Literature DB >> 24979666

Csp3-csp3 homocoupling reaction of benzyl halides catalyzed by rhodium.

Kazuyuki Sato1, Yuichi Inoue, Tomohisa Mori, Atsushi Sakaue, Atsushi Tarui, Masaaki Omote, Itsumaro Kumadaki, Akira Ando.   

Abstract

A highly reactive alkylrhodium complex was formed from Me(2)Zn and RhCl(PPh(3))(3) and effectively catalyzed a Csp(3)-Csp(3) homocoupling reaction of benzyl halides. A Csp(3)-Csp(3) coupling reaction using Rh catalyst has not been reported up to now. The reaction proceeded under very mild conditions and gave the corresponding homocoupling products even if they had reactive substituents such as an uncovered formyl or hydroxymethyl group.

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Year:  2014        PMID： 24979666     DOI： 10.1021/ol501619w

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Luminescent tungsten(vi) complexes as photocatalysts for light-driven C-C and C-B bond formation reactions.

Authors:  Daohong Yu; Wai-Pong To; Glenna So Ming Tong; Liang-Liang Wu; Kaai-Tung Chan; Lili Du; David Lee Phillips; Yungen Liu; Chi-Ming Che
Journal:  Chem Sci       Date:  2020-05-25       Impact factor: 9.825

2.  C-Cl Oxidative Addition and C-C Reductive Elimination Reactions in the Context of the Rhodium-Promoted Direct Arylation.

Authors:  Laura A de Las Heras; Miguel A Esteruelas; Montserrat Oliván; Enrique Oñate
Journal:  Organometallics       Date:  2022-03-17       Impact factor: 3.876

3.  C(sp3)-C(sp3) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine.

Authors:  Dawei Cao; Chen-Chen Li; Huiying Zeng; Yong Peng; Chao-Jun Li
Journal:  Nat Commun       Date:  2021-06-17       Impact factor: 14.919
  3 in total

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