Literature DB >> 24827449

Hypervalent iodine: a powerful electrophile for asymmetric α-functionalization of carbonyl compounds.

Dao-Qing Dong1, Shuang-Hong Hao, Zu-Li Wang, Chao Chen.   

Abstract

Environmentally friendly hypervalent iodine reagents are unusually effective promoters of asymmetric α-functionalization of carbonyl compounds. By using hypervalent iodine reagents, various substituents can be introduced into the α-position of carbonyl compounds. In the present review, we briefly survey the asymmetric α-functionalization of carbonyl compound reactions catalyzed by these hypervalent iodine reagents.

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Year:  2014        PMID： 24827449     DOI： 10.1039/c4ob00318g

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  9 in total

1.  Sulfur(iv)-mediated umpolung α-heterofunctionalization of 2-oxazolines.

Authors:  Qifeng Zhang; Yuchen Liang; Ruiqi Li; Ziyi Huang; Lichun Kong; Peng Du; Bo Peng
Journal:  Chem Sci       Date:  2022-04-09       Impact factor: 9.969

2.  Towards an asymmetric organocatalytic α-cyanation of β-ketoesters.

Authors:  Raghunath Chowdhury; Johannes Schörgenhumer; Johanna Novacek; Mario Waser
Journal:  Tetrahedron Lett       Date:  2015-04-01       Impact factor: 2.415

Review 3.  A survey of chiral hypervalent iodine reagents in asymmetric synthesis.

Authors:  Soumen Ghosh; Suman Pradhan; Indranil Chatterjee
Journal:  Beilstein J Org Chem       Date:  2018-05-30       Impact factor: 2.883

Review 4.  IBX-Mediated Organic Transformations in Heterocyclic Chemistry-A Decade Update.

Authors:  Yadavalli Venkata Durga Nageswar; Katla Ramesh; Katla Rakhi
Journal:  Front Chem       Date:  2022-02-28       Impact factor: 5.221

Review 5.  Palladium-Catalyzed Organic Reactions Involving Hypervalent Iodine Reagents.

Authors:  Samata E Shetgaonkar; Ritu Mamgain; Kotaro Kikushima; Toshifumi Dohi; Fateh V Singh
Journal:  Molecules       Date:  2022-06-17       Impact factor: 4.927

Review 6.  Recent discoveries on the structure of iodine(iii) reagents and their use in cross-nucleophile coupling.

Authors:  Adriano Bauer; Nuno Maulide
Journal:  Chem Sci       Date:  2021-01-07       Impact factor: 9.825

7.  Enantioselective Oxidative Rearrangements with Chiral Hypervalent Iodine Reagents.

Authors:  Michael Brown; Ravi Kumar; Julia Rehbein; Thomas Wirth
Journal:  Chemistry       Date:  2016-01-21       Impact factor: 5.236

8.  Hypervalent Iodine(III)-Catalysed Enantioselective α-Acetoxylation of Ketones.

Authors:  Tobias Hokamp; Thomas Wirth
Journal:  Chemistry       Date:  2020-07-20       Impact factor: 5.236

9.  An umpolung strategy to react catalytic enols with nucleophiles.

Authors:  Amparo Sanz-Marco; Samuel Martinez-Erro; Martin Pauze; Enrique Gómez-Bengoa; Belén Martín-Matute
Journal:  Nat Commun       Date:  2019-11-20       Impact factor: 14.919
  9 in total

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