Literature DB >> 24893594

Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration.

Xue-Qiang Chu1, You Zi, Hua Meng, Xiao-Ping Xu, Shun-Jun Ji.   

Abstract

A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp(3)) and C(sp(3))-P bonds was observed.

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Year:  2014        PMID： 24893594     DOI： 10.1039/c4cc02114b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Photocatalytic Radical Aroylation of Unactivated Alkenes: Pathway to β-Functionalized 1,4-, 1,6-, and 1,7-Diketones.

Authors:  Satavisha Sarkar; Arghya Banerjee; Wang Yao; Eric V Patterson; Ming-Yu Ngai
Journal:  ACS Catal       Date:  2019-10-17       Impact factor: 13.084

2.  Radical Aryl Migration from Boron to Carbon.

Authors:  Dinghai Wang; Christian Mück-Lichtenfeld; Constantin G Daniliuc; Armido Studer
Journal:  J Am Chem Soc       Date:  2021-06-20       Impact factor: 15.419

3.  Palladium-Catalyzed Cross-Coupling of α-Bromocarbonyls and Allylic Alcohols for the Synthesis of α-Aryl Dicarbonyl Compounds.

Authors:  Yang Yu; Uttam K Tambar
Journal:  Chem Sci       Date:  2015       Impact factor: 9.825
  3 in total

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