Literature DB >> 24867599

Synthesis and electronic structure of the first cyaphide-alkynyl complexes.

Nicola Trathen1, Matthew C Leech, Ian R Crossley, Victoria K Greenacre, S Mark Roe.   

Abstract

The novel complexes trans-[Ru(dppe)2(C≡CR)(C≡P)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.

Entities:  

Year:  2014        PMID: 24867599     DOI: 10.1039/c4dt01108b

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  A Cyaphide Transfer Reagent.

Authors:  Daniel W N Wilson; Stephanie J Urwin; Eric S Yang; Jose M Goicoechea
Journal:  J Am Chem Soc       Date:  2021-06-30       Impact factor: 15.419

  1 in total

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