Literature DB >> 24993111

Thiol as a synthon for preparing thiocarbonyl: aerobic oxidation of thiols for the synthesis of thioamides.

Xi Wang1, Miran Ji, Seungyeon Lim, Hye-Young Jang.   

Abstract

It is a constant challenge to develop an environmentally friendly, atom-economical, and step-economical method for the preparation of thioamides. Herein, we describe an oxidation method that affords the direct conversion of thiols to thioamides without the use of exogenous sulfur reagents. This is the first instance of a successful utilization of thiols as a synthon for the preparation of thioamides under economical conditions.

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Year:  2014        PMID： 24993111     DOI： 10.1021/jo501378v

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

1.  Aerobic Oxidation of Benzylic Carbons Using a Guanidine Base.

Authors:  Seulchan Lee; Si Ae Kim; Hye-Young Jang
Journal:  ACS Omega       Date:  2019-10-15

2.  Cellulose-reinforced poly(ethylene-co-vinyl acetate)-supported Ag nanoparticles with excellent catalytic properties: synthesis of thioamides using the Willgerodt-Kindler reaction.

Authors:  Anoop Singh; Sanjeev Saini; Narinder Singh; Navneet Kaur; Doo Ok Jang
Journal:  RSC Adv       Date:  2022-02-25       Impact factor: 3.361

3.  Microwave-assisted iodine-catalyzed oxidative coupling of dibenzyl(difurfuryl)disulfides with amines: a rapid and efficient protocol for thioamides.

Authors:  Jinyang Chen; Lan Mei; Jialing Liu; Chuntao Zhong; Binfang Yuan; Qiang Li
Journal:  RSC Adv       Date:  2019-09-10       Impact factor: 4.036

4.  Dimethylamine as the key intermediate generated in situ from dimethylformamide (DMF) for the synthesis of thioamides.

Authors:  Weibing Liu; Cui Chen; Hailing Liu
Journal:  Beilstein J Org Chem       Date:  2015-09-23       Impact factor: 2.883
  4 in total

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