Literature DB >> 24867436

Metal-free azaphosphaannulation of phosphonamides through intramolecular oxidative C-N bond formation.

Yea Rin Kim1, Seungyoon Cho, Phil Ho Lee.   

Abstract

We report an efficient metal-free azaphosphaannulation of a myriad of phosphonamides through intramolecular oxidative C-N bond formation using PhI(OAc)2 and iodine in acetonitrile under air, thus leading to the formation of benzazaphosphol-3-one 1-oxides, which are novel phosphorus heterocyclic privileged structures.

Entities:  

Year:  2014        PMID: 24867436     DOI: 10.1021/ol501207w

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

Review 1.  Synthetic strategies for the preparation of γ-phostams: 1,2-azaphospholidine 2-oxides and 1,2-azaphospholine 2-oxides.

Authors:  Jiaxi Xu
Journal:  Beilstein J Org Chem       Date:  2022-07-22       Impact factor: 2.544

  1 in total

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