| Literature DB >> 25010774 |
Brian C Sanders1, Sayed M Hassan, Todd C Harrop.
Abstract
The selective reduction of nitrite (NO2(-)) to nitric oxide (NO) is a fundamentally important chemical transformation related to environmental remediation of NOx and mammalian blood flow. We report the synthesis and characterization of two nonheme Fe complexes, [Fe(LN4(Im))(MeCN)2](BF4)2 (1(MeCN)) and [Fe(LN4(Im))(NO2)2] (2), geared toward understanding the NO2(-) to NO conversion. Complex 2 represents the first structurally characterized Fe(II) complex with two axial NO2(-) ligands that functions as a nitrite reduction catalyst.Entities:
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Year: 2014 PMID： 25010774 DOI： 10.1021/ja505236x
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419