| Literature DB >> 24990250 |
Paul A Lummis1, Mohammad R Momeni, Melanie W Lui, Robert McDonald, Michael J Ferguson, Mark Miskolzie, Alex Brown, Eric Rivard.
Abstract
We present isolable examples of formal zinc hydride cations supported by N-heterocyclic carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) character of the encapsulated [ZnH](+) units by computational methods and preliminary hydrosilylation catalysis.Entities:
Keywords: N-heterocyclic carbene; cations; homogeneous catalysis; hydrides; zinc
Year: 2014 PMID： 24990250 DOI： 10.1002/anie.201404611
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336