| Literature DB >> 25043525 |
Akihiro Tsurusaki1, Makoto Koganezono, Kyohei Otsuka, Shintaro Ishida, Soichiro Kyushin.
Abstract
The organosilicon cluster 1 with two pentasilahousanes fused together was synthesized by the reduction of 1,1,3-trichlorocyclotetrasilane. This reaction involves dimerization and rearrangement of the silicon skeleton. The structure and properties of 1 were studied by X-ray crystallographic and spectroscopic analyses.Entities:
Keywords: organosilicon clusters; pentasilahousane; theoretical calculations; trigonal monopyramidal geometry; σ conjugation
Year: 2014 PMID： 25043525 DOI： 10.1002/chem.201403375
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236