Literature DB >> 24956498

A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties.

Corentin Rinfray1, Séverine Renaudineau, Guillaume Izzet, Anna Proust.   

Abstract

A new polyoxomolybdate-based hybrid platform TBA4[PMo11O39{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.

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Year:  2014        PMID： 24956498     DOI： 10.1039/c4cc03779k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Effective Storage of Electrons in Water by the Formation of Highly Reduced Polyoxometalate Clusters.

Authors:  Jia-Jia Chen; Laia Vilà-Nadal; Albert Solé-Daura; Greig Chisholm; Takuo Minato; Christoph Busche; Tingting Zhao; Balamurugan Kandasamy; Alexey Y Ganin; Rachelle M Smith; Ian Colliard; Jorge J Carbó; Josep M Poblet; May Nyman; Leroy Cronin
Journal:  J Am Chem Soc       Date:  2022-05-10       Impact factor: 16.383

2.  Rapid photoinduced charge injection into covalent polyoxometalate-bodipy conjugates.

Authors:  Fiona A Black; Aurélie Jacquart; Georgios Toupalas; Sandra Alves; Anna Proust; Ian P Clark; Elizabeth A Gibson; Guillaume Izzet
Journal:  Chem Sci       Date:  2018-06-01       Impact factor: 9.825

3.  When Identification of the Reduction Sites in Mixed Molybdenum/Tungsten Keggin-Type Polyoxometalate Hybrids Turns Out Tricky.

Authors:  Maxime Laurans; Michele Mattera; Raphaël Salles; Ludivine K'Bidi; Pierre Gouzerh; Séverine Renaudineau; Florence Volatron; Geoffroy Guillemot; Sébastien Blanchard; Guillaume Izzet; Albert Solé-Daura; Josep M Poblet; Anna Proust
Journal:  Inorg Chem       Date:  2022-05-12       Impact factor: 5.436
  3 in total

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