Literature DB >> 24890908

Continuous flow photochemistry.

Kerry Gilmore1, Peter H Seeberger.   

Abstract

Due to the narrow width of tubing/reactors used, photochemistry performed in micro- and mesoflow systems is significantly more efficient than when performed in batch due to the Beer-Lambert Law. Owing to the constant removal of product and facility of flow chemical scalability, the degree of degradation observed is generally decreased and the productivity of photochemical processes is increased. In this Personal Account, we describe a wide range of photochemical transformations we have examined using both visible and UV light, covering cyclizations, intermolecular couplings, radical polymerizations, as well as singlet oxygen oxygenations.
Copyright © 2014 The Chemical Society of Japan and Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords:  continuous flow; photochemistry; radical polymerization; single electron transfer; singlet oxygen

Mesh:

Substances:

Year:  2014        PMID: 24890908     DOI: 10.1002/tcr.201402035

Source DB:  PubMed          Journal:  Chem Rec        ISSN: 1528-0691            Impact factor:   6.771


  14 in total

1.  A photochemical flow reactor for large scale syntheses of aglain and rocaglate natural product analogues.

Authors:  Han Yueh; Qiwen Gao; John A Porco; Aaron B Beeler
Journal:  Bioorg Med Chem       Date:  2017-06-11       Impact factor: 3.641

2.  Divergent Total Syntheses of Rhodomyrtosones A and B.

Authors:  Anais Gervais; Kiel E Lazarski; John A Porco
Journal:  J Org Chem       Date:  2015-10-02       Impact factor: 4.354

Review 3.  Machine-Assisted Organic Synthesis.

Authors:  Steven V Ley; Daniel E Fitzpatrick; Rebecca M Myers; Claudio Battilocchio; Richard J Ingham
Journal:  Angew Chem Int Ed Engl       Date:  2015-07-16       Impact factor: 15.336

Review 4.  Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis.

Authors:  Markus D Kärkäs; John A Porco; Corey R J Stephenson
Journal:  Chem Rev       Date:  2016-04-27       Impact factor: 60.622

5.  Visible Light-Promoted Beckmann Rearrangements: Separating Sequential Photochemical and Thermal Phenomena in a Continuous Flow Reactor.

Authors:  Yuesu Chen; David Cantillo; C Oliver Kappe
Journal:  European J Org Chem       Date:  2019-03-08

6.  A flow reactor setup for photochemistry of biphasic gas/liquid reactions.

Authors:  Josef Schachtner; Patrick Bayer; Axel Jacobi von Wangelin
Journal:  Beilstein J Org Chem       Date:  2016-08-11       Impact factor: 2.883

7.  Organophotocatalytic N-Demethylation of Oxycodone Using Molecular Oxygen.

Authors:  Yuesu Chen; Gabriel Glotz; David Cantillo; C Oliver Kappe
Journal:  Chemistry       Date:  2020-02-18       Impact factor: 5.236

8.  Organophotoredox Hydrodefluorination of Trifluoromethylarenes with Translational Applicability to Drug Discovery.

Authors:  Jeroen B I Sap; Natan J W Straathof; Thomas Knauber; Claudio F Meyer; Maurice Médebielle; Laura Buglioni; Christophe Genicot; Andrés A Trabanco; Timothy Noël; Christopher W Am Ende; Véronique Gouverneur
Journal:  J Am Chem Soc       Date:  2020-05-11       Impact factor: 15.419

Review 9.  Photosensitized direct C-H fluorination and trifluoromethylation in organic synthesis.

Authors:  Shahboz Yakubov; Joshua P Barham
Journal:  Beilstein J Org Chem       Date:  2020-09-03       Impact factor: 2.883

Review 10.  Sunscreen-Assisted Selective Photochemical Transformations.

Authors:  Or Eivgi; N Gabriel Lemcoff
Journal:  Molecules       Date:  2020-05-01       Impact factor: 4.411

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