Entities:  

Year:  2014        PMID： 25051013     DOI： 10.1039/c4cc01922a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Enantioselective Organocopper-Catalyzed Hetero Diels-Alder Reaction through in Situ Oxidation of Ethers into Enol Ethers.

Authors:  Ahmet Yesilcimen; Na-Chuan Jiang; Felix H Gottlieb; Masayuki Wasa
Journal:  J Am Chem Soc       Date:  2022-04-05       Impact factor: 16.383

2.  Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines.

Authors:  Michael H Holthausen; Rashi R Hiranandani; Douglas W Stephan
Journal:  Chem Sci       Date:  2015-01-27       Impact factor: 9.825

3.  Heterolytic Si-H Bond Cleavage at a Molybdenum-Oxido-Based Lewis Pair.

Authors:  Niklas Zwettler; Simon P Walg; Ferdinand Belaj; Nadia C Mösch-Zanetti
Journal:  Chemistry       Date:  2018-04-27       Impact factor: 5.236

4.  The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6-i Pr2 C6 H3 N)}2 )GePCO.

Authors:  Yile Wu; Zhao Zhao; Ting Chen; Jingjie Tan; Zheng-Wang Qu; Stefan Grimme; Yufen Zhao; Douglas W Stephan
Journal:  Chemistry       Date:  2022-03-24       Impact factor: 5.020

5.  Directing group assisted meta-hydroxylation by C-H activation.

Authors:  Arun Maji; Bangaru Bhaskararao; Santanu Singha; Raghavan B Sunoj; Debabrata Maiti
Journal:  Chem Sci       Date:  2016-01-21       Impact factor: 9.825
  5 in total

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