Literature DB >> 24844447

Phosphine catalyzed reduction of CO2 with boranes.

Tongen Wang1, Douglas W Stephan.   

Abstract

Phosphine is shown to catalyse the reaction of CO2 with 9-BBN to give mixtures of HCO2(B(C8H14)) 3, H2C(OB(C8H14))24 and MeOB(C8H14) 5; at 0.02 mol% of tBu3P 5 is obtained in 98% yield at 60 °C with TON of almost 5500 and a TOF of 170. Under stoichiometric conditions the species (R3PCH2O)(HC(O)O)B(C8H14) (R = tBu 1,4-MeC6H42) were isolated and characterized.

Entities:  

Year:  2014        PMID： 24844447     DOI： 10.1039/c4cc02103g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  9 in total

1.  Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

Authors:  Lingyu Liu; Siu-Kwan Lo; Cory Smith; Jose M Goicoechea
Journal:  Chemistry       Date:  2021-10-27       Impact factor: 5.020

2.  Quantifying the efficiency of CO2 capture by Lewis pairs.

Authors:  Jay J Chi; Timothy C Johnstone; Dan Voicu; Paul Mehlmann; Fabian Dielmann; Eugenia Kumacheva; Douglas W Stephan
Journal:  Chem Sci       Date:  2017-02-20       Impact factor: 9.825

3.  Transforming atmospheric CO2 into alternative fuels: a metal-free approach under ambient conditions.

Authors:  Samaresh Chandra Sau; Rameswar Bhattacharjee; Pradip Kumar Hota; Pavan K Vardhanapu; Gonela Vijaykumar; R Govindarajan; Ayan Datta; Swadhin K Mandal
Journal:  Chem Sci       Date:  2018-11-30       Impact factor: 9.825

4.  Double Phosphinoboration of CO2 : A Facile Route to Diphospha-Ureas.

Authors:  James H W LaFortune; Zheng-Wang Qu; Karlee L Bamford; Alina Trofimova; Stephen A Westcott; Douglas W Stephan
Journal:  Chemistry       Date:  2019-08-23       Impact factor: 5.236

5.  Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2.

Authors:  Natalia Szynkiewicz; Anna Ordyszewska; Jarosław Chojnacki; Rafał Grubba
Journal:  RSC Adv       Date:  2019-09-03       Impact factor: 4.036

Review 6.  From CO2 activation to catalytic reduction: a metal-free approach.

Authors:  Sreejyothi P; Swadhin K Mandal
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.825

7.  Metal-free disproportionation of formic acid mediated by organoboranes.

Authors:  Clément Chauvier; Pierre Thuéry; Thibault Cantat
Journal:  Chem Sci       Date:  2016-05-19       Impact factor: 9.825

8.  Two tris-(3,5-disubstituted phen-yl)phosphines and their isostructural PV oxides.

Authors:  Nathan D D Hill; René T Boeré
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-06-05

9.  Catalytic CO2 Reduction with Boron- and Aluminum Hydrides.

Authors:  Daniel Franz; Christian Jandl; Claire Stark; Shigeyoshi Inoue
Journal:  ChemCatChem       Date:  2019-09-30       Impact factor: 5.686
  9 in total

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