| Literature DB >> 25025392 |
Ken Kawano1, Kosei Yamauchi, Ken Sakai.
Abstract
A macrocyclic N-heterocyclic carbene (NHC)-cobalt complex was found to act as an improved H2-evolving catalyst in a [Ru(bpy)3](2+)-sensitized photosystem using methylviologen as a redox acceptor (MV(2+) + e(-) → MV(+)˙, MV(2+) = N,N'-dimethyl-4,4'-bipyridinium), which provides a driving force of only 150 meV for H2 evolution at pH 5.0.Entities:
Year: 2014 PMID： 25025392 DOI： 10.1039/c4cc03493g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222