Literature DB >> 24827003

Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes.

Luke J Batchelor1, Irene Cimatti, Régis Guillot, Floriana Tuna, Wolfgang Wernsdorfer, Liviu Ungur, Liviu F Chibotaru, Victoria E Campbell, Talal Mallah.   

Abstract

A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations.

Year:  2014        PMID: 24827003     DOI: 10.1039/c4dt00846d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Crystal structures of two isotypic lanthanide(III) complexes: tri-aqua-[2,6-di-acetyl-pyridine bis-(benzoyl-hydrazone)]methano-llanthanide(III) trichloride methanol disolvates (LnIII = Tb and Dy).

Authors:  Chihiro Kachi-Terajima; Norihisa Kimura
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-03-16
  1 in total

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