(1,6,7,12-Tetra-aza-perylene-κ(2) N,N')bis-(4,4',5,5'-tetra-methyl-2,2'-bipyridyl-κ(2) N,N')ruthenium(II) bis-(hexa-fluorido-phosphate) aceto-nitrile tris-olvate.

In the title compound, rac-[Ru(C14H16N2)2(C16H8N4)](PF6)2·3C2H3N, discrete dimers of complex cations, [Ru(tmbpy)2-tape](2+), of opposite chirality are formed (tmbpy = tetra-methyl-bipyridine; tape = tetraazaperylene), held together by π-π stacking inter-actions between the tetra-aza-perylene moieties with centroid-centroid distances in the range 3.563 (3)-3.837 (3) Å. These inter-actions exhibit a parallel displaced π-π stacking mode. Additional weak C-H⋯π-ring and C-H⋯N and C-H⋯F inter-actions are found, leading to a three-dimensional architecture. The Ru(II) atom is coordinated in a distorted octa-hedral geometry. The counter-charge is provided by two hexa-fluorido-phosphate anions and the asymmetric unit is completed by three aceto-nitrile solvent mol-ecules of crystallization. Four F atoms of one PF6 (-) anion are disordered over three sets of sites with occupancies of 0.517 (3):0.244 (3):0.239 (3). Two aceto-nitrile solvent mol-ecules are highly disordered and their estimated scattering contribution was subtracted from the observed diffraction data using the SQUEEZE option in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155].

Related literature

For related RuII complexes with tape and bpy-type ligands, see: Brietzke et al. (2012 ▶). For background to the alkaloid eilatin, see: Rudia et al. (1988 ▶). For RuII complexes including eilatin-type ligands, see: Gut et al. (2002 ▶); Bergman et al. (2004 ▶, 2005 ▶).

Experimental

Crystal data

[Ru(C14H16N2)2(C16H8N4)](PF6)2·3C2H3N

M = 1195.01

Triclinic,

a = 12.7485 (5) Å

b = 13.6973 (7) Å

c = 17.3623 (9) Å

α = 105.786 (4)°

β = 92.858 (4)°

γ = 110.436 (3)°

V = 2698.3 (2) Å3

Z = 2

Mo Kα radiation

μ = 0.44 mm−1

T = 210 K

0.55 × 0.40 × 0.25 mm

Data collection

Stoe IPDS-2 diffractometer

Absorption correction: integration (X-RED; Stoe & Cie, 2011 ▶) T min = 0.758, T max = 0.955

17495 measured reflections

8918 independent reflections

6396 reflections with I > 2σ(I)

R int = 0.044

Refinement

R[F 2 > 2σ(F 2)] = 0.047

wR(F 2) = 0.124

S = 0.94

8918 reflections

743 parameters

363 restraints

H-atom parameters constrained

Δρmax = 0.51 e Å−3

Δρmin = −0.54 e Å−3

Data collection: X-AREA (Stoe & Cie, 2011 ▶); cell refinement: X-AREA; data reduction: X-RED (Stoe & Cie, 2011 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 2012 ▶) and ORTEP-3 for Windows (Farrugia, 2012 ▶); software used to prepare material for publication: SHELXL2013 and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536814011969/tk5315sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536814011969/tk5315Isup2.hkl

CCDC reference: 1004679

Additional supporting information: crystallographic information; 3D view; checkCIF report

[Ru(C14H16N2)2(C16H8N4)](PF6)2·3C2H3N	Z = 2
Mr = 1195.01	F(000) = 1216
Triclinic, P1	Dx = 1.471 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 12.7485 (5) Å	Cell parameters from 17908 reflections
b = 13.6973 (7) Å	θ = 1.2–27.1°
c = 17.3623 (9) Å	µ = 0.44 mm−1
α = 105.786 (4)°	T = 210 K
β = 92.858 (4)°	Prism, dark green
γ = 110.436 (3)°	0.55 × 0.40 × 0.25 mm
V = 2698.3 (2) Å3

Stoe IPDS-2 diffractometer	8918 independent reflections
Radiation source: fine-focus sealed tube	6396 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.044
ω scan	θmax = 25.0°, θmin = 1.7°
Absorption correction: integration (X-RED; Stoe & Cie, 2011)	h = −15→15
Tmin = 0.758, Tmax = 0.955	k = −16→16
17495 measured reflections	l = −20→20

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.124	H-atom parameters constrained
S = 0.94	w = 1/[σ2(Fo2) + (0.0767P)2] where P = (Fo2 + 2Fc2)/3
8918 reflections	(Δ/σ)max = 0.048
743 parameters	Δρmax = 0.51 e Å−3
363 restraints	Δρmin = −0.54 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.9535 (4)	0.5550 (3)	0.7768 (3)	0.0491 (10)
H1	0.9615	0.5471	0.7227	0.059*
C2	1.0166 (4)	0.6518 (3)	0.8328 (3)	0.0535 (11)
H2	1.0652	0.7083	0.8165	0.064*
C3	1.0691 (4)	0.7631 (4)	0.9812 (3)	0.0587 (12)
H3	1.1193	0.8251	0.9717	0.070*
C4	1.0525 (5)	0.7629 (4)	1.0582 (3)	0.0651 (13)
H4	1.0935	0.8267	1.1002	0.078*
C5	0.7638 (4)	0.4080 (4)	1.1288 (3)	0.0609 (12)
H5	0.7596	0.4113	1.1828	0.073*
C6	0.6955 (4)	0.3138 (4)	1.0720 (3)	0.0607 (12)
H6	0.6458	0.2564	1.0869	0.073*
C7	0.6375 (4)	0.2133 (4)	0.9220 (3)	0.0607 (12)
H7	0.5850	0.1513	0.9301	0.073*
C8	0.6524 (4)	0.2154 (3)	0.8455 (3)	0.0526 (11)
H8	0.6092	0.1540	0.8023	0.063*
C9	0.8701 (3)	0.4816 (3)	0.8733 (2)	0.0410 (9)
C10	0.9343 (4)	0.5786 (3)	0.9364 (2)	0.0432 (9)
C11	0.9233 (4)	0.5869 (3)	1.0184 (2)	0.0478 (10)
C12	0.8452 (4)	0.4914 (3)	1.0381 (2)	0.0469 (10)
C13	0.7788 (4)	0.3962 (3)	0.9733 (2)	0.0445 (9)
C14	0.7897 (3)	0.3907 (3)	0.8918 (2)	0.0412 (9)
C15	1.0090 (4)	0.6679 (3)	0.9168 (3)	0.0494 (10)
C16	0.7017 (4)	0.3052 (4)	0.9898 (3)	0.0515 (10)
C17	0.5981 (4)	0.4380 (3)	0.7574 (3)	0.0504 (10)
H17	0.5880	0.4096	0.8006	0.060*
C18	0.5422 (4)	0.5060 (4)	0.7492 (3)	0.0597 (12)
C19	0.5588 (4)	0.5515 (4)	0.6870 (3)	0.0592 (12)
C20	0.6286 (4)	0.5230 (4)	0.6332 (3)	0.0545 (11)
H20	0.6410	0.5517	0.5902	0.065*
C21	0.6795 (4)	0.4524 (3)	0.6434 (2)	0.0453 (10)
C22	0.7530 (3)	0.4178 (3)	0.5882 (2)	0.0418 (9)
C23	0.7676 (4)	0.4405 (3)	0.5163 (2)	0.0463 (10)
H23	0.7321	0.4832	0.5016	0.056*
C24	0.8338 (4)	0.4018 (3)	0.4652 (2)	0.0471 (10)
C25	0.8860 (3)	0.3373 (3)	0.4896 (2)	0.0438 (9)
C26	0.8688 (3)	0.3188 (3)	0.5624 (2)	0.0421 (9)
H26	0.9051	0.2780	0.5790	0.051*
C27	0.4646 (5)	0.5281 (5)	0.8090 (4)	0.0837 (17)
H27A	0.4665	0.4915	0.8488	0.126*
H27B	0.3885	0.5011	0.7808	0.126*
H27C	0.4895	0.6055	0.8355	0.126*
C28	0.5044 (6)	0.6280 (5)	0.6749 (3)	0.0866 (19)
H28A	0.5374	0.6964	0.7176	0.130*
H28B	0.4245	0.5963	0.6756	0.130*
H28C	0.5164	0.6403	0.6236	0.130*
C29	0.8467 (5)	0.4249 (4)	0.3863 (3)	0.0637 (13)
H29A	0.8157	0.3573	0.3426	0.096*
H29B	0.9256	0.4610	0.3846	0.096*
H29C	0.8070	0.4713	0.3809	0.096*
C30	0.9579 (4)	0.2884 (4)	0.4384 (3)	0.0611 (12)
H30A	0.9115	0.2353	0.3891	0.092*
H30B	0.9910	0.2533	0.4678	0.092*
H30C	1.0169	0.3452	0.4258	0.092*
C31	0.5323 (3)	0.1451 (3)	0.6379 (2)	0.0432 (9)
H31	0.5073	0.2028	0.6455	0.052*
C32	0.4521 (3)	0.0394 (3)	0.6086 (2)	0.0428 (9)
C33	0.4911 (4)	−0.0465 (3)	0.5967 (2)	0.0468 (10)
C34	0.6065 (4)	−0.0215 (3)	0.6128 (2)	0.0470 (10)
H34	0.6337	−0.0778	0.6035	0.056*
C35	0.6821 (3)	0.0867 (3)	0.6427 (2)	0.0406 (9)
C36	0.8029 (3)	0.1188 (3)	0.6649 (2)	0.0424 (9)
C37	0.8613 (4)	0.0500 (3)	0.6433 (3)	0.0508 (10)
H37	0.8221	−0.0223	0.6114	0.061*
C38	0.9769 (4)	0.0865 (3)	0.6681 (3)	0.0520 (11)
C39	1.0332 (4)	0.1945 (3)	0.7174 (2)	0.0471 (10)
C40	0.9713 (4)	0.2604 (3)	0.7350 (2)	0.0434 (9)
H40	1.0093	0.3331	0.7665	0.052*
C41	0.3296 (4)	0.0203 (4)	0.5928 (3)	0.0590 (11)
H41A	0.3002	−0.0190	0.5366	0.089*
H41B	0.3207	0.0895	0.6062	0.089*
H41C	0.2890	−0.0217	0.6255	0.089*
C42	0.4105 (4)	−0.1637 (3)	0.5686 (3)	0.0629 (13)
H42A	0.3631	−0.1776	0.5190	0.094*
H42B	0.3642	−0.1780	0.6092	0.094*
H42C	0.4526	−0.2107	0.5595	0.094*
C43	1.0396 (5)	0.0110 (4)	0.6420 (4)	0.0752 (15)
H43A	1.0889	0.0354	0.6053	0.113*
H43B	0.9861	−0.0621	0.6153	0.113*
H43C	1.0837	0.0117	0.6887	0.113*
C44	1.1565 (4)	0.2395 (4)	0.7511 (3)	0.0655 (13)
H44A	1.1776	0.3125	0.7873	0.098*
H44B	1.1999	0.2410	0.7075	0.098*
H44C	1.1713	0.1939	0.7800	0.098*
P1	0.28562 (13)	0.29009 (10)	0.53337 (8)	0.0656 (4)
F1A	0.3747 (3)	0.4046 (3)	0.5343 (2)	0.1070 (13)
F2A	0.1974 (3)	0.1762 (3)	0.5305 (2)	0.1152 (13)
F3A	0.2296 (13)	0.3494 (9)	0.5977 (9)	0.187 (10)	0.517 (3)
F4A	0.2066 (10)	0.2982 (11)	0.4647 (8)	0.100 (5)	0.517 (3)
F5A	0.3413 (12)	0.2335 (8)	0.4672 (11)	0.168 (9)	0.517 (3)
F6A	0.3657 (11)	0.2851 (10)	0.6007 (9)	0.170 (10)	0.517 (3)
F3B	0.3496 (11)	0.2988 (11)	0.6149 (6)	0.052 (6)	0.244 (3)
F4B	0.2101 (12)	0.3466 (11)	0.5793 (11)	0.107 (11)	0.244 (3)
F5B	0.2216 (13)	0.2815 (13)	0.4509 (8)	0.082 (10)	0.244 (3)
F6B	0.3595 (13)	0.2331 (11)	0.4864 (9)	0.144 (15)	0.244 (3)
F3C	0.3232 (18)	0.3186 (15)	0.6257 (6)	0.096 (12)	0.239 (3)
F4C	0.1944 (12)	0.3408 (11)	0.550 (2)	0.150 (18)	0.239 (3)
F5C	0.250 (2)	0.2632 (16)	0.4400 (7)	0.19 (3)	0.239 (3)
F6C	0.3778 (14)	0.2404 (13)	0.516 (2)	0.167 (18)	0.239 (3)
P2	0.30495 (19)	−0.05892 (15)	0.82144 (11)	0.1025 (6)
F7	0.3074 (8)	0.0519 (5)	0.8355 (7)	0.328 (7)
F8	0.3046 (7)	−0.1780 (4)	0.8031 (5)	0.240 (4)
F9	0.4063 (5)	−0.0332 (5)	0.7752 (3)	0.197 (3)
F10	0.2122 (6)	−0.0902 (6)	0.8698 (4)	0.271 (5)
F11	0.3925 (6)	−0.0232 (7)	0.8972 (3)	0.260 (5)
F12	0.2236 (6)	−0.1051 (6)	0.7437 (4)	0.243 (4)
N1	0.8782 (3)	0.4674 (2)	0.79498 (18)	0.0410 (7)
N2	0.9818 (3)	0.6779 (3)	1.0784 (2)	0.0575 (10)
N3	0.8370 (3)	0.4969 (3)	1.1151 (2)	0.0547 (9)
N4	0.7285 (3)	0.3040 (2)	0.82864 (19)	0.0417 (7)
N5	0.6659 (3)	0.4114 (2)	0.70604 (19)	0.0413 (8)
N6	0.8028 (3)	0.3555 (2)	0.61199 (17)	0.0388 (7)
N7	0.6437 (3)	0.1696 (2)	0.65597 (18)	0.0411 (8)
N8	0.8593 (3)	0.2260 (2)	0.70947 (18)	0.0385 (7)
Ru1	0.76414 (3)	0.32203 (2)	0.71845 (2)	0.03817 (11)
C45	0.6212 (11)	−0.0934 (9)	0.9095 (7)	0.172 (4)
H45A	0.6471	−0.0405	0.9626	0.258*
H45B	0.6331	−0.1586	0.9102	0.258*
H45C	0.5418	−0.1109	0.8942	0.258*
C46	0.6826 (9)	−0.0492 (7)	0.8529 (6)	0.123 (3)
N9	0.7363 (9)	−0.0128 (7)	0.8093 (6)	0.167 (3)
C47	0.8808 (10)	0.8156 (10)	0.7475 (6)	0.172 (5)
H47A	0.8579	0.8733	0.7417	0.259*
H47B	0.8611	0.7587	0.6964	0.259*
H47C	0.9613	0.8442	0.7647	0.259*
C48	0.8237 (9)	0.7712 (9)	0.8072 (7)	0.142 (3)
N10	0.7779 (10)	0.7379 (9)	0.8572 (6)	0.181 (4)

	U11	U22	U33	U12	U13	U23
C1	0.048 (3)	0.048 (2)	0.048 (2)	0.015 (2)	0.0124 (19)	0.0115 (18)
C2	0.050 (3)	0.043 (2)	0.062 (3)	0.008 (2)	0.011 (2)	0.019 (2)
C3	0.054 (3)	0.046 (2)	0.062 (3)	0.010 (2)	0.003 (2)	0.007 (2)
C4	0.063 (4)	0.050 (3)	0.063 (3)	0.013 (2)	0.004 (2)	0.000 (2)
C5	0.064 (4)	0.085 (3)	0.046 (2)	0.037 (3)	0.025 (2)	0.026 (2)
C6	0.057 (3)	0.072 (3)	0.058 (3)	0.024 (3)	0.023 (2)	0.026 (2)
C7	0.060 (3)	0.054 (3)	0.065 (3)	0.014 (2)	0.020 (2)	0.022 (2)
C8	0.049 (3)	0.049 (2)	0.055 (2)	0.014 (2)	0.014 (2)	0.0135 (19)
C9	0.037 (3)	0.0408 (19)	0.042 (2)	0.0148 (18)	0.0106 (17)	0.0069 (16)
C10	0.038 (3)	0.042 (2)	0.043 (2)	0.0150 (19)	0.0058 (17)	0.0043 (16)
C11	0.045 (3)	0.048 (2)	0.046 (2)	0.021 (2)	0.0094 (18)	0.0029 (18)
C12	0.043 (3)	0.055 (2)	0.043 (2)	0.023 (2)	0.0103 (18)	0.0109 (18)
C13	0.041 (3)	0.049 (2)	0.044 (2)	0.018 (2)	0.0143 (18)	0.0118 (17)
C14	0.038 (3)	0.042 (2)	0.044 (2)	0.0167 (19)	0.0121 (17)	0.0111 (17)
C15	0.045 (3)	0.043 (2)	0.054 (2)	0.015 (2)	0.0067 (19)	0.0073 (18)
C16	0.049 (3)	0.057 (2)	0.053 (2)	0.020 (2)	0.019 (2)	0.022 (2)
C17	0.047 (3)	0.051 (2)	0.056 (2)	0.024 (2)	0.016 (2)	0.0095 (19)
C18	0.054 (3)	0.059 (3)	0.062 (3)	0.032 (2)	0.011 (2)	−0.002 (2)
C19	0.058 (3)	0.058 (3)	0.061 (3)	0.034 (2)	0.002 (2)	0.002 (2)
C20	0.063 (3)	0.055 (2)	0.051 (2)	0.033 (2)	0.007 (2)	0.0107 (19)
C21	0.044 (3)	0.040 (2)	0.050 (2)	0.0174 (19)	0.0086 (18)	0.0060 (17)
C22	0.037 (3)	0.0349 (18)	0.047 (2)	0.0114 (18)	0.0036 (17)	0.0062 (16)
C23	0.050 (3)	0.039 (2)	0.046 (2)	0.017 (2)	0.0047 (19)	0.0070 (17)
C24	0.045 (3)	0.039 (2)	0.046 (2)	0.0083 (19)	0.0080 (18)	0.0062 (17)
C25	0.036 (3)	0.044 (2)	0.041 (2)	0.0104 (19)	0.0050 (17)	0.0031 (16)
C26	0.033 (3)	0.045 (2)	0.044 (2)	0.0157 (19)	0.0074 (17)	0.0063 (16)
C27	0.080 (4)	0.099 (4)	0.093 (4)	0.060 (4)	0.037 (3)	0.024 (3)
C28	0.108 (5)	0.097 (4)	0.078 (4)	0.077 (4)	0.017 (3)	0.012 (3)
C29	0.075 (4)	0.067 (3)	0.049 (2)	0.025 (3)	0.018 (2)	0.019 (2)
C30	0.060 (3)	0.074 (3)	0.050 (2)	0.033 (3)	0.019 (2)	0.010 (2)
C31	0.034 (3)	0.047 (2)	0.050 (2)	0.017 (2)	0.0038 (17)	0.0143 (17)
C32	0.032 (3)	0.049 (2)	0.044 (2)	0.0112 (19)	0.0049 (17)	0.0145 (17)
C33	0.040 (3)	0.046 (2)	0.045 (2)	0.011 (2)	0.0032 (18)	0.0077 (17)
C34	0.045 (3)	0.039 (2)	0.051 (2)	0.016 (2)	0.0014 (18)	0.0044 (17)
C35	0.035 (3)	0.043 (2)	0.040 (2)	0.0153 (19)	0.0063 (16)	0.0075 (16)
C36	0.038 (3)	0.040 (2)	0.045 (2)	0.0142 (19)	0.0034 (17)	0.0065 (16)
C37	0.044 (3)	0.042 (2)	0.061 (3)	0.020 (2)	0.006 (2)	0.0038 (18)
C38	0.042 (3)	0.051 (2)	0.064 (3)	0.022 (2)	0.011 (2)	0.013 (2)
C39	0.036 (3)	0.058 (2)	0.046 (2)	0.019 (2)	0.0031 (18)	0.0114 (18)
C40	0.037 (3)	0.048 (2)	0.040 (2)	0.0132 (19)	0.0027 (17)	0.0089 (16)
C41	0.042 (3)	0.061 (3)	0.077 (3)	0.017 (2)	0.011 (2)	0.028 (2)
C42	0.044 (3)	0.045 (2)	0.083 (3)	0.008 (2)	−0.001 (2)	0.007 (2)
C43	0.054 (4)	0.064 (3)	0.108 (4)	0.035 (3)	0.013 (3)	0.011 (3)
C44	0.048 (3)	0.075 (3)	0.068 (3)	0.027 (3)	0.001 (2)	0.009 (2)
P1	0.0775 (11)	0.0526 (7)	0.0667 (8)	0.0315 (7)	−0.0020 (7)	0.0117 (6)
F1A	0.116 (3)	0.0721 (19)	0.110 (3)	0.012 (2)	−0.037 (2)	0.0338 (18)
F2A	0.115 (4)	0.079 (2)	0.125 (3)	0.002 (2)	−0.015 (2)	0.042 (2)
F3A	0.36 (3)	0.203 (15)	0.115 (10)	0.214 (17)	0.126 (15)	0.073 (9)
F4A	0.073 (7)	0.140 (10)	0.102 (9)	0.040 (8)	0.001 (8)	0.065 (8)
F5A	0.143 (13)	0.093 (8)	0.27 (2)	0.070 (9)	0.101 (14)	0.013 (10)
F6A	0.178 (15)	0.080 (7)	0.223 (18)	0.018 (8)	−0.108 (14)	0.069 (9)
F3B	0.059 (12)	0.089 (12)	0.038 (7)	0.055 (11)	0.023 (7)	0.025 (7)
F4B	0.120 (19)	0.21 (3)	0.060 (10)	0.14 (2)	0.015 (10)	0.041 (12)
F5B	0.051 (14)	0.14 (2)	0.043 (10)	0.037 (16)	0.009 (10)	0.015 (11)
F6B	0.23 (3)	0.23 (3)	0.041 (9)	0.19 (3)	0.013 (11)	0.022 (11)
F3C	0.045 (11)	0.14 (2)	0.037 (7)	−0.019 (13)	0.015 (8)	0.004 (9)
F4C	0.068 (15)	0.078 (12)	0.31 (5)	0.027 (10)	−0.03 (2)	0.077 (19)
F5C	0.23 (5)	0.16 (3)	0.047 (12)	−0.09 (3)	−0.02 (2)	0.025 (15)
F6C	0.19 (4)	0.17 (3)	0.17 (3)	0.11 (3)	0.12 (3)	0.03 (2)
P2	0.1084 (17)	0.0854 (11)	0.0800 (11)	−0.0078 (10)	0.0051 (10)	0.0333 (9)
F7	0.346 (13)	0.100 (4)	0.573 (18)	0.103 (6)	0.239 (13)	0.106 (7)
F8	0.324 (11)	0.128 (5)	0.250 (8)	0.050 (6)	0.030 (7)	0.082 (5)
F9	0.185 (7)	0.242 (7)	0.157 (5)	0.050 (5)	0.078 (5)	0.084 (5)
F10	0.237 (9)	0.240 (7)	0.196 (6)	−0.064 (6)	0.122 (6)	0.039 (5)
F11	0.190 (7)	0.362 (11)	0.099 (4)	−0.014 (7)	−0.024 (4)	0.035 (5)
F12	0.233 (9)	0.265 (8)	0.159 (5)	0.029 (7)	−0.085 (5)	0.064 (5)
N1	0.040 (2)	0.0414 (17)	0.0426 (17)	0.0152 (16)	0.0121 (14)	0.0128 (14)
N2	0.057 (3)	0.054 (2)	0.048 (2)	0.017 (2)	0.0046 (17)	0.0003 (17)
N3	0.053 (3)	0.070 (2)	0.0403 (18)	0.027 (2)	0.0151 (16)	0.0100 (17)
N4	0.034 (2)	0.0397 (17)	0.0462 (18)	0.0119 (15)	0.0091 (14)	0.0082 (14)
N5	0.038 (2)	0.0381 (16)	0.0453 (18)	0.0160 (15)	0.0135 (15)	0.0064 (14)
N6	0.037 (2)	0.0370 (16)	0.0377 (16)	0.0159 (15)	0.0046 (14)	0.0027 (13)
N7	0.039 (2)	0.0395 (16)	0.0421 (17)	0.0149 (16)	0.0077 (14)	0.0077 (13)
N8	0.035 (2)	0.0394 (16)	0.0384 (16)	0.0135 (15)	0.0054 (14)	0.0085 (13)
Ru1	0.0355 (2)	0.03675 (17)	0.03886 (17)	0.01383 (14)	0.00804 (12)	0.00568 (12)
C45	0.202 (12)	0.162 (9)	0.177 (10)	0.084 (9)	0.077 (9)	0.064 (8)
C46	0.144 (9)	0.107 (6)	0.124 (7)	0.054 (6)	0.043 (6)	0.033 (5)
N9	0.178 (9)	0.152 (7)	0.188 (9)	0.057 (7)	0.074 (7)	0.079 (6)
C47	0.200 (12)	0.244 (12)	0.139 (8)	0.118 (10)	0.087 (8)	0.105 (9)
C48	0.124 (9)	0.152 (8)	0.149 (9)	0.073 (7)	0.009 (7)	0.019 (7)
N10	0.178 (10)	0.232 (11)	0.154 (8)	0.075 (8)	0.054 (7)	0.088 (8)

C1—C2	1.351 (6)	C31—C32	1.384 (6)
C1—N1	1.375 (5)	C31—H31	0.9300
C1—H1	0.9300	C32—C33	1.401 (5)
C2—C15	1.428 (6)	C32—C41	1.487 (6)
C2—H2	0.9300	C33—C34	1.383 (6)
C3—C4	1.365 (7)	C33—C42	1.498 (6)
C3—C15	1.400 (6)	C34—C35	1.389 (5)
C3—H3	0.9300	C34—H34	0.9300
C4—N2	1.347 (6)	C35—N7	1.357 (5)
C4—H4	0.9300	C35—C36	1.446 (6)
C5—N3	1.342 (6)	C36—N8	1.364 (5)
C5—C6	1.354 (7)	C36—C37	1.382 (5)
C5—H5	0.9300	C37—C38	1.383 (6)
C6—C16	1.407 (6)	C37—H37	0.9300
C6—H6	0.9300	C38—C39	1.395 (6)
C7—C8	1.359 (6)	C38—C43	1.507 (6)
C7—C16	1.421 (6)	C39—C40	1.379 (5)
C7—H7	0.9300	C39—C44	1.493 (6)
C8—N4	1.379 (5)	C40—N8	1.346 (5)
C8—H8	0.9300	C40—H40	0.9300
C9—N1	1.335 (5)	C41—H41A	0.9600
C9—C10	1.412 (5)	C41—H41B	0.9600
C9—C14	1.437 (6)	C41—H41C	0.9600
C10—C15	1.402 (6)	C42—H42A	0.9600
C10—C11	1.415 (5)	C42—H42B	0.9600
C11—N2	1.327 (5)	C42—H42C	0.9600
C11—C12	1.479 (6)	C43—H43A	0.9600
C12—N3	1.328 (5)	C43—H43B	0.9600
C12—C13	1.421 (6)	C43—H43C	0.9600
C13—C16	1.404 (6)	C44—H44A	0.9600
C13—C14	1.413 (5)	C44—H44B	0.9600
C14—N4	1.334 (5)	C44—H44C	0.9600
C17—N5	1.340 (5)	P1—F6A	1.545 (7)
C17—C18	1.386 (6)	P1—F3C	1.550 (9)
C17—H17	0.9300	P1—F5A	1.551 (8)
C18—C19	1.376 (7)	P1—F6B	1.550 (9)
C18—C27	1.512 (6)	P1—F3B	1.551 (8)
C19—C20	1.395 (6)	P1—F4C	1.552 (9)
C19—C28	1.496 (6)	P1—F3A	1.552 (7)
C20—C21	1.381 (6)	P1—F6C	1.554 (9)
C20—H20	0.9300	P1—F4B	1.556 (8)
C21—N5	1.347 (5)	P1—F2A	1.559 (4)
C21—C22	1.475 (5)	P1—F5C	1.565 (9)
C22—N6	1.359 (5)	P1—F5B	1.567 (9)
C22—C23	1.372 (6)	P2—F7	1.460 (5)
C23—C24	1.382 (6)	P2—F10	1.493 (5)
C23—H23	0.9300	P2—F12	1.496 (5)
C24—C25	1.409 (6)	P2—F11	1.529 (6)
C24—C29	1.492 (6)	P2—F9	1.542 (5)
C25—C26	1.369 (5)	P2—F8	1.573 (6)
C25—C30	1.505 (5)	N1—Ru1	2.048 (3)
C26—N6	1.354 (5)	N4—Ru1	2.047 (3)
C26—H26	0.9300	N5—Ru1	2.074 (3)
C27—H27A	0.9600	N6—Ru1	2.065 (3)
C27—H27B	0.9600	N7—Ru1	2.063 (3)
C27—H27C	0.9600	N8—Ru1	2.061 (3)
C28—H28A	0.9600	C45—C46	1.420 (12)
C28—H28B	0.9600	C45—H45A	0.9600
C28—H28C	0.9600	C45—H45B	0.9600
C29—H29A	0.9600	C45—H45C	0.9600
C29—H29B	0.9600	C46—N9	1.143 (11)
C29—H29C	0.9600	C47—C48	1.444 (14)
C30—H30A	0.9600	C47—H47A	0.9600
C30—H30B	0.9600	C47—H47B	0.9600
C30—H30C	0.9600	C47—H47C	0.9600
C31—N7	1.339 (5)	C48—N10	1.176 (13)
C2—C1—N1	123.9 (4)	C37—C38—C39	118.2 (4)
C2—C1—H1	118.1	C37—C38—C43	120.5 (4)
N1—C1—H1	118.1	C39—C38—C43	121.4 (4)
C1—C2—C15	120.4 (4)	C40—C39—C38	118.0 (4)
C1—C2—H2	119.8	C40—C39—C44	119.9 (4)
C15—C2—H2	119.8	C38—C39—C44	122.1 (4)
C4—C3—C15	118.6 (4)	N8—C40—C39	124.0 (4)
C4—C3—H3	120.7	N8—C40—H40	118.0
C15—C3—H3	120.7	C39—C40—H40	118.0
N2—C4—C3	125.4 (4)	C32—C41—H41A	109.5
N2—C4—H4	117.3	C32—C41—H41B	109.5
C3—C4—H4	117.3	H41A—C41—H41B	109.5
N3—C5—C6	126.4 (4)	C32—C41—H41C	109.5
N3—C5—H5	116.8	H41A—C41—H41C	109.5
C6—C5—H5	116.8	H41B—C41—H41C	109.5
C5—C6—C16	118.2 (4)	C33—C42—H42A	109.5
C5—C6—H6	120.9	C33—C42—H42B	109.5
C16—C6—H6	120.9	H42A—C42—H42B	109.5
C8—C7—C16	120.4 (4)	C33—C42—H42C	109.5
C8—C7—H7	119.8	H42A—C42—H42C	109.5
C16—C7—H7	119.8	H42B—C42—H42C	109.5
C7—C8—N4	123.2 (4)	C38—C43—H43A	109.5
C7—C8—H8	118.4	C38—C43—H43B	109.5
N4—C8—H8	118.4	H43A—C43—H43B	109.5
N1—C9—C10	124.1 (4)	C38—C43—H43C	109.5
N1—C9—C14	116.0 (3)	H43A—C43—H43C	109.5
C10—C9—C14	119.9 (3)	H43B—C43—H43C	109.5
C15—C10—C9	119.0 (4)	C39—C44—H44A	109.5
C15—C10—C11	120.0 (4)	C39—C44—H44B	109.5
C9—C10—C11	121.0 (4)	H44A—C44—H44B	109.5
N2—C11—C10	121.9 (4)	C39—C44—H44C	109.5
N2—C11—C12	118.9 (4)	H44A—C44—H44C	109.5
C10—C11—C12	119.3 (3)	H44B—C44—H44C	109.5
N3—C12—C13	121.7 (4)	F6A—P1—F5A	90.7 (6)
N3—C12—C11	119.8 (4)	F6B—P1—F3B	90.0 (6)
C13—C12—C11	118.5 (3)	F3C—P1—F4C	90.5 (7)
C16—C13—C14	118.9 (4)	F6A—P1—F3A	91.0 (6)
C16—C13—C12	119.9 (4)	F5A—P1—F3A	177.9 (7)
C14—C13—C12	121.2 (4)	F3C—P1—F6C	89.6 (7)
N4—C14—C13	123.6 (4)	F4C—P1—F6C	179.4 (8)
N4—C14—C9	116.4 (3)	F6B—P1—F4B	179.1 (8)
C13—C14—C9	120.0 (4)	F3B—P1—F4B	90.8 (6)
C3—C15—C10	117.0 (4)	F6A—P1—F2A	90.2 (4)
C3—C15—C2	126.7 (4)	F3C—P1—F2A	90.9 (5)
C10—C15—C2	116.3 (4)	F5A—P1—F2A	90.3 (4)
C13—C16—C6	116.8 (4)	F6B—P1—F2A	89.9 (6)
C13—C16—C7	116.8 (4)	F3B—P1—F2A	90.0 (5)
C6—C16—C7	126.3 (4)	F4C—P1—F2A	90.1 (5)
N5—C17—C18	123.1 (4)	F3A—P1—F2A	91.0 (5)
N5—C17—H17	118.5	F6C—P1—F2A	90.5 (6)
C18—C17—H17	118.5	F4B—P1—F2A	89.8 (5)
C19—C18—C17	119.2 (4)	F3C—P1—F5C	178.7 (8)
C19—C18—C27	122.0 (4)	F4C—P1—F5C	90.0 (7)
C17—C18—C27	118.9 (5)	F6C—P1—F5C	89.9 (7)
C18—C19—C20	117.7 (4)	F2A—P1—F5C	90.3 (5)
C18—C19—C28	122.8 (4)	F6B—P1—F5B	89.8 (7)
C20—C19—C28	119.5 (5)	F3B—P1—F5B	179.7 (8)
C21—C20—C19	120.3 (4)	F4B—P1—F5B	89.4 (7)
C21—C20—H20	119.8	F2A—P1—F5B	90.2 (5)
C19—C20—H20	119.8	F7—P2—F10	94.1 (4)
N5—C21—C20	121.5 (4)	F7—P2—F12	93.9 (5)
N5—C21—C22	115.3 (3)	F10—P2—F12	92.6 (4)
C20—C21—C22	123.2 (4)	F7—P2—F11	92.3 (5)
N6—C22—C23	121.2 (3)	F10—P2—F11	89.6 (4)
N6—C22—C21	114.5 (3)	F12—P2—F11	173.2 (5)
C23—C22—C21	124.2 (4)	F7—P2—F9	90.4 (4)
C22—C23—C24	121.7 (4)	F10—P2—F9	174.2 (5)
C22—C23—H23	119.2	F12—P2—F9	90.7 (4)
C24—C23—H23	119.2	F11—P2—F9	86.5 (4)
C23—C24—C25	117.5 (4)	F7—P2—F8	177.6 (5)
C23—C24—C29	121.1 (4)	F10—P2—F8	88.1 (4)
C25—C24—C29	121.4 (4)	F12—P2—F8	85.0 (4)
C26—C25—C24	117.7 (3)	F11—P2—F8	88.6 (4)
C26—C25—C30	119.8 (4)	F9—P2—F8	87.5 (4)
C24—C25—C30	122.5 (4)	C9—N1—C1	116.2 (3)
N6—C26—C25	124.9 (4)	C9—N1—Ru1	114.1 (3)
N6—C26—H26	117.6	C1—N1—Ru1	129.3 (3)
C25—C26—H26	117.6	C11—N2—C4	117.2 (4)
C18—C27—H27A	109.5	C12—N3—C5	116.9 (4)
C18—C27—H27B	109.5	C14—N4—C8	117.0 (3)
H27A—C27—H27B	109.5	C14—N4—Ru1	114.0 (3)
C18—C27—H27C	109.5	C8—N4—Ru1	128.9 (3)
H27A—C27—H27C	109.5	C17—N5—C21	118.1 (3)
H27B—C27—H27C	109.5	C17—N5—Ru1	126.1 (3)
C19—C28—H28A	109.5	C21—N5—Ru1	115.6 (2)
C19—C28—H28B	109.5	C26—N6—C22	117.0 (3)
H28A—C28—H28B	109.5	C26—N6—Ru1	127.0 (3)
C19—C28—H28C	109.5	C22—N6—Ru1	116.0 (2)
H28A—C28—H28C	109.5	C31—N7—C35	118.8 (3)
H28B—C28—H28C	109.5	C31—N7—Ru1	126.1 (2)
C24—C29—H29A	109.5	C35—N7—Ru1	114.5 (3)
C24—C29—H29B	109.5	C40—N8—C36	118.1 (3)
H29A—C29—H29B	109.5	C40—N8—Ru1	126.8 (2)
C24—C29—H29C	109.5	C36—N8—Ru1	114.7 (3)
H29A—C29—H29C	109.5	N4—Ru1—N1	79.34 (13)
H29B—C29—H29C	109.5	N4—Ru1—N8	91.00 (12)
C25—C30—H30A	109.5	N1—Ru1—N8	100.20 (12)
C25—C30—H30B	109.5	N4—Ru1—N7	92.60 (13)
H30A—C30—H30B	109.5	N1—Ru1—N7	171.90 (12)
C25—C30—H30C	109.5	N8—Ru1—N7	79.05 (13)
H30A—C30—H30C	109.5	N4—Ru1—N6	174.66 (12)
H30B—C30—H30C	109.5	N1—Ru1—N6	96.31 (12)
N7—C31—C32	124.1 (3)	N8—Ru1—N6	92.82 (12)
N7—C31—H31	118.0	N7—Ru1—N6	91.79 (12)
C32—C31—H31	118.0	N4—Ru1—N5	98.07 (12)
C31—C32—C33	117.3 (4)	N1—Ru1—N5	85.26 (12)
C31—C32—C41	120.2 (4)	N8—Ru1—N5	170.18 (12)
C33—C32—C41	122.5 (4)	N7—Ru1—N5	96.70 (13)
C34—C33—C32	118.8 (4)	N6—Ru1—N5	78.38 (12)
C34—C33—C42	119.9 (4)	C46—C45—H45A	109.5
C32—C33—C42	121.3 (4)	C46—C45—H45B	109.5
C33—C34—C35	120.7 (4)	H45A—C45—H45B	109.5
C33—C34—H34	119.7	C46—C45—H45C	109.5
C35—C34—H34	119.7	H45A—C45—H45C	109.5
N7—C35—C34	120.3 (4)	H45B—C45—H45C	109.5
N7—C35—C36	115.8 (3)	N9—C46—C45	177.0 (13)
C34—C35—C36	123.8 (3)	C48—C47—H47A	109.5
N8—C36—C37	120.3 (4)	C48—C47—H47B	109.5
N8—C36—C35	115.0 (3)	H47A—C47—H47B	109.5
C37—C36—C35	124.7 (4)	C48—C47—H47C	109.5
C36—C37—C38	121.3 (4)	H47A—C47—H47C	109.5
C36—C37—H37	119.4	H47B—C47—H47C	109.5
C38—C37—H37	119.4	N10—C48—C47	178.2 (13)
N1—C1—C2—C15	0.9 (7)	C30—C25—C26—N6	−177.7 (4)
C15—C3—C4—N2	−0.3 (8)	N7—C31—C32—C33	−0.6 (6)
N3—C5—C6—C16	1.4 (8)	N7—C31—C32—C41	178.0 (4)
C16—C7—C8—N4	0.0 (7)	C31—C32—C33—C34	−1.5 (6)
N1—C9—C10—C15	2.3 (6)	C41—C32—C33—C34	179.9 (4)
C14—C9—C10—C15	−177.5 (4)	C31—C32—C33—C42	177.4 (4)
N1—C9—C10—C11	−178.5 (4)	C41—C32—C33—C42	−1.2 (6)
C14—C9—C10—C11	1.7 (6)	C32—C33—C34—C35	2.1 (6)
C15—C10—C11—N2	0.2 (6)	C42—C33—C34—C35	−176.8 (4)
C9—C10—C11—N2	−179.1 (4)	C33—C34—C35—N7	−0.5 (6)
C15—C10—C11—C12	−179.2 (4)	C33—C34—C35—C36	176.7 (4)
C9—C10—C11—C12	1.6 (6)	N7—C35—C36—N8	11.4 (5)
N2—C11—C12—N3	−1.8 (6)	C34—C35—C36—N8	−165.9 (4)
C10—C11—C12—N3	177.6 (4)	N7—C35—C36—C37	−167.8 (4)
N2—C11—C12—C13	177.0 (4)	C34—C35—C36—C37	14.9 (6)
C10—C11—C12—C13	−3.6 (6)	N8—C36—C37—C38	2.1 (6)
N3—C12—C13—C16	0.4 (6)	C35—C36—C37—C38	−178.8 (4)
C11—C12—C13—C16	−178.3 (4)	C36—C37—C38—C39	1.4 (7)
N3—C12—C13—C14	−178.9 (4)	C36—C37—C38—C43	−178.3 (4)
C11—C12—C13—C14	2.4 (6)	C37—C38—C39—C40	−3.3 (6)
C16—C13—C14—N4	1.6 (6)	C43—C38—C39—C40	176.3 (4)
C12—C13—C14—N4	−179.1 (4)	C37—C38—C39—C44	176.6 (4)
C16—C13—C14—C9	−178.4 (4)	C43—C38—C39—C44	−3.8 (7)
C12—C13—C14—C9	0.9 (6)	C38—C39—C40—N8	2.0 (6)
N1—C9—C14—N4	−2.9 (5)	C44—C39—C40—N8	−177.9 (4)
C10—C9—C14—N4	176.9 (3)	C10—C9—N1—C1	−1.0 (6)
N1—C9—C14—C13	177.2 (3)	C14—C9—N1—C1	178.8 (3)
C10—C9—C14—C13	−3.0 (6)	C10—C9—N1—Ru1	−175.3 (3)
C4—C3—C15—C10	0.6 (7)	C14—C9—N1—Ru1	4.5 (4)
C4—C3—C15—C2	−178.7 (4)	C2—C1—N1—C9	−0.7 (6)
C9—C10—C15—C3	178.7 (4)	C2—C1—N1—Ru1	172.7 (3)
C11—C10—C15—C3	−0.6 (6)	C10—C11—N2—C4	0.2 (6)
C9—C10—C15—C2	−1.9 (6)	C12—C11—N2—C4	179.6 (4)
C11—C10—C15—C2	178.9 (4)	C3—C4—N2—C11	−0.1 (8)
C1—C2—C15—C3	179.8 (5)	C13—C12—N3—C5	0.6 (6)
C1—C2—C15—C10	0.4 (6)	C11—C12—N3—C5	179.3 (4)
C14—C13—C16—C6	178.8 (4)	C6—C5—N3—C12	−1.6 (7)
C12—C13—C16—C6	−0.5 (6)	C13—C14—N4—C8	−1.1 (6)
C14—C13—C16—C7	−1.2 (6)	C9—C14—N4—C8	178.9 (3)
C12—C13—C16—C7	179.5 (4)	C13—C14—N4—Ru1	179.8 (3)
C5—C6—C16—C13	−0.3 (6)	C9—C14—N4—Ru1	−0.2 (4)
C5—C6—C16—C7	179.7 (5)	C7—C8—N4—C14	0.3 (6)
C8—C7—C16—C13	0.5 (7)	C7—C8—N4—Ru1	179.3 (3)
C8—C7—C16—C6	−179.5 (4)	C18—C17—N5—C21	−0.3 (6)
N5—C17—C18—C19	−2.0 (7)	C18—C17—N5—Ru1	174.2 (3)
N5—C17—C18—C27	178.1 (5)	C20—C21—N5—C17	2.1 (6)
C17—C18—C19—C20	2.4 (7)	C22—C21—N5—C17	−178.6 (4)
C27—C18—C19—C20	−177.7 (5)	C20—C21—N5—Ru1	−173.0 (3)
C17—C18—C19—C28	−178.4 (5)	C22—C21—N5—Ru1	6.2 (4)
C27—C18—C19—C28	1.6 (8)	C25—C26—N6—C22	−2.0 (6)
C18—C19—C20—C21	−0.7 (7)	C25—C26—N6—Ru1	175.4 (3)
C28—C19—C20—C21	−179.9 (5)	C23—C22—N6—C26	1.2 (5)
C19—C20—C21—N5	−1.7 (7)	C21—C22—N6—C26	178.2 (3)
C19—C20—C21—C22	179.2 (4)	C23—C22—N6—Ru1	−176.5 (3)
N5—C21—C22—N6	−4.5 (5)	C21—C22—N6—Ru1	0.5 (4)
C20—C21—C22—N6	174.8 (4)	C32—C31—N7—C35	2.1 (6)
N5—C21—C22—C23	172.5 (4)	C32—C31—N7—Ru1	−168.2 (3)
C20—C21—C22—C23	−8.3 (7)	C34—C35—N7—C31	−1.5 (5)
N6—C22—C23—C24	−0.3 (6)	C36—C35—N7—C31	−178.9 (3)
C21—C22—C23—C24	−177.1 (4)	C34—C35—N7—Ru1	169.9 (3)
C22—C23—C24—C25	0.1 (6)	C36—C35—N7—Ru1	−7.5 (4)
C22—C23—C24—C29	178.5 (4)	C39—C40—N8—C36	1.5 (6)
C23—C24—C25—C26	−0.8 (6)	C39—C40—N8—Ru1	−170.6 (3)
C29—C24—C25—C26	−179.2 (4)	C37—C36—N8—C40	−3.5 (6)
C23—C24—C25—C30	178.7 (4)	C35—C36—N8—C40	177.3 (3)
C29—C24—C25—C30	0.3 (6)	C37—C36—N8—Ru1	169.6 (3)
C24—C25—C26—N6	1.8 (6)	C35—C36—N8—Ru1	−9.6 (4)

D—H···A	D—H	H···A	D···A	D—H···A
C2—H2···F10i	0.93	2.61	3.402 (7)	143
C3—H3···F10i	0.93	2.50	3.318 (8)	147
C6—H6···F8ii	0.93	2.58	3.218 (8)	126
C8—H8···N7	0.93	2.65	3.166 (5)	116
C20—H20···F1Aiii	0.93	2.41	3.320 (6)	166
C20—H20···F5Ciii	0.93	2.64	3.411 (15)	141
C23—H23···F1Aiii	0.93	2.55	3.479 (5)	177
C26—H26···N8	0.93	2.59	3.138 (5)	118
C31—H31···F6A	0.93	2.63	3.461 (13)	150
C34—H34···F5Aiv	0.93	2.29	3.170 (8)	158
C34—H34···F6Biv	0.93	2.30	3.129 (11)	148
C34—H34···F6Civ	0.93	2.55	3.295 (19)	137
C45—H45A···F11ii	0.96	2.49	3.343 (12)	148
C45—H45C···F11	0.96	2.58	3.388 (15)	142
C47—H47A···N9v	0.96	2.66	3.452 (14)	140
C47—H47B···F5Biii	0.96	2.55	3.343 (16)	140
C47—H47B···F5Ciii	0.96	2.59	3.293 (15)	131
C8—H8···Cg1	0.93	2.92	3.711 (5)	144
C26—H26···Cg2	0.93	2.90	3.708 (4)	146
C42—H42A···Cg3vi	0.96	2.79	3.339 (5)	117

Table 1

Selected bond lengths (Å)

N1—Ru1	2.048 (3)
N4—Ru1	2.047 (3)
N5—Ru1	2.074 (3)
N6—Ru1	2.065 (3)
N7—Ru1	2.063 (3)
N8—Ru1	2.061 (3)

Table 2

Hydrogen-bond geometry (Å, °)

Cg1, Cg2 and Cg3 denote the centroids of the N7/C31–C35, N8/C36–C40 and N6/C22–C26 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C2—H2⋯F10i	0.93	2.61	3.402 (7)	143
C3—H3⋯F10i	0.93	2.50	3.318 (8)	147
C6—H6⋯F8ii	0.93	2.58	3.218 (8)	126
C8—H8⋯N7	0.93	2.65	3.166 (5)	116
C20—H20⋯F1A iii	0.93	2.41	3.320 (6)	166
C20—H20⋯F5C iii	0.93	2.64	3.411 (15)	141
C23—H23⋯F1A iii	0.93	2.55	3.479 (5)	177
C26—H26⋯N8	0.93	2.59	3.138 (5)	118
C31—H31⋯F6A	0.93	2.63	3.461 (13)	150
C34—H34⋯F5A iv	0.93	2.29	3.170 (8)	158
C34—H34⋯F6B iv	0.93	2.30	3.129 (11)	148
C34—H34⋯F6C iv	0.93	2.55	3.295 (19)	137
C45—H45A⋯F11ii	0.96	2.49	3.343 (12)	148
C45—H45C⋯F11	0.96	2.58	3.388 (15)	142
C47—H47A⋯N9v	0.96	2.66	3.452 (14)	140
C47—H47B⋯F5B iii	0.96	2.55	3.343 (16)	140
C47—H47B⋯F5C iii	0.96	2.59	3.293 (15)	131
C8—H8⋯Cg1	0.93	2.92	3.711 (5)	144
C26—H26⋯Cg2	0.93	2.90	3.708 (4)	146
C42—H42A⋯Cg3vi	0.96	2.79	3.339 (5)	117

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) .