Bis[tris-(phenanthroline-κ(2) N,N')cobalt(II)] undeca-tungsto(VI)vanado(V)phosphate dihydrate.

In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co(2+) ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octa-hedron. Possible very weak intra-molecular C-H⋯π inter-actions occur in the cation. In the crystal, the components are linked by O-H⋯O and C-H⋯O inter-actions, building a three-dimensional network featuring one-dimensional voids along the c-axis direction.

Related literature

For related vanadium-substituted Keggin-ion structures, see: Glinskaya et al. (1989 ▶); Klevtsova et al. (1990 ▶, 1991 ▶); Li et al. (2008 ▶); Radkov & Beer (1995 ▶). For IR spectroscopy investigations of Keggin ions, see: Lee & Misono (1997 ▶); Deltcheff et al. (1983 ▶); Watras & Teplyakov (2005 ▶). For bond-valence calculations, see: Brown & Altermatt (1985 ▶). For background to polyoxidometalate chemistry, see: Pope & Müller (1991 ▶, 1994 ▶).

Experimental

Crystal data

[Co(C12H8N2)3][PVW11O40]·2H2O

M = 3979.38

Monoclinic,

a = 19.487 (2) Å

b = 18.049 (3) Å

c = 25.216 (2) Å

β = 100.22 (3)°

V = 8728.4 (18) Å3

Z = 4

Mo Kα radiation

μ = 15.02 mm−1

T = 295 K

0.13 × 0.08 × 0.04 mm

Data collection

Nonius KappaCCD diffractometer

Absorption correction: multi-scan (SORTAV; Blessing, 1995 ▶) T min = 0.202, T max = 0.421

62427 measured reflections

11235 independent reflections

8172 reflections with I > 2σ(I)

R int = 0.070

Refinement

R[F 2 > 2σ(F 2)] = 0.054

wR(F 2) = 0.095

S = 1.16

11235 reflections

688 parameters

3 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 1.39 e Å−3

Δρmin = −1.51 e Å−3

Data collection: COLLECT (Hooft, 1998 ▶); cell refinement: DIRAX/LSQ (Duisenberg et al., 2000 ▶); data reduction: EVALCCD (Duisenberg et al., 2003 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012 ▶) and DIAMOND (Brandenburg & Putz, 2005 ▶); software used to prepare material for publication: WinGX (Farrugia, 2012 ▶).

Crystal structure: contains datablock(s) I. DOI: 10.1107/S160053681400484X/hb7203sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681400484X/hb7203Isup2.hkl

CCDC reference: 989480

Additional supporting information: crystallographic information; 3D view; checkCIF report

[Co(C12H8N2)3][PVW11O40]·2H2O	F(000) = 7240
Mr = 3979.38	Dx = 3.028 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
a = 19.487 (2) Å	Cell parameters from 25 reflections
b = 18.049 (3) Å	θ = 9–11°
c = 25.216 (2) Å	µ = 15.02 mm−1
β = 100.22 (3)°	T = 295 K
V = 8728.4 (18) Å3	PRISM, yellow
Z = 4	0.13 × 0.08 × 0.04 mm

Nonius KappaCCD diffractometer	11235 independent reflections
Radiation source: fine-focus sealed tube	8172 reflections with I > 2σ(I)
Horizonally mounted graphite crystal monochromator	Rint = 0.070
Detector resolution: 9 pixels mm-1	θmax = 28.8°, θmin = 6.4°
CCD rotation images, thick slices scans	h = −26→25
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	k = −24→24
Tmin = 0.202, Tmax = 0.421	l = −34→32
62427 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.054	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.095	H atoms treated by a mixture of independent and constrained refinement
S = 1.16	w = 1/[σ2(Fo2) + 250.0304P] where P = (Fo2 + 2Fc2)/3
11235 reflections	(Δ/σ)max = 0.002
688 parameters	Δρmax = 1.39 e Å−3
3 restraints	Δρmin = −1.51 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
W1	0.90431 (2)	0.16939 (2)	0.468951 (18)	0.03506 (10)	0.91
V1	0.90431 (2)	0.16939 (2)	0.468951 (18)	0.03506 (10)	0.09
W2	0.91248 (2)	0.27877 (3)	0.587700 (17)	0.03574 (11)	0.91
V2	0.91248 (2)	0.27877 (3)	0.587700 (17)	0.03574 (11)	0.09
W3	0.83223 (2)	0.10207 (3)	0.579002 (19)	0.04092 (12)	0.92
V3	0.83223 (2)	0.10207 (3)	0.579002 (19)	0.04092 (12)	0.08
W4	0.82438 (2)	0.32068 (3)	0.391898 (18)	0.04283 (12)	0.92
V4	0.82438 (2)	0.32068 (3)	0.391898 (18)	0.04283 (12)	0.08
W5	0.67180 (3)	0.07254 (3)	0.48920 (2)	0.04756 (13)	0.92
V5	0.67180 (3)	0.07254 (3)	0.48920 (2)	0.04756 (13)	0.08
W6	0.74373 (3)	0.14331 (3)	0.380723 (19)	0.04799 (13)	0.92
V6	0.74373 (3)	0.14331 (3)	0.380723 (19)	0.04799 (13)	0.08
O1E	0.9773 (4)	0.1310 (5)	0.4547 (4)	0.072 (3)
O2E	0.9883 (4)	0.2925 (5)	0.6293 (3)	0.064 (2)
O3E	0.8718 (5)	0.0319 (5)	0.6152 (3)	0.066 (2)
O4E	0.8576 (4)	0.3557 (5)	0.3403 (3)	0.057 (2)
O5E	0.6360 (4)	−0.0117 (4)	0.4862 (3)	0.052 (2)
O6E	0.7424 (5)	0.0939 (5)	0.3244 (3)	0.069 (3)
O1	0.9412 (4)	0.2330 (4)	0.5277 (3)	0.051 (2)
O2	0.8823 (4)	0.1027 (4)	0.5215 (3)	0.053 (2)
O3	0.8945 (5)	0.2558 (5)	0.4245 (3)	0.073 (3)
O4	0.8351 (5)	0.1247 (5)	0.4175 (4)	0.079 (3)
O5	0.8869 (4)	0.1821 (4)	0.6090 (3)	0.053 (2)
O6A	0.8877 (8)	0.3591 (10)	0.5382 (7)	0.038 (4)	0.50
O6B	0.9132 (8)	0.3772 (9)	0.5575 (6)	0.030 (3)	0.50
O7	0.8556 (4)	0.3900 (6)	0.4469 (4)	0.081 (3)
O8	0.7761 (5)	0.2355 (5)	0.3599 (3)	0.072 (3)
O9A	0.8604 (7)	0.3245 (9)	0.6394 (6)	0.032 (3)	0.50
O9B	0.8340 (7)	0.3084 (10)	0.6198 (6)	0.035 (4)	0.50
O10	0.7634 (4)	0.1309 (7)	0.6194 (4)	0.086 (4)
O11A	0.7035 (10)	0.0633 (11)	0.4178 (7)	0.041 (4)	0.50
O11B	0.7226 (10)	0.0845 (10)	0.4384 (7)	0.038 (4)	0.50
O12	0.7599 (4)	0.0525 (6)	0.5323 (4)	0.081 (3)
P	0.7500	0.2500	0.5000	0.0229 (6)
O1C	0.7595 (6)	0.3206 (7)	0.4667 (4)	0.028 (3)	0.50
O3C	0.7921 (6)	0.2294 (7)	0.4564 (5)	0.028 (3)	0.50
O4C	0.8176 (6)	0.2148 (7)	0.5224 (4)	0.027 (3)	0.50
O2C	0.7968 (6)	0.3041 (7)	0.5406 (4)	0.028 (3)	0.50
O1W	1.0714 (7)	0.1131 (6)	0.3771 (6)	0.098 (4)
H1W1	1.033 (6)	0.115 (9)	0.388 (8)	0.147*
H2W1	1.092 (8)	0.071 (5)	0.380 (9)	0.147*
Co	0.80233 (7)	0.31178 (8)	0.15603 (5)	0.0367 (3)
N1	0.8600 (5)	0.2468 (6)	0.2151 (4)	0.051 (2)
N2	0.7596 (5)	0.2088 (5)	0.1326 (4)	0.047 (2)
N3	0.8759 (5)	0.3135 (5)	0.1070 (3)	0.041 (2)
N4	0.8545 (6)	0.4082 (6)	0.1827 (4)	0.054 (3)
N5	0.7316 (4)	0.3680 (5)	0.0981 (3)	0.0375 (19)
N6	0.7208 (4)	0.3243 (5)	0.1973 (3)	0.0365 (19)
C1	0.9090 (6)	0.2668 (9)	0.2556 (5)	0.064 (4)
H1	0.9240	0.3158	0.2573	0.077*
C2	0.9398 (8)	0.2178 (13)	0.2961 (6)	0.083 (5)
H2	0.9743	0.2340	0.3239	0.099*
C3	0.9184 (9)	0.1468 (12)	0.2937 (6)	0.085 (5)
H3	0.9379	0.1135	0.3203	0.102*
C4	0.8660 (7)	0.1226 (8)	0.2505 (5)	0.061 (3)
C5	0.8418 (9)	0.0467 (8)	0.2431 (6)	0.075 (4)
H5	0.8620	0.0104	0.2671	0.089*
C6	0.7912 (9)	0.0282 (8)	0.2025 (6)	0.073 (4)
H6	0.7755	−0.0205	0.1995	0.088*
C7	0.7601 (7)	0.0823 (7)	0.1630 (5)	0.060 (3)
C8	0.7059 (8)	0.0667 (8)	0.1192 (6)	0.070 (4)
H8	0.6881	0.0190	0.1136	0.084*
C9	0.6808 (8)	0.1224 (9)	0.0859 (6)	0.072 (4)
H9	0.6444	0.1135	0.0574	0.086*
C10	0.7080 (7)	0.1908 (8)	0.0936 (5)	0.060 (3)
H10	0.6891	0.2279	0.0698	0.072*
C11	0.7863 (6)	0.1554 (6)	0.1681 (4)	0.046 (3)
C12	0.8393 (6)	0.1741 (8)	0.2123 (5)	0.054 (3)
C13	0.8843 (6)	0.2656 (7)	0.0680 (5)	0.052 (3)
H13	0.8576	0.2226	0.0639	0.062*
C14	0.9317 (6)	0.2776 (8)	0.0331 (5)	0.059 (3)
H14	0.9351	0.2440	0.0057	0.071*
C15	0.9731 (6)	0.3399 (7)	0.0398 (5)	0.058 (3)
H15	1.0055	0.3478	0.0174	0.069*
C16	0.9669 (6)	0.3917 (7)	0.0805 (5)	0.051 (3)
C17	1.0060 (6)	0.4588 (7)	0.0903 (6)	0.060 (3)
H17	1.0397	0.4700	0.0696	0.072*
C18	0.9948 (6)	0.5058 (7)	0.1291 (6)	0.064 (4)
H18	1.0210	0.5491	0.1347	0.077*
C19	0.9437 (6)	0.4915 (7)	0.1621 (5)	0.057 (3)
C20	0.9284 (8)	0.5398 (8)	0.2027 (6)	0.066 (4)
H20	0.9512	0.5851	0.2089	0.079*
C21	0.8798 (9)	0.5191 (8)	0.2324 (6)	0.073 (4)
H21	0.8715	0.5488	0.2607	0.087*
C22	0.8431 (8)	0.4549 (7)	0.2207 (5)	0.063 (4)
H22	0.8084	0.4435	0.2403	0.076*
C23	0.9041 (6)	0.4266 (6)	0.1535 (4)	0.046 (3)
C24	0.9158 (5)	0.3752 (6)	0.1129 (4)	0.043 (2)
C25	0.7358 (7)	0.3868 (7)	0.0480 (5)	0.057 (3)
H25	0.7775	0.3777	0.0361	0.068*
C26	0.6827 (7)	0.4185 (7)	0.0127 (5)	0.058 (3)
H26	0.6883	0.4298	−0.0222	0.069*
C27	0.6220 (7)	0.4333 (7)	0.0292 (5)	0.059 (3)
H27	0.5860	0.4561	0.0058	0.071*
C28	0.6129 (6)	0.4147 (6)	0.0813 (4)	0.044 (3)
C29	0.5491 (6)	0.4251 (8)	0.1015 (5)	0.063 (4)
H29	0.5109	0.4472	0.0800	0.076*
C30	0.5453 (6)	0.4023 (9)	0.1519 (6)	0.069 (4)
H30	0.5036	0.4096	0.1643	0.083*
C31	0.6020 (5)	0.3676 (8)	0.1873 (5)	0.054 (3)
C32	0.6007 (6)	0.3421 (9)	0.2395 (5)	0.067 (4)
H32	0.5605	0.3479	0.2541	0.080*
C33	0.6570 (6)	0.3094 (8)	0.2688 (5)	0.060 (3)
H33	0.6559	0.2934	0.3037	0.072*
C34	0.7170 (6)	0.2996 (7)	0.2464 (4)	0.049 (3)
H34	0.7552	0.2753	0.2662	0.058*
C35	0.6646 (5)	0.3573 (6)	0.1679 (4)	0.036 (2)
C36	0.6705 (5)	0.3812 (6)	0.1147 (4)	0.036 (2)

	U11	U22	U33	U12	U13	U23
W1	0.0286 (2)	0.0352 (2)	0.0414 (2)	0.00378 (18)	0.00621 (17)	−0.00271 (19)
V1	0.0286 (2)	0.0352 (2)	0.0414 (2)	0.00378 (18)	0.00621 (17)	−0.00271 (19)
W2	0.0295 (2)	0.0391 (2)	0.0366 (2)	0.00004 (18)	0.00030 (17)	0.00294 (18)
V2	0.0295 (2)	0.0391 (2)	0.0366 (2)	0.00004 (18)	0.00030 (17)	0.00294 (18)
W3	0.0345 (2)	0.0374 (3)	0.0478 (3)	0.00344 (19)	−0.00085 (19)	0.0026 (2)
V3	0.0345 (2)	0.0374 (3)	0.0478 (3)	0.00344 (19)	−0.00085 (19)	0.0026 (2)
W4	0.0409 (3)	0.0558 (3)	0.0327 (2)	−0.0115 (2)	0.00890 (19)	0.0005 (2)
V4	0.0409 (3)	0.0558 (3)	0.0327 (2)	−0.0115 (2)	0.00890 (19)	0.0005 (2)
W5	0.0452 (3)	0.0292 (2)	0.0711 (3)	−0.0081 (2)	0.0181 (2)	−0.0074 (2)
V5	0.0452 (3)	0.0292 (2)	0.0711 (3)	−0.0081 (2)	0.0181 (2)	−0.0074 (2)
W6	0.0643 (3)	0.0444 (3)	0.0366 (2)	−0.0025 (2)	0.0124 (2)	−0.0138 (2)
V6	0.0643 (3)	0.0444 (3)	0.0366 (2)	−0.0025 (2)	0.0124 (2)	−0.0138 (2)
O1E	0.042 (5)	0.056 (5)	0.129 (8)	0.000 (4)	0.046 (5)	−0.017 (5)
O2E	0.047 (5)	0.093 (7)	0.044 (4)	−0.032 (5)	−0.013 (4)	−0.003 (4)
O3E	0.094 (7)	0.044 (5)	0.062 (5)	0.022 (5)	0.021 (5)	0.014 (4)
O4E	0.046 (4)	0.082 (6)	0.042 (4)	−0.008 (4)	0.010 (4)	0.019 (4)
O5E	0.042 (4)	0.029 (4)	0.079 (6)	−0.007 (3)	−0.003 (4)	−0.001 (4)
O6E	0.071 (6)	0.080 (7)	0.055 (5)	−0.003 (5)	0.005 (4)	−0.041 (5)
O1	0.077 (5)	0.044 (4)	0.034 (4)	−0.018 (4)	0.017 (4)	−0.006 (3)
O2	0.079 (6)	0.042 (4)	0.041 (4)	−0.023 (4)	0.021 (4)	−0.011 (3)
O3	0.084 (6)	0.053 (5)	0.062 (5)	−0.022 (5)	−0.038 (5)	0.019 (4)
O4	0.097 (7)	0.047 (5)	0.072 (6)	−0.027 (5)	−0.045 (5)	0.011 (4)
O5	0.077 (6)	0.043 (4)	0.043 (4)	−0.024 (4)	0.021 (4)	−0.004 (3)
O6A	0.024 (9)	0.051 (11)	0.039 (10)	−0.005 (7)	0.003 (7)	0.003 (8)
O6B	0.028 (9)	0.032 (9)	0.028 (9)	0.005 (7)	−0.002 (6)	0.006 (6)
O7	0.029 (4)	0.124 (9)	0.091 (7)	−0.010 (5)	0.010 (4)	−0.070 (6)
O8	0.081 (6)	0.050 (5)	0.066 (5)	−0.024 (5)	−0.039 (5)	0.019 (4)
O9A	0.019 (8)	0.043 (9)	0.031 (8)	0.003 (7)	−0.006 (6)	0.003 (7)
O9B	0.009 (7)	0.063 (11)	0.028 (8)	−0.004 (7)	−0.007 (5)	−0.003 (7)
O10	0.027 (4)	0.137 (9)	0.092 (7)	−0.007 (5)	0.008 (4)	−0.070 (7)
O11A	0.041 (10)	0.039 (11)	0.044 (12)	0.000 (8)	0.009 (8)	−0.012 (8)
O11B	0.044 (11)	0.045 (11)	0.029 (9)	0.006 (8)	0.019 (8)	−0.010 (7)
O12	0.033 (4)	0.112 (8)	0.095 (7)	−0.008 (5)	0.004 (4)	−0.068 (6)
P	0.0258 (15)	0.0167 (14)	0.0257 (15)	−0.0004 (12)	0.0030 (12)	−0.0015 (12)
O1C	0.027 (6)	0.031 (7)	0.022 (6)	0.001 (5)	−0.003 (5)	0.005 (5)
O3C	0.026 (6)	0.030 (7)	0.030 (6)	0.005 (5)	0.010 (5)	−0.004 (5)
O4C	0.020 (6)	0.038 (7)	0.025 (6)	0.000 (5)	0.008 (5)	−0.001 (5)
O2C	0.025 (6)	0.031 (7)	0.022 (6)	−0.009 (5)	−0.010 (5)	−0.006 (5)
O1W	0.109 (10)	0.069 (7)	0.129 (10)	0.024 (7)	0.057 (8)	0.007 (7)
Co	0.0363 (7)	0.0382 (8)	0.0355 (7)	0.0024 (6)	0.0067 (6)	0.0015 (6)
N1	0.036 (5)	0.074 (7)	0.045 (5)	0.006 (5)	0.013 (4)	−0.004 (5)
N2	0.047 (5)	0.048 (6)	0.048 (5)	0.002 (4)	0.014 (4)	0.000 (4)
N3	0.047 (5)	0.034 (5)	0.041 (5)	0.007 (4)	0.002 (4)	0.000 (4)
N4	0.070 (7)	0.051 (6)	0.039 (5)	0.017 (5)	0.009 (5)	−0.001 (4)
N5	0.041 (5)	0.036 (5)	0.035 (4)	−0.004 (4)	0.005 (4)	0.006 (4)
N6	0.035 (4)	0.043 (5)	0.030 (4)	0.006 (4)	0.000 (3)	−0.005 (4)
C1	0.048 (7)	0.091 (11)	0.056 (8)	0.008 (7)	0.017 (6)	0.000 (7)
C2	0.051 (8)	0.139 (17)	0.058 (9)	0.012 (10)	0.007 (7)	−0.007 (10)
C3	0.076 (11)	0.114 (15)	0.067 (10)	0.040 (11)	0.020 (8)	0.025 (10)
C4	0.070 (9)	0.067 (9)	0.048 (7)	0.029 (7)	0.017 (6)	0.013 (6)
C5	0.103 (12)	0.060 (9)	0.069 (9)	0.040 (9)	0.040 (9)	0.019 (7)
C6	0.099 (12)	0.052 (8)	0.078 (10)	0.022 (8)	0.042 (9)	0.000 (7)
C7	0.077 (9)	0.049 (7)	0.064 (8)	0.008 (7)	0.038 (7)	−0.007 (6)
C8	0.082 (10)	0.057 (9)	0.079 (10)	−0.015 (8)	0.037 (8)	−0.028 (8)
C9	0.080 (10)	0.081 (11)	0.053 (8)	−0.001 (8)	0.006 (7)	−0.028 (8)
C10	0.060 (8)	0.069 (9)	0.050 (7)	−0.020 (7)	0.007 (6)	−0.018 (6)
C11	0.054 (7)	0.045 (7)	0.044 (6)	0.008 (5)	0.023 (5)	0.002 (5)
C12	0.049 (7)	0.068 (9)	0.049 (7)	0.010 (6)	0.020 (6)	0.007 (6)
C13	0.053 (7)	0.041 (7)	0.062 (7)	0.007 (5)	0.013 (6)	−0.005 (6)
C14	0.044 (7)	0.064 (8)	0.068 (8)	0.020 (6)	0.005 (6)	−0.017 (7)
C15	0.041 (6)	0.064 (8)	0.066 (8)	0.017 (6)	0.007 (6)	−0.010 (7)
C16	0.040 (6)	0.054 (7)	0.058 (7)	0.018 (6)	0.005 (5)	0.012 (6)
C17	0.038 (6)	0.048 (7)	0.093 (10)	0.011 (6)	0.009 (6)	0.003 (7)
C18	0.040 (7)	0.043 (7)	0.102 (11)	0.006 (6)	−0.006 (7)	0.015 (7)
C19	0.048 (7)	0.044 (7)	0.070 (8)	0.012 (6)	−0.014 (6)	0.004 (6)
C20	0.065 (9)	0.054 (8)	0.068 (9)	0.010 (7)	−0.022 (7)	0.000 (7)
C21	0.097 (12)	0.055 (9)	0.057 (8)	0.024 (8)	−0.012 (8)	−0.012 (7)
C22	0.085 (10)	0.049 (8)	0.055 (7)	0.017 (7)	0.009 (7)	−0.006 (6)
C23	0.044 (6)	0.045 (6)	0.043 (6)	0.011 (5)	−0.005 (5)	0.005 (5)
C24	0.032 (5)	0.040 (6)	0.053 (6)	0.007 (5)	−0.005 (5)	−0.006 (5)
C25	0.068 (8)	0.059 (8)	0.044 (6)	−0.004 (7)	0.014 (6)	0.007 (6)
C26	0.068 (8)	0.057 (8)	0.046 (7)	0.004 (6)	0.005 (6)	0.029 (6)
C27	0.058 (8)	0.049 (7)	0.060 (8)	−0.010 (6)	−0.014 (6)	0.024 (6)
C28	0.044 (6)	0.038 (6)	0.044 (6)	−0.010 (5)	−0.010 (5)	0.001 (5)
C29	0.032 (6)	0.083 (10)	0.068 (8)	0.004 (6)	−0.010 (6)	0.013 (7)
C30	0.030 (6)	0.104 (12)	0.069 (9)	0.016 (7)	−0.001 (6)	−0.006 (8)
C31	0.030 (5)	0.085 (9)	0.047 (6)	−0.006 (6)	0.010 (5)	−0.012 (6)
C32	0.037 (6)	0.116 (12)	0.050 (7)	0.001 (7)	0.015 (6)	−0.005 (7)
C33	0.052 (7)	0.093 (10)	0.036 (6)	−0.010 (7)	0.010 (5)	0.006 (6)
C34	0.044 (6)	0.069 (8)	0.031 (5)	0.001 (6)	0.005 (5)	0.001 (5)
C35	0.032 (5)	0.037 (5)	0.038 (5)	−0.002 (4)	0.002 (4)	0.002 (4)
C36	0.030 (5)	0.035 (5)	0.041 (5)	−0.010 (4)	−0.004 (4)	−0.002 (4)

W1—O1E	1.677 (7)	N2—C11	1.355 (14)
W1—O4	1.880 (8)	N3—C13	1.342 (13)
W1—O2	1.895 (7)	N3—C24	1.350 (13)
W1—O3	1.909 (8)	N4—C22	1.325 (14)
W1—O1	1.912 (7)	N4—C23	1.357 (15)
W1—O4C	2.481 (11)	N5—C25	1.323 (13)
W2—O2E	1.672 (7)	N5—C36	1.352 (12)
W2—O1	1.893 (7)	N6—C34	1.328 (13)
W2—O5	1.917 (7)	N6—C35	1.348 (12)
W2—O6A	1.917 (18)	C1—C2	1.40 (2)
W2—O9A	1.971 (15)	C1—H1	0.9300
W2—O4C	2.526 (12)	C2—C3	1.35 (2)
W3—O3E	1.667 (8)	C2—H2	0.9300
W3—O5	1.873 (7)	C3—C4	1.42 (2)
W3—O2	1.886 (7)	C3—H3	0.9300
W3—O12	1.893 (8)	C4—C12	1.373 (17)
W3—O10	1.896 (8)	C4—C5	1.45 (2)
W3—O1Ci	2.396 (11)	C5—C6	1.33 (2)
W3—O4C	2.473 (12)	C5—H5	0.9300
W4—O4E	1.676 (7)	C6—C7	1.45 (2)
W4—O3	1.875 (9)	C6—H6	0.9300
W4—O7	1.887 (8)	C7—C11	1.412 (17)
W4—O10i	1.897 (9)	C7—C8	1.41 (2)
W4—O8	1.905 (8)	C8—C9	1.35 (2)
W4—O1C	2.451 (12)	C8—H8	0.9300
W5—O5E	1.669 (7)	C9—C10	1.344 (19)
W5—O6Ai	1.750 (18)	C9—H9	0.9300
W5—O12	1.897 (9)	C10—H10	0.9300
W5—O7i	1.908 (8)	C11—C12	1.421 (17)
W5—O11A	2.012 (19)	C13—C14	1.401 (17)
W5—O1Ci	2.494 (12)	C13—H13	0.9300
W6—O6E	1.673 (7)	C14—C15	1.376 (18)
W6—O4	1.885 (9)	C14—H14	0.9300
W6—O8	1.887 (8)	C15—C16	1.410 (17)
W6—O11A	1.96 (2)	C15—H15	0.9300
W6—O9Ai	2.085 (14)	C16—C24	1.426 (16)
O6A—W5i	1.750 (18)	C16—C17	1.429 (17)
O6B—V5i	2.064 (15)	C17—C18	1.342 (18)
O7—V5i	1.908 (8)	C17—H17	0.9300
O7—W5i	1.908 (8)	C18—C19	1.429 (19)
O9A—W6i	2.085 (14)	C18—H18	0.9300
O9B—V6i	1.746 (15)	C19—C23	1.397 (17)
O10—V4i	1.897 (9)	C19—C20	1.417 (19)
O10—W4i	1.897 (9)	C20—C21	1.36 (2)
P—O4C	1.481 (11)	C20—H20	0.9300
P—O4Ci	1.481 (11)	C21—C22	1.37 (2)
P—O3C	1.530 (11)	C21—H21	0.9300
P—O3Ci	1.530 (11)	C22—H22	0.9300
P—O1Ci	1.554 (12)	C23—C24	1.430 (15)
P—O1C	1.554 (12)	C25—C26	1.366 (16)
P—O2C	1.582 (11)	C25—H25	0.9300
P—O2Ci	1.582 (11)	C26—C27	1.347 (18)
O1C—O4Ci	1.698 (16)	C26—H26	0.9300
O1C—W3i	2.396 (11)	C27—C28	1.399 (16)
O1C—W5i	2.494 (12)	C27—H27	0.9300
O4C—O1Ci	1.698 (16)	C28—C36	1.413 (14)
O2C—V6i	2.453 (12)	C28—C29	1.436 (17)
O2C—V5i	2.462 (12)	C29—C30	1.351 (18)
O1W—H1W1	0.851 (10)	C29—H29	0.9300
O1W—H2W1	0.851 (10)	C30—C31	1.436 (17)
Co—N3	2.053 (9)	C30—H30	0.9300
Co—N6	2.060 (8)	C31—C32	1.398 (17)
Co—N1	2.066 (10)	C31—C35	1.406 (14)
Co—N4	2.066 (11)	C32—C33	1.346 (17)
Co—N2	2.078 (10)	C32—H32	0.9300
Co—N5	2.085 (8)	C33—C34	1.398 (16)
N1—C1	1.318 (16)	C33—H33	0.9300
N1—C12	1.369 (16)	C34—H34	0.9300
N2—C10	1.318 (14)	C35—C36	1.432 (14)
O1E—W1—O4	102.0 (5)	W3—O4C—W1	91.2 (4)
O1E—W1—O2	101.1 (4)	P—O4C—W2	123.5 (7)
O4—W1—O2	89.3 (4)	O1Ci—O4C—W2	129.3 (7)
O1E—W1—O3	102.3 (5)	W3—O4C—W2	90.2 (4)
O4—W1—O3	87.7 (3)	W1—O4C—W2	90.8 (4)
O2—W1—O3	156.6 (4)	P—O2C—V6i	122.1 (6)
O1E—W1—O1	101.4 (4)	P—O2C—V5i	120.4 (6)
O4—W1—O1	156.7 (4)	V6i—O2C—V5i	91.7 (4)
O2—W1—O1	86.5 (3)	H1W1—O1W—H2W1	116 (2)
O3—W1—O1	87.1 (3)	N3—Co—N6	170.4 (3)
O1E—W1—O4C	159.7 (5)	N3—Co—N1	95.4 (3)
O4—W1—O4C	92.4 (5)	N6—Co—N1	93.8 (3)
O2—W1—O4C	64.5 (4)	N3—Co—N4	80.0 (4)
O3—W1—O4C	92.4 (4)	N6—Co—N4	97.0 (4)
O1—W1—O4C	65.1 (4)	N1—Co—N4	94.0 (4)
O2E—W2—O1	102.2 (4)	N3—Co—N2	97.5 (3)
O2E—W2—O5	101.8 (4)	N6—Co—N2	86.3 (3)
O1—W2—O5	87.4 (3)	N1—Co—N2	80.6 (4)
O2E—W2—O6A	112.9 (6)	N4—Co—N2	173.9 (4)
O1—W2—O6A	83.5 (6)	N3—Co—N5	90.9 (3)
O5—W2—O6A	145.3 (6)	N6—Co—N5	80.1 (3)
O2E—W2—O9A	91.4 (5)	N1—Co—N5	171.6 (4)
O1—W2—O9A	166.4 (5)	N4—Co—N5	92.5 (4)
O5—W2—O9A	90.3 (5)	N2—Co—N5	93.1 (4)
O6A—W2—O9A	90.8 (7)	C1—N1—C12	117.9 (12)
O2E—W2—O4C	160.0 (4)	C1—N1—Co	129.0 (10)
O1—W2—O4C	64.3 (3)	C12—N1—Co	112.9 (8)
O5—W2—O4C	64.5 (4)	C10—N2—C11	118.0 (11)
O6A—W2—O4C	81.4 (6)	C10—N2—Co	130.3 (9)
O9A—W2—O4C	102.7 (5)	C11—N2—Co	111.2 (8)
O3E—W3—O5	100.9 (4)	C13—N3—C24	118.0 (10)
O3E—W3—O2	100.0 (4)	C13—N3—Co	128.4 (8)
O5—W3—O2	88.3 (3)	C24—N3—Co	113.4 (7)
O3E—W3—O12	101.7 (5)	C22—N4—C23	117.6 (12)
O5—W3—O12	157.3 (4)	C22—N4—Co	129.5 (10)
O2—W3—O12	87.4 (4)	C23—N4—Co	112.8 (7)
O3E—W3—O10	102.5 (5)	C25—N5—C36	117.2 (9)
O5—W3—O10	88.7 (4)	C25—N5—Co	130.4 (8)
O2—W3—O10	157.5 (5)	C36—N5—Co	112.2 (6)
O12—W3—O10	86.8 (4)	C34—N6—C35	119.1 (9)
O3E—W3—O1Ci	159.8 (4)	C34—N6—Co	127.5 (7)
O5—W3—O1Ci	93.8 (4)	C35—N6—Co	113.2 (6)
O2—W3—O1Ci	94.0 (4)	N1—C1—C2	123.2 (15)
O12—W3—O1Ci	64.3 (4)	N1—C1—H1	118.4
O10—W3—O1Ci	63.9 (5)	C2—C1—H1	118.4
O3E—W3—O4C	159.3 (4)	C3—C2—C1	118.6 (15)
O5—W3—O4C	66.2 (4)	C3—C2—H2	120.7
O2—W3—O4C	64.8 (4)	C1—C2—H2	120.7
O12—W3—O4C	91.9 (5)	C2—C3—C4	120.0 (15)
O10—W3—O4C	93.7 (5)	C2—C3—H3	120.0
O1Ci—W3—O4C	40.8 (4)	C4—C3—H3	120.0
O4E—W4—O3	103.0 (4)	C12—C4—C3	117.4 (14)
O4E—W4—O7	101.6 (5)	C12—C4—C5	118.4 (13)
O3—W4—O7	88.7 (4)	C3—C4—C5	124.1 (14)
O4E—W4—O10i	99.9 (5)	C6—C5—C4	121.0 (13)
O3—W4—O10i	157.1 (5)	C6—C5—H5	119.5
O7—W4—O10i	88.2 (4)	C4—C5—H5	119.5
O4E—W4—O8	101.9 (4)	C5—C6—C7	121.5 (15)
O3—W4—O8	87.0 (4)	C5—C6—H6	119.3
O7—W4—O8	156.5 (4)	C7—C6—H6	119.3
O10i—W4—O8	86.8 (4)	C11—C7—C8	117.7 (13)
O4E—W4—O1C	157.0 (4)	C11—C7—C6	117.8 (14)
O3—W4—O1C	95.6 (4)	C8—C7—C6	124.5 (14)
O7—W4—O1C	65.0 (4)	C9—C8—C7	118.6 (13)
O10i—W4—O1C	62.7 (4)	C9—C8—H8	120.7
O8—W4—O1C	92.4 (4)	C7—C8—H8	120.7
O5E—W5—O6Ai	112.5 (6)	C10—C9—C8	120.3 (14)
O5E—W5—O12	100.4 (4)	C10—C9—H9	119.9
O6Ai—W5—O12	146.1 (6)	C8—C9—H9	119.9
O5E—W5—O7i	100.6 (4)	N2—C10—C9	124.4 (14)
O6Ai—W5—O7i	79.6 (7)	N2—C10—H10	117.8
O12—W5—O7i	86.8 (4)	C9—C10—H10	117.8
O5E—W5—O11A	94.4 (6)	N2—C11—C7	121.0 (11)
O6Ai—W5—O11A	89.5 (8)	N2—C11—C12	119.3 (11)
O12—W5—O11A	96.1 (6)	C7—C11—C12	119.7 (12)
O7i—W5—O11A	164.0 (7)	N1—C12—C4	122.8 (12)
O5E—W5—O1Ci	155.8 (4)	N1—C12—C11	115.7 (11)
O6Ai—W5—O1Ci	84.0 (6)	C4—C12—C11	121.4 (13)
O12—W5—O1Ci	62.1 (4)	N3—C13—C14	122.7 (11)
O7i—W5—O1Ci	63.8 (4)	N3—C13—H13	118.6
O11A—W5—O1Ci	103.7 (6)	C14—C13—H13	118.6
O6E—W6—O4	101.1 (5)	C15—C14—C13	119.1 (12)
O6E—W6—O8	100.9 (5)	C15—C14—H14	120.4
O4—W6—O8	87.8 (4)	C13—C14—H14	120.4
O6E—W6—O11A	93.7 (6)	C14—C15—C16	120.5 (12)
O4—W6—O11A	93.3 (6)	C14—C15—H15	119.8
O8—W6—O11A	164.8 (6)	C16—C15—H15	119.8
O6E—W6—O9Ai	94.2 (5)	C15—C16—C24	115.9 (11)
O4—W6—O9Ai	164.3 (5)	C15—C16—C17	125.1 (12)
O8—W6—O9Ai	92.6 (5)	C24—C16—C17	119.0 (11)
O11A—W6—O9Ai	82.3 (7)	C18—C17—C16	120.7 (12)
W2—O1—W1	139.3 (4)	C18—C17—H17	119.7
W3—O2—W1	138.9 (5)	C16—C17—H17	119.7
W4—O3—W1	139.2 (6)	C17—C18—C19	122.0 (13)
W1—O4—W6	139.7 (6)	C17—C18—H18	119.0
W3—O5—W2	138.3 (4)	C19—C18—H18	119.0
W5i—O6A—W2	149.7 (10)	C23—C19—C20	116.5 (13)
W4—O7—V5i	138.9 (5)	C23—C19—C18	118.9 (12)
W4—O7—W5i	138.9 (5)	C20—C19—C18	124.5 (13)
V5i—O7—W5i	0.00 (3)	C21—C20—C19	119.0 (14)
W6—O8—W4	139.3 (5)	C21—C20—H20	120.5
W2—O9A—W6i	123.3 (7)	C19—C20—H20	120.5
W3—O10—V4i	138.7 (6)	C20—C21—C22	120.2 (14)
W3—O10—W4i	138.7 (6)	C20—C21—H21	119.9
V4i—O10—W4i	0.00 (3)	C22—C21—H21	119.9
W6—O11A—W5	125.4 (9)	N4—C22—C21	123.2 (14)
W3—O12—W5	139.9 (6)	N4—C22—H22	118.4
O4C—P—O4Ci	180.0 (8)	C21—C22—H22	118.4
O4C—P—O3C	67.4 (6)	N4—C23—C19	123.3 (11)
O4Ci—P—O3C	112.6 (6)	N4—C23—C24	116.6 (11)
O4C—P—O3Ci	112.6 (6)	C19—C23—C24	120.1 (11)
O4Ci—P—O3Ci	67.4 (6)	N3—C24—C16	123.8 (10)
O3C—P—O3Ci	180.000 (3)	N3—C24—C23	116.9 (10)
O4C—P—O1Ci	68.0 (6)	C16—C24—C23	119.3 (11)
O4Ci—P—O1Ci	112.0 (6)	N5—C25—C26	124.1 (12)
O3C—P—O1Ci	108.6 (6)	N5—C25—H25	117.9
O3Ci—P—O1Ci	71.4 (6)	C26—C25—H25	117.9
O4C—P—O1C	112.0 (6)	C27—C26—C25	119.2 (11)
O4Ci—P—O1C	68.0 (6)	C27—C26—H26	120.4
O3C—P—O1C	71.4 (6)	C25—C26—H26	120.4
O3Ci—P—O1C	108.6 (6)	C26—C27—C28	120.5 (11)
O1Ci—P—O1C	180.0 (7)	C26—C27—H27	119.8
O4C—P—O2C	69.2 (6)	C28—C27—H27	119.8
O4Ci—P—O2C	110.8 (6)	C27—C28—C36	116.3 (11)
O3C—P—O2C	107.1 (6)	C27—C28—C29	124.3 (11)
O3Ci—P—O2C	72.9 (6)	C36—C28—C29	119.4 (10)
O1Ci—P—O2C	105.5 (6)	C30—C29—C28	119.3 (11)
O1C—P—O2C	74.5 (6)	C30—C29—H29	120.4
O4C—P—O2Ci	110.8 (6)	C28—C29—H29	120.4
O4Ci—P—O2Ci	69.2 (6)	C29—C30—C31	123.6 (11)
O3C—P—O2Ci	72.9 (6)	C29—C30—H30	118.2
O3Ci—P—O2Ci	107.1 (6)	C31—C30—H30	118.2
O1Ci—P—O2Ci	74.5 (6)	C32—C31—C35	116.5 (11)
O1C—P—O2Ci	105.5 (6)	C32—C31—C30	126.1 (11)
O2C—P—O2Ci	180.0 (7)	C35—C31—C30	117.4 (11)
P—O1C—O4Ci	54.0 (6)	C33—C32—C31	120.8 (11)
P—O1C—W3i	126.0 (6)	C33—C32—H32	119.6
O4Ci—O1C—W3i	72.0 (6)	C31—C32—H32	119.6
P—O1C—W4	122.9 (7)	C32—C33—C34	119.5 (11)
O4Ci—O1C—W4	135.7 (7)	C32—C33—H33	120.2
W3i—O1C—W4	94.1 (4)	C34—C33—H33	120.2
P—O1C—W5i	120.0 (6)	N6—C34—C33	121.5 (11)
O4Ci—O1C—W5i	129.8 (7)	N6—C34—H34	119.2
W3i—O1C—W5i	93.4 (4)	C33—C34—H34	119.2
W4—O1C—W5i	91.9 (4)	N6—C35—C31	122.5 (9)
P—O4C—O1Ci	58.0 (5)	N6—C35—C36	117.2 (9)
P—O4C—W3	125.2 (6)	C31—C35—C36	120.3 (9)
O1Ci—O4C—W3	67.2 (5)	N5—C36—C28	122.7 (9)
P—O4C—W1	125.4 (6)	N5—C36—C35	117.3 (9)
O1Ci—O4C—W1	132.1 (7)	C28—C36—C35	119.9 (9)
N3—Co—N1—C1	83.6 (10)	Co—N1—C12—C4	−173.8 (9)
N6—Co—N1—C1	−94.0 (10)	C1—N1—C12—C11	179.9 (10)
N4—Co—N1—C1	3.3 (10)	Co—N1—C12—C11	4.1 (12)
N2—Co—N1—C1	−179.7 (10)	C3—C4—C12—N1	−1.5 (18)
N5—Co—N1—C1	−138 (2)	C5—C4—C12—N1	−178.5 (11)
N3—Co—N1—C12	−101.2 (7)	C3—C4—C12—C11	−179.3 (11)
N6—Co—N1—C12	81.2 (7)	C5—C4—C12—C11	3.8 (17)
N4—Co—N1—C12	178.5 (7)	N2—C11—C12—N1	−0.5 (15)
N2—Co—N1—C12	−4.5 (7)	C7—C11—C12—N1	−177.9 (10)
N5—Co—N1—C12	37 (3)	N2—C11—C12—C4	177.4 (10)
N3—Co—N2—C10	−89.4 (10)	C7—C11—C12—C4	0.0 (16)
N6—Co—N2—C10	81.8 (10)	C24—N3—C13—C14	−1.0 (16)
N1—Co—N2—C10	176.3 (10)	Co—N3—C13—C14	172.4 (9)
N4—Co—N2—C10	−155 (3)	N3—C13—C14—C15	2.1 (18)
N5—Co—N2—C10	1.9 (10)	C13—C14—C15—C16	−1.4 (18)
N3—Co—N2—C11	98.4 (7)	C14—C15—C16—C24	−0.2 (16)
N6—Co—N2—C11	−90.4 (7)	C14—C15—C16—C17	−178.5 (11)
N1—Co—N2—C11	4.1 (7)	C15—C16—C17—C18	177.9 (11)
N4—Co—N2—C11	33 (4)	C24—C16—C17—C18	−0.3 (17)
N5—Co—N2—C11	−170.3 (7)	C16—C17—C18—C19	−0.1 (19)
N6—Co—N3—C13	−105 (2)	C17—C18—C19—C23	−0.3 (18)
N1—Co—N3—C13	88.7 (10)	C17—C18—C19—C20	−178.3 (12)
N4—Co—N3—C13	−178.2 (10)	C23—C19—C20—C21	3.5 (17)
N2—Co—N3—C13	7.5 (10)	C18—C19—C20—C21	−178.4 (12)
N5—Co—N3—C13	−85.8 (9)	C19—C20—C21—C22	−4.4 (19)
N6—Co—N3—C24	68 (2)	C23—N4—C22—C21	−1.6 (18)
N1—Co—N3—C24	−97.7 (7)	Co—N4—C22—C21	−176.6 (10)
N4—Co—N3—C24	−4.5 (7)	C20—C21—C22—N4	4 (2)
N2—Co—N3—C24	−178.8 (7)	C22—N4—C23—C19	0.8 (16)
N5—Co—N3—C24	87.9 (7)	Co—N4—C23—C19	176.6 (8)
N3—Co—N4—C22	−180.0 (11)	C22—N4—C23—C24	179.7 (10)
N6—Co—N4—C22	9.2 (11)	Co—N4—C23—C24	−4.5 (12)
N1—Co—N4—C22	−85.2 (10)	C20—C19—C23—N4	−1.8 (16)
N2—Co—N4—C22	−113 (3)	C18—C19—C23—N4	−179.9 (10)
N5—Co—N4—C22	89.5 (10)	C20—C19—C23—C24	179.3 (10)
N3—Co—N4—C23	4.8 (7)	C18—C19—C23—C24	1.1 (16)
N6—Co—N4—C23	−166.0 (7)	C13—N3—C24—C16	−0.8 (15)
N1—Co—N4—C23	99.7 (8)	Co—N3—C24—C16	−175.2 (8)
N2—Co—N4—C23	71 (4)	C13—N3—C24—C23	177.9 (9)
N5—Co—N4—C23	−85.6 (8)	Co—N3—C24—C23	3.5 (11)
N3—Co—N5—C25	6.6 (10)	C15—C16—C24—N3	1.4 (16)
N6—Co—N5—C25	−176.6 (10)	C17—C16—C24—N3	179.8 (10)
N1—Co—N5—C25	−132 (2)	C15—C16—C24—C23	−177.3 (10)
N4—Co—N5—C25	86.7 (10)	C17—C16—C24—C23	1.1 (15)
N2—Co—N5—C25	−90.9 (10)	N4—C23—C24—N3	0.7 (14)
N3—Co—N5—C36	−179.0 (7)	C19—C23—C24—N3	179.7 (9)
N6—Co—N5—C36	−2.3 (7)	N4—C23—C24—C16	179.5 (9)
N1—Co—N5—C36	42 (3)	C19—C23—C24—C16	−1.5 (15)
N4—Co—N5—C36	−98.9 (7)	C36—N5—C25—C26	0.2 (17)
N2—Co—N5—C36	83.5 (7)	Co—N5—C25—C26	174.4 (9)
N3—Co—N6—C34	−162.2 (18)	N5—C25—C26—C27	1 (2)
N1—Co—N6—C34	3.7 (10)	C25—C26—C27—C28	−1.6 (19)
N4—Co—N6—C34	−90.8 (9)	C26—C27—C28—C36	0.9 (17)
N2—Co—N6—C34	84.0 (10)	C26—C27—C28—C29	−176.9 (13)
N5—Co—N6—C34	177.8 (10)	C27—C28—C29—C30	177.4 (13)
N3—Co—N6—C35	23 (2)	C36—C28—C29—C30	−0.4 (19)
N1—Co—N6—C35	−171.4 (7)	C28—C29—C30—C31	0 (2)
N4—Co—N6—C35	94.0 (7)	C29—C30—C31—C32	−179.1 (15)
N2—Co—N6—C35	−91.2 (7)	C29—C30—C31—C35	0 (2)
N5—Co—N6—C35	2.7 (7)	C35—C31—C32—C33	0 (2)
C12—N1—C1—C2	−1.2 (17)	C30—C31—C32—C33	179.1 (14)
Co—N1—C1—C2	173.8 (9)	C31—C32—C33—C34	−1 (2)
N1—C1—C2—C3	0 (2)	C35—N6—C34—C33	−2.3 (17)
C1—C2—C3—C4	0 (2)	Co—N6—C34—C33	−177.2 (9)
C2—C3—C4—C12	0 (2)	C32—C33—C34—N6	2 (2)
C2—C3—C4—C5	177.0 (14)	C34—N6—C35—C31	0.8 (16)
C12—C4—C5—C6	−5.0 (19)	Co—N6—C35—C31	176.4 (9)
C3—C4—C5—C6	178.3 (13)	C34—N6—C35—C36	−178.3 (9)
C4—C5—C6—C7	2 (2)	Co—N6—C35—C36	−2.7 (11)
C5—C6—C7—C11	1.5 (18)	C32—C31—C35—N6	0.5 (17)
C5—C6—C7—C8	−179.5 (13)	C30—C31—C35—N6	−178.9 (11)
C11—C7—C8—C9	−2.1 (18)	C32—C31—C35—C36	179.6 (11)
C6—C7—C8—C9	178.9 (12)	C30—C31—C35—C36	0.1 (17)
C7—C8—C9—C10	2 (2)	C25—N5—C36—C28	−1.0 (15)
C11—N2—C10—C9	−1.5 (18)	Co—N5—C36—C28	−176.1 (8)
Co—N2—C10—C9	−173.2 (10)	C25—N5—C36—C35	176.7 (10)
C8—C9—C10—N2	0 (2)	Co—N5—C36—C35	1.5 (11)
C10—N2—C11—C7	0.8 (15)	C27—C28—C36—N5	0.4 (15)
Co—N2—C11—C7	174.1 (8)	C29—C28—C36—N5	178.4 (10)
C10—N2—C11—C12	−176.5 (10)	C27—C28—C36—C35	−177.2 (10)
Co—N2—C11—C12	−3.3 (12)	C29—C28—C36—C35	0.7 (15)
C8—C7—C11—N2	0.9 (16)	N6—C35—C36—N5	0.8 (13)
C6—C7—C11—N2	180.0 (10)	C31—C35—C36—N5	−178.4 (10)
C8—C7—C11—C12	178.3 (10)	N6—C35—C36—C28	178.5 (9)
C6—C7—C11—C12	−2.7 (16)	C31—C35—C36—C28	−0.6 (15)
C1—N1—C12—C4	2.0 (16)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W1···O1E	0.85 (1)	2.17 (11)	2.928 (14)	149 (20)
O1W—H2W1···O3Eii	0.85 (1)	1.99 (3)	2.836 (13)	173 (17)
C9—H9···O5Eiii	0.93	2.55	3.208 (15)	128
C26—H26···O12iv	0.93	2.46	2.973 (15)	114
C33—H33···O5i	0.93	2.53	3.345 (13)	147
C34—H34···O8	0.93	2.43	3.114 (13)	130
C34—H34···Cg1	0.93	3.04	3.811 (12)	142
C25—H25···Cg2	0.93	2.99	3.777 (13)	143

Table 1

Selected bond lengths (Å)

Co—N3	2.053 (9)
Co—N6	2.060 (8)
Co—N1	2.066 (10)
Co—N4	2.066 (11)
Co—N2	2.078 (10)
Co—N5	2.085 (8)

Table 2

Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the N1/C1–C4/C12 and N3/C13–C16/C24 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1W1⋯O1E	0.85 (1)	2.17 (11)	2.928 (14)	149 (20)
O1W—H2W1⋯O3E i	0.85 (1)	1.99 (3)	2.836 (13)	173 (17)
C9—H9⋯O5E ii	0.93	2.55	3.208 (15)	128
C26—H26⋯O12iii	0.93	2.46	2.973 (15)	114
C33—H33⋯O5iv	0.93	2.53	3.345 (13)	147
C34—H34⋯O8	0.93	2.43	3.114 (13)	130
C34—H34⋯Cg1	0.93	3.04	3.811 (12)	142
C25—H25⋯Cg2	0.93	2.99	3.777 (13)	143

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .