Literature DB >> 24826904

Ascorbate as an electron relay between an irreversible electron donor and Ru(II) or Re(I) photosensitizers.

Cyril Bachmann1, Benjamin Probst, Miguel Guttentag, Roger Alberto.   

Abstract

Ascorbate acts as a reversible electron shuttle between tris(2-carboxyethyl) phosphine (TCEP) and Re(I) or Ru(II) photosensitizers. Oxidized ascorbate is recycled up to 50 times by the TCEP → TCEP[double bond, length as m-dash]O redox process which enables 30 000 TONs per WRC in photocatalytic hydrogen production, thus exceeding the performance with pure ascorbate by far.

Entities:  

Year:  2014        PMID： 24826904     DOI： 10.1039/c4cc01500b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.

Authors:  Kristian E Dalle; Julien Warnan; Jane J Leung; Bertrand Reuillard; Isabell S Karmel; Erwin Reisner
Journal:  Chem Rev       Date:  2019-02-15       Impact factor: 60.622

2.  Recent Developments in Hydrogen Evolving Molecular Cobalt(II)-Polypyridyl Catalysts.

Authors:  N Queyriaux; R T Jane; J Massin; V Artero; M Chavarot-Kerlidou
Journal:  Coord Chem Rev       Date:  2015-12-01       Impact factor: 22.315

3.  Understanding light-driven H2 evolution through the electronic tuning of aminopyridine cobalt complexes.

Authors:  Arnau Call; Federico Franco; Noufal Kandoth; Sergio Fernández; María González-Béjar; Julia Pérez-Prieto; Josep M Luis; Julio Lloret-Fillol
Journal:  Chem Sci       Date:  2017-12-19       Impact factor: 9.825

4.  Electrochemical Properties of a Rhodium(III) Mono-Terpyridyl Complex and Use as a Catalyst for Light-Driven Hydrogen Evolution in Water.

Authors:  Fakourou Camara; Thomas Gavaggio; Baptiste Dautreppe; Jérôme Chauvin; Jacques Pécaut; Dmitry Aldakov; Marie-Noëlle Collomb; Jérôme Fortage
Journal:  Molecules       Date:  2022-10-05       Impact factor: 4.927

5.  Imidazolium-modification enhances photocatalytic CO2 reduction on ZnSe quantum dots.

Authors:  Constantin D Sahm; Eric Mates-Torres; Nora Eliasson; Kamil Sokołowski; Andreas Wagner; Kristian E Dalle; Zehuan Huang; Oren A Scherman; Leif Hammarström; Max García-Melchor; Erwin Reisner
Journal:  Chem Sci       Date:  2021-05-17       Impact factor: 9.825

6.  Photocatalytic proton reduction with ruthenium and cobalt complexes immobilized on fumed reversed-phase silica.

Authors:  C Bachmann; B Probst; M Oberholzer; T Fox; R Alberto
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

7.  Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation.

Authors:  Debashis Basu; Shivnath Mazumder; Jens Niklas; Habib Baydoun; Dakshika Wanniarachchi; Xuetao Shi; Richard J Staples; Oleg Poluektov; H Bernhard Schlegel; Cláudio N Verani
Journal:  Chem Sci       Date:  2016-02-02       Impact factor: 9.825
  7 in total

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