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Literature DB >> 24915842

Nickel-catalysed carboxylation of organoboronates.

Yusuke Makida¹, Enrico Marelli, Alexandra M Z Slawin, Steven P Nolan.

Abstract

A nickel/N-heterocyclic carbene (NHC) catalysed carboxylation of aryl-, heteroaryl- and alkenylboronates, affording the corresponding carboxylic acids, has been developed. This transformation proceeds under one atmosphere of CO2 with a broad range of substrates and exhibits good functional group compatibility.

Entities: Chemical Disease

Year: 2014 PMID： 24915842 DOI： 10.1039/c4cc03650f

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. Well-defined nickel and palladium precatalysts for cross-coupling.

Authors: Nilay Hazari; Patrick R Melvin; Megan Mohadjer Beromi
Journal: Nat Rev Chem Date: 2017-03-01 Impact factor: 34.035

2. Modifications to the Aryl Group of dppf-Ligated Ni σ‑Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions.

Authors: Megan Mohadjer Beromi; Gourab Banerjee; Gary W Brudvig; David J Charboneau; Nilay Hazari; Hannah M C Lant; Brandon Q Mercado
Journal: Organometallics Date: 2018-10-16 Impact factor: 3.876

Nickel-catalysed carboxylation of organoboronates.

1. Well-defined nickel and palladium precatalysts for cross-coupling.

2. Modifications to the Aryl Group of dppf-Ligated Ni σ‑Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions.

3. Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp³)-H bonds.

4. Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles.

5. Formal C-H Carboxylation of Unactivated Arenes.

6. Nickel-catalyzed cyclization of alkyne-nitriles with organoboronic acids involving anti-carbometalation of alkynes.

Nickel-catalysed carboxylation of organoboronates.

1. Well-defined nickel and palladium precatalysts for cross-coupling.

2. Modifications to the Aryl Group of dppf-Ligated Ni σ‑Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions.

3. Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp3)-H bonds.

4. Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles.

5. Formal C-H Carboxylation of Unactivated Arenes.

6. Nickel-catalyzed cyclization of alkyne-nitriles with organoboronic acids involving anti-carbometalation of alkynes.

3. Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp³)-H bonds.