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Literature DB >> 24835499

Infrared spectra and structures of anionic complexes of cobalt with carbon dioxide ligands.

Abstract

We present infrared photodissociation spectra of [Co(CO2)n](-) ions (n = 3-11) in the wavenumber region 1000-2400 cm(-1), interpreted with the aid of density functional theory calculations. The spectra are dominated by the signatures of a core ion showing bidentate interaction of two CO2 ligands with the Co atom, each forming C-Co and O-Co bonds. This structural motif is very robust and is only weakly affected by solvation with additional CO2 solvent molecules. The Co atom is in oxidation state +1, and both CO2 ligands carry a negative charge.

Entities: Chemical Gene

Year: 2014 PMID： 24835499 DOI： 10.1021/jp503194v

Source DB: PubMed Journal: J Phys Chem A ISSN： 1089-5639 Impact factor: 2.781

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Cited

4 in total

1. Carbon-carbon bond formation in the reaction of hydrated carbon dioxide radical anions with 3-butyn-1-ol.

Authors: Andreas Herburger; Milan Ončák; Erik Barwa; Christian van der Linde; Martin K Beyer
Journal: Int J Mass Spectrom Date: 2018-10-12 Impact factor: 1.986

2. Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg ^.+ to CO₂ in [MgCO₂ (H₂ O)_n ]^.+ , n=0-8.

Authors: Erik Barwa; Tobias F Pascher; Milan Ončák; Christian van der Linde; Martin K Beyer
Journal: Angew Chem Int Ed Engl Date: 2020-03-12 Impact factor: 15.336

3. Infrared Spectroscopy of Size-Selected Hydrated Carbon Dioxide Radical Anions CO₂ ^.- (H₂ O)_n (n=2-61) in the C-O Stretch Region.

Authors: Andreas Herburger; Milan Ončák; Chi-Kit Siu; Ephrem G Demissie; Jakob Heller; Wai Kit Tang; Martin K Beyer
Journal: Chemistry Date: 2019-07-01 Impact factor: 5.236

4. Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO₂ (H₂ O)_n ^- , n=1-10, in the C-O Stretch Region.

Authors: Erik Barwa; Milan Ončák; Tobias F Pascher; Andreas Herburger; Christian van der Linde; Martin K Beyer
Journal: Chemistry Date: 2020-01-16 Impact factor: 5.236

4 in total

Infrared spectra and structures of anionic complexes of cobalt with carbon dioxide ligands.

1. Carbon-carbon bond formation in the reaction of hydrated carbon dioxide radical anions with 3-butyn-1-ol.

2. Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg .+ to CO2 in [MgCO2 (H2 O)n ].+ , n=0-8.

3. Infrared Spectroscopy of Size-Selected Hydrated Carbon Dioxide Radical Anions CO2 .- (H2 O)n (n=2-61) in the C-O Stretch Region.

4. Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO2 (H2 O)n - , n=1-10, in the C-O Stretch Region.

2. Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg ^.+ to CO₂ in [MgCO₂ (H₂ O)_n ]^.+ , n=0-8.

3. Infrared Spectroscopy of Size-Selected Hydrated Carbon Dioxide Radical Anions CO₂ ^.- (H₂ O)_n (n=2-61) in the C-O Stretch Region.

4. Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO₂ (H₂ O)_n ^- , n=1-10, in the C-O Stretch Region.