Literature DB >> 25012792

Palladium/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination.

Bin Feng1, Hong-Gang Cheng, Jia-Rong Chen, Qiao-Hui Deng, Liang-Qiu Lu, Wen-Jing Xiao.   

Abstract

The Pd/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.

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Year:  2014        PMID: 25012792     DOI: 10.1039/c4cc03920c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Successive Nucleophilic and Electrophilic Allylation for the Catalytic Enantioselective Synthesis of 2,4-Disubstituted Pyrrolidines.

Authors:  Guoshun Luo; Ming Xiang; Michael J Krische
Journal:  Org Lett       Date:  2019-02-28       Impact factor: 6.005

2.  Palladium-catalyzed tandem allylic substitution/cyclization and cascade hydrosilylated reduction: the influence of reaction parameters and hydrosilanes on the stereoselectivity.

Authors:  Peng-Wei Long; Jian-Xing Xu; Xing-Feng Bai; Zheng Xu; Zhan-Jiang Zheng; Ke-Fang Yang; Li Li; Li-Wen Xu
Journal:  RSC Adv       Date:  2018-06-22       Impact factor: 3.361

  2 in total

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