Literature DB >> 24852893

A new twist in the old story-can compression induce mixing of phase separated solid dispersions? A case study of spray-dried miconazole-PVP VA64 solid dispersions.

Abhishek Singh1, Jan Van Humbeeck, Guy Van den Mooter.   

Abstract

PURPOSE: The phase response of Miconazole-PVP VA64 solid dispersions upon compression was investigated. This would allow understanding the phase behavior of these solid dispersions upon application of a different kind of stress (other than humidity and temperature) and ultimately lead to mechanistic perception of the phase changes taking place.
METHODS: Miconazole and PVP VA64 were chosen as a model drug and polymer, respectively and solid dispersions were prepared by spray drying. Dried solid dispersions were compressed using different compression pressure but constant dwell time. MDSC and XRPD were used to characterize and study the effect of compression on the system.
RESULTS: The solid dispersions showed a single Tg till 20% drug loading after which two Tg's were observed. Application of compression to the phase separated 30 and 40% compositions induced mixing resulting in only a single Tg. This reduction in number of Tg's upon compression is a result of mixing which can be attributed to polymer flow resulting in reduction of the domain size of different phases in the solid dispersions.
CONCLUSIONS: Application of compression can influence the phase behavior of Miconazole-PVP VA64 solid dispersions. This observation may have drastic impact on the formulation development approach for solid dispersions to be administered as tablets.

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Year:  2014        PMID: 24852893     DOI: 10.1007/s11095-014-1411-6

Source DB:  PubMed          Journal:  Pharm Res        ISSN: 0724-8741            Impact factor:   4.200


  16 in total

Review 1.  Effects of mechanical processing on phase composition.

Authors:  Harry G Brittain
Journal:  J Pharm Sci       Date:  2002-07       Impact factor: 3.534

2.  An investigation into the compaction of powders.

Authors:  D TRAIN
Journal:  J Pharm Pharmacol       Date:  1956-10       Impact factor: 3.765

3.  Effect of compression on non-isothermal crystallization behaviour of amorphous indomethacin.

Authors:  Zelalem Ayenew; Amrit Paudel; Patrick Rombaut; Guy Van den Mooter
Journal:  Pharm Res       Date:  2012-05-26       Impact factor: 4.200

4.  Is a distinctive single Tg a reliable indicator for the homogeneity of amorphous solid dispersion?

Authors:  Feng Qian; Jun Huang; Qing Zhu; Raja Haddadin; John Gawel; Robert Garmise; Munir Hussain
Journal:  Int J Pharm       Date:  2010-05-24       Impact factor: 5.875

Review 5.  Compression physics in the formulation development of tablets.

Authors:  Sarsvatkumar Patel; Aditya Mohan Kaushal; Arvind Kumar Bansal
Journal:  Crit Rev Ther Drug Carrier Syst       Date:  2006       Impact factor: 4.889

6.  Direct measurement of molecular mobility in actively deformed polymer glasses.

Authors:  Hau-Nan Lee; Keewook Paeng; Stephen F Swallen; M D Ediger
Journal:  Science       Date:  2008-11-27       Impact factor: 47.728

Review 7.  Oral formulation strategies to improve solubility of poorly water-soluble drugs.

Authors:  Abhishek Singh; Zelalem Ayenew Worku; Guy Van den Mooter
Journal:  Expert Opin Drug Deliv       Date:  2011-08-03       Impact factor: 6.648

8.  Can compression induce demixing in amorphous solid dispersions? A case study of naproxen-PVP K25.

Authors:  Zelalem Ayenew; Amrit Paudel; Guy Van den Mooter
Journal:  Eur J Pharm Biopharm       Date:  2012-01-24       Impact factor: 5.571

9.  The potential of small-scale fusion experiments and the Gordon-Taylor equation to predict the suitability of drug/polymer blends for melt extrusion.

Authors:  A Forster; J Hempenstall; T Rades
Journal:  Drug Dev Ind Pharm       Date:  2001-07       Impact factor: 3.225

10.  Estimation of drug-polymer miscibility and solubility in amorphous solid dispersions using experimentally determined interaction parameters.

Authors:  Patrick J Marsac; Tonglei Li; Lynne S Taylor
Journal:  Pharm Res       Date:  2008-09-09       Impact factor: 4.200

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  1 in total

1.  The effects of polymer carrier, hot melt extrusion process and downstream processing parameters on the moisture sorption properties of amorphous solid dispersions.

Authors:  Xin Feng; Anh Vo; Hemlata Patil; Roshan V Tiwari; Abdullah S Alshetaili; Manjeet B Pimparade; Michael A Repka
Journal:  J Pharm Pharmacol       Date:  2015-11-21       Impact factor: 3.765

  1 in total

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