Literature DB >> 24875676

A truncated [Mn(III)₁₂] tetrahedron from oxime-based [Mn(III)₃O] building blocks.

J M Frost1, S Sanz, T Rajeshkumar, M B Pitak, S J Coles, G Rajaraman, W Wernsdorfer, J Schnack, P J Lusby, E K Brechin.   

Abstract

The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn(III)12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

Entities:  

Year:  2014        PMID： 24875676     DOI： 10.1039/c4dt01469c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Crystal structure of 2-hydroxy-N-(2-hydroxyethyl)-N-{2-hydroxy-3-[(E)-N-hydroxyethanimidoyl]-5-methylbenzyl}ethanaminium acetate monohydrate.

Authors:  Gary S Nichol; Jamie M Frost; Sergio Sanz; Euan K Brechin
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-02-18

2.  From Gas Phase Observations to Solid State Reality: The Identification and Isolation of Trinuclear Salicylaldoximato Copper Complexes.

Authors:  Benjamin D Roach; Ross S Forgan; Eduardo Kamenetzky; Simon Parsons; Paul G Plieger; Fraser J White; Sidney Woodhouse; Peter A Tasker
Journal:  Molecules       Date:  2022-09-29       Impact factor: 4.927

3.  Supramolecular aggregates of single-molecule magnets: exchange-biased quantum tunneling of magnetization in a rectangular [Mn3]4 tetramer.

Authors:  Tu N Nguyen; Wolfgang Wernsdorfer; Muhandis Shiddiq; Khalil A Abboud; Stephen Hill; George Christou
Journal:  Chem Sci       Date:  2015-11-16       Impact factor: 9.825
  3 in total

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