| Literature DB >> 25032503 |
Michael Grigalunas1, Tobias Ankner, Per-Ola Norrby, Olaf Wiest, Paul Helquist.
Abstract
A protocol for a mild, catalytic, intermolecular alkenylation of ketone enolates has been developed using a Pd/Q-Phos catalyst. Efficient intermolecular coupling of a variety of ketones with alkenyl bromides was achieved with a slight excess of LiHMDS and temperatures down to 0 °C.Entities:
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Year: 2014 PMID： 25032503 DOI： 10.1021/ol5017965
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005