Literature DB >> 24837070

High-yield, regiospecific bis-functionalization of C₇₀ using a Diels-Alder reaction in molten anthracene.

Venkata S Pavan K Neti1, Maira R Cerón, A Duarte-Ruiz, Marilyn M Olmstead, Alan L Balch, Luis Echegoyen.   

Abstract

A regiospecific bis-adduct of C70 with anthracene was prepared with unusually high yield (68%) by the Diels-Alder reaction in the absence of solvent (melt). The structure of the bis-adduct was an unexpected 12 o'clock isomer, as determined by single crystal X-ray diffraction, thermal gravimetric analysis (TGA) and spectroscopy.

Entities:  

Year:  2014        PMID: 24837070     DOI: 10.1039/c4cc02472a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Highly Regioselective Synthesis of Bisadduct[C70] Additive toward the Enhanced Performance of Perovskite Solar Cells.

Authors:  Muqing Chen; Yanyan Zeng; Gui Chen; Yongfu Qiu
Journal:  Nanomaterials (Basel)       Date:  2022-07-09       Impact factor: 5.719

  1 in total

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