| Literature DB >> 24957407 |
Kerstin Freitag1, Hung Banh, Christian Gemel, Rüdiger W Seidel, Samia Kahlal, Jean-Yves Saillard, Roland A Fischer.
Abstract
The first example of ligand protected Cu-Zn clusters is described. Reaction of [CpCu(CN(t)Bu)] with [Zn2Cp*2] yields [(CuCN(t)Bu)4(ZnCp*)4] (1a) and [(CuCN(t)Bu)4(ZnCp*)3(ZnCp)] (1b). According to DFT calculations, the [Cu4Zn4] unit fulfils the unified superatom model for cluster valence shell closing.Entities:
Year: 2014 PMID： 24957407 DOI： 10.1039/c4cc03401e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222