Literature DB >> 24888758

Azaphosphatrane organocatalysts in confined space: cage effect in CO(2) conversion.

Bastien Chatelet1, Lionel Joucla, Jean-Pierre Dutasta, Alexandre Martinez, Véronique Dufaud.   

Abstract

The endohedral functionalization of a molecular cage by an azaphosphatrane unit has allowed for the creation of highly engineered catalytic cavities for efficient conversion of CO2 into cyclic carbonates. Strong structure/activity/stability correlations have been demonstrated by careful adjustment of the size, shape, and electronic properties of the hemicryptophane host.
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CO2 conversion; azaphosphatranes; cyclic carbonates; green chemistry; organocatalysis

Year:  2014        PMID: 24888758     DOI: 10.1002/chem.201402058

Source DB:  PubMed          Journal:  Chemistry        ISSN: 0947-6539            Impact factor:   5.236


  3 in total

1.  Novel porous organocatalysts for cycloaddition of CO2 and epoxides.

Authors:  Joel M Kolle; Abdelhamid Sayari
Journal:  RSC Adv       Date:  2019-08-07       Impact factor: 4.036

2.  Tailored oxido-vanadium(V) cage complexes for selective sulfoxidation in confined spaces.

Authors:  Dawei Zhang; Kelsey Jamieson; Laure Guy; Guohua Gao; Jean-Pierre Dutasta; Alexandre Martinez
Journal:  Chem Sci       Date:  2016-09-05       Impact factor: 9.825

3.  Metal-salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides under ambient conditions.

Authors:  Chee Koon Ng; Ren Wei Toh; Ting Ting Lin; He-Kuan Luo; T S Andy Hor; Jie Wu
Journal:  Chem Sci       Date:  2018-11-29       Impact factor: 9.825

  3 in total

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