Literature DB >> 24909943

An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH].

David A Ruiz1, Mohand Melaimi, Guy Bertrand.   

Abstract

Two-electron reduction of bis(carbene) boronium salts allows for the preparation of unsymmetrically substituted nucleophilic boron derivatives of type (L1)(L2)BH, which are characterized by X-ray crystallography. A single electron reduction of the same starting materials leads to the corresponding boron-centered radical cations (L1)(L2)BH˙(+), X(-).

Entities:  

Year:  2014        PMID： 24909943     DOI： 10.1039/c4cc03497j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  19 in total

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Review 2.  Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.

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3.  Probing the Boundaries between Lewis-Basic and Redox Behavior of a Parent Borylene.

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Journal:  Chemistry       Date:  2021-11-11       Impact factor: 5.020

4.  An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry.

Authors:  Wei Lu; Arumugam Jayaraman; Felipe Fantuzzi; Rian D Dewhurst; Marcel Härterich; Maximilian Dietz; Stephan Hagspiel; Ivo Krummenacher; Kai Hammond; Jingjing Cui; Holger Braunschweig
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-03       Impact factor: 16.823

5.  1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres.

Authors:  Di Wu; Lingbing Kong; Yongxin Li; Rakesh Ganguly; Rei Kinjo
Journal:  Nat Commun       Date:  2015-06-15       Impact factor: 14.919

6.  Ambiphilic boron in 1,4,2,5-diazadiborinine.

Authors:  Baolin Wang; Yongxin Li; Rakesh Ganguly; Hajime Hirao; Rei Kinjo
Journal:  Nat Commun       Date:  2016-06-09       Impact factor: 14.919

7.  Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.

Authors:  Lingbing Kong; Rakesh Ganguly; Yongxin Li; Rei Kinjo
Journal:  Chem Sci       Date:  2015-02-23       Impact factor: 9.825

8.  Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.

Authors:  Dominic Auerhammer; Merle Arrowsmith; Holger Braunschweig; Rian D Dewhurst; J Oscar C Jiménez-Halla; Thomas Kupfer
Journal:  Chem Sci       Date:  2017-08-04       Impact factor: 9.825

9.  Easy access to nucleophilic boron through diborane to magnesium boryl metathesis.

Authors:  Anne-Frédérique Pécharman; Annie L Colebatch; Michael S Hill; Claire L McMullin; Mary F Mahon; Catherine Weetman
Journal:  Nat Commun       Date:  2017-04-07       Impact factor: 14.919

10.  Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.

Authors:  Johannes Landmann; Philipp T Hennig; Nikolai V Ignat'ev; Maik Finze
Journal:  Chem Sci       Date:  2017-06-26       Impact factor: 9.825
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