| Literature DB >> 25044615 |
Feng Wang1, Jerrik Mielby, Felix Herrmann Richter, Guanghui Wang, Gonzalo Prieto, Takeshi Kasama, Claudia Weidenthaler, Hans-Josef Bongard, Søren Kegnæs, Alois Fürstner, Ferdi Schüth.
Abstract
We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.Entities:
Keywords: cross-coupling; nanoparticles; polymer supports; polyphenylenes
Year: 2014 PMID: 25044615 DOI: 10.1002/anie.201404912
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336