| Literature DB >> 24958540 |
Marie Betou1, Nicolas Kerisit, Esme Meledje, Yann R Leroux, Claudine Katan, Jean-François Halet, Jean-Claude Guillemin, Yann Trolez.
Abstract
A high-yielding sequence of [2+2] cycloaddition-retroelectrocyclization of ynamides with tetracyanoethylene (TCNE) is described. The reaction provided tetracyanobutadiene (TCBD) species, which were characterized by various techniques. DFT and TD-DFT calculations were also performed to complement experimental findings.Entities:
Keywords: [2+2] cycloaddition; tetracyanobutadienes; tetracyanoethylene; ynamides
Year: 2014 PMID： 24958540 DOI： 10.1002/chem.201402653
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236