| Literature DB >> 25003871 |
Taek Kang1, Seog Boem Song, Won-Yeob Kim, Byung Gyu Kim, Hee-Yoon Lee.
Abstract
The first total synthesis of (-)-crinipellin A is described. The tetraquinane core skeleton of crinipellin A was assembled through the tandem [2 + 3] cycloaddition reaction of an allenyl diazo substrate containing a cyclopentane ring in a single operation. The absolute stereochemistry was confirmed through the total synthesis.Entities:
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Year: 2014 PMID： 25003871 DOI： 10.1021/ja5054412
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419