| Literature DB >> 25033232 |
Amit K Bali1, Sunil K Sunnam, Kavirayani R Prasad.
Abstract
The enantiospecific total synthesis of 14-membered macrolactone Sch 725674 was accomplished from tartaric acid. Key reactions in the synthesis include the Ley's dithiaketalization of an alkynone derived from the bis-Weinreb amide of tartaric acid, Boord olefination, and ring-closing metathesis of an acrylate ester.Entities:
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Year: 2014 PMID： 25033232 DOI： 10.1021/ol5018678
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005