Literature DB >> 24890043

Hydrogenation of esters to alcohols with a well-defined iron complex.

Svenja Werkmeister1, Kathrin Junge, Bianca Wendt, Elisabetta Alberico, Haijun Jiao, Wolfgang Baumann, Henrik Junge, Fabrice Gallou, Matthias Beller.   

Abstract

We present the first base-free Fe-catalyzed ester reduction applying molecular hydrogen. Without any additives, a variety of carboxylic acid esters and lactones were hydrogenated with high efficiency. Computations reveal an outer-sphere mechanism involving simultaneous hydrogen transfer from the iron center and the ligand. This assumption is supported by NMR experiments.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alcohols; esters; homogeneous catalysis; hydrogenation; iron

Mesh：

Substances：

Year:  2014        PMID： 24890043     DOI： 10.1002/anie.201402542

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  18 in total

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Journal:  ChemCatChem       Date:  2021-09-14       Impact factor: 5.497

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3.  Synthesis, Structure, and Reactivity of Co(II) and Ni(II) PCP Pincer Borohydride Complexes.

Authors:  Sathiyamoorthy Murugesan; Berthold Stöger; Matthias Weil; Luis F Veiros; Karl Kirchner
Journal:  Organometallics       Date:  2015-03-16       Impact factor: 3.876

4.  CH2 Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors:  Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal:  Sci Rep       Date:  2017-06-21       Impact factor: 4.379

5.  Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters.

Authors:  Robbert van Putten; Evgeny A Uslamin; Marcel Garbe; Chong Liu; Angela Gonzalez-de-Castro; Martin Lutz; Kathrin Junge; Emiel J M Hensen; Matthias Beller; Laurent Lefort; Evgeny A Pidko
Journal:  Angew Chem Int Ed Engl       Date:  2017-04-21       Impact factor: 15.336

6.  Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors:  Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

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8.  Highly Efficient and Selective Hydrogenation of Aldehydes: A Well-Defined Fe(II) Catalyst Exhibits Noble-Metal Activity.

Authors:  Nikolaus Gorgas; Berthold Stöger; Luis F Veiros; Karl Kirchner
Journal:  ACS Catal       Date:  2016-03-11       Impact factor: 13.084

9.  Iron catalyzed CO2 hydrogenation to formate enhanced by Lewis acid co-catalysts.

Authors:  Yuanyuan Zhang; Alex D MacIntosh; Janice L Wong; Elizabeth A Bielinski; Paul G Williard; Brandon Q Mercado; Nilay Hazari; Wesley H Bernskoetter
Journal:  Chem Sci       Date:  2015-05-28       Impact factor: 9.825

10.  Chemoselective Hydrogenation of Aldehydes under Mild, Base-Free Conditions: Manganese Outperforms Rhenium.

Authors:  Mathias Glatz; Berthold Stöger; Daniel Himmelbauer; Luis F Veiros; Karl Kirchner
Journal:  ACS Catal       Date:  2018-04-02       Impact factor: 13.084
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