Tetra-μ3-iodido-tetra-kis-[(tri-n-butyl-phosphane-κP)copper(I)].

The title complex, [Cu4I4(C12H27P)4], crystallizes with six mol-ecules in the unit cell and with three independent one-third mol-ecule fragments, completed by application of the relevant symmetry operators, in the asymmetric unit. The tetranuclear copper core shows a tetrahedral geometry (site symmetry 3..). The I atoms also form a tetra-hedron, with I⋯I distances of 4.471 (1) Å. Both tetra-hedra show an orientation similar to that of a pair of self-dual platonic bodies. The edges of the I-tetra-hedral structure are capped to the face centers of the Cu-tetra-hedron and vice versa. The Cuface⋯I distances are 2.18 Å (averaged) and the Iface⋯Cu distances are 0.78 Å (averaged). As a geometric consequence of these properties there are eight distorted trigonal-bipyramidal polyhedra evident, wherein each trigonal face builds up the equatorial site and the opposite Cu⋯I positions form the axial site. As expected, the n-butyl moieties are highly flexible, resulting in large elongations of their anisotropic displacement parameters. Some C atoms of the n-butyl groups were needed to fix alternative discrete disordered positions.

Related literature

For general background to this work, see: Ainscough et al. (2001 ▶); Alyea et al. (1985 ▶); Baker et al. (1994 ▶); Barron et al. (1984 ▶); Bowmaker et al. (1989 ▶, 1992 ▶, 1994 ▶ 1999 ▶, 2002 ▶); Churchill & Kalra (1973 ▶, 1974 ▶); Churchill, DeBoer & Donovan (1975 ▶); Churchill, DeBoer & Mendak (1975 ▶); Churchill & Rotella (1977 ▶, 1979 ▶); Dyason, Engelhardt et al. (1985 ▶); Dyason, Healy et al. (1985 ▶); Gill et al. (1976 ▶); Goel & Beauchamp (1983 ▶); Hadjikakou et al. (1993 ▶); Herberhold et al. (2003 ▶); Hermann et al. (2001 ▶); Jansen (1987 ▶); Krause (2002 ▶); Mann et al. (1936 ▶); Medina et al. (2005 ▶); Moers & Op Het Veld (1970 ▶); Ramaprabhu et al. (1993 ▶, 1998 ▶); Schwerdtfeger et al. (2004 ▶); Soloveichik et al. (1992 ▶); Wells (1936 ▶); Whitesides et al. (1971 ▶). The Cu⋯Cu distance is markably short as compared with the reported distances of other tetranuclear copper phosphane complexes (Medina et al., 2005 ▶). Nevertheless there are examples for tetra­meric copper complexes with a Cu⋯Cu distance shorter than 2.700 Å (Blake et al., 2001 ▶; Churchill et al., 1982 ▶; Kim et al., 2008 ▶; Schramm, 1978 ▶). Both tetra­hedra formed by iodines show an orientation similar to that of a pair of self-dual platonic bodies (Glaeser & Polthier, 2010 ▶).

Experimental

Crystal data

[Cu4I4(C12H27P)4]

M = 1570.98

Trigonal,

a = 22.006 (2) Å

c = 23.276 (2) Å

V = 9761.6 (15) Å3

Z = 6

Mo Kα radiation

μ = 3.31 mm−1

T = 110 K

0.23 × 0.19 × 0.13 mm

Data collection

Bruker Kappa APEXII DUO diffractometer

Absorption correction: numerical (Blessing, 1995 ▶) T min = 0.674, T max = 0.852

89010 measured reflections

13415 independent reflections

10102 reflections with I > 2σ(I)

R int = 0.039

Refinement

R[F 2 > 2σ(F 2)] = 0.046

wR(F 2) = 0.099

S = 1.03

13415 reflections

612 parameters

341 restraints

H-atom parameters constrained

Δρmax = 1.62 e Å−3

Δρmin = −1.16 e Å−3

Absolute structure: Flack (1983 ▶), 6695 Friedel pairs

Absolute structure parameter: −0.02 (2)

Data collection: APEX2 (Bruker, 2008 ▶); cell refinement: SAINT (Bruker, 2008 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: XP in SHELXTL-Plus (Sheldrick, 2008 ▶); software used to prepare material for publication: PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536814003390/hp2064sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536814003390/hp2064Isup2.hkl

CCDC reference: 957683

Additional supporting information: crystallographic information; 3D view; checkCIF report

[Cu4I4(C12H27P)4]	Dx = 1.603 Mg m−3
Mr = 1570.98	Mo Kα radiation, λ = 0.71073 Å
Trigonal, P3c1	Cell parameters from 10102 reflections
Hall symbol: P 3 -2"c	θ = 1.8–26.4°
a = 22.006 (2) Å	µ = 3.31 mm−1
c = 23.276 (2) Å	T = 110 K
V = 9761.6 (15) Å3	Irregular, colourless
Z = 6	0.23 × 0.19 × 0.13 mm
F(000) = 4704

Bruker Kappa APEXII DUO diffractometer	13415 independent reflections
Radiation source: fine-focus sealed tube	10102 reflections with I > 2σ(I)
Triumph monochromator	Rint = 0.039
ω + Phi Scans scans	θmax = 26.4°, θmin = 1.8°
Absorption correction: numerical (Blessing, 1995)	h = −27→27
Tmin = 0.674, Tmax = 0.852	k = −23→27
89010 measured reflections	l = −28→29

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.046	H-atom parameters constrained
wR(F2) = 0.099	w = 1/[σ2(Fo2) + (0.0213P)2 + 46.6098P] where P = (Fo2 + 2Fc2)/3
S = 1.03	(Δ/σ)max = 0.001
13415 reflections	Δρmax = 1.62 e Å−3
612 parameters	Δρmin = −1.16 e Å−3
341 restraints	Absolute structure: Flack (1983), 6695 Friedel pairs
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.02 (2)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
I1	0.98362 (3)	0.87545 (3)	0.58137 (2)	0.04502 (13)
I2	1.0000	1.0000	0.73872 (3)	0.0401 (2)
Cu1	0.92257 (5)	0.93441 (5)	0.64411 (4)	0.0433 (2)
Cu2	1.0000	1.0000	0.54664 (6)	0.0437 (4)
P1	1.0000	1.0000	0.45024 (14)	0.0444 (9)
C1	1.0170 (5)	0.9357 (5)	0.4165 (3)	0.056 (2)
H1A	0.9796	0.8883	0.4281	0.067*
H1B	1.0140	0.9394	0.3744	0.067*
C2	1.0876 (5)	0.9430 (5)	0.4311 (4)	0.055 (2)
H2A	1.0941	0.9465	0.4733	0.066*
H2B	1.1254	0.9868	0.4139	0.066*
C3	1.0940 (6)	0.8809 (6)	0.4090 (4)	0.073 (3)
H3A	1.0837	0.8748	0.3674	0.087*
H3B	1.0591	0.8375	0.4288	0.087*
C4	1.1690 (6)	0.8926 (6)	0.4198 (5)	0.085 (3)
H4A	1.2032	0.9326	0.3971	0.127*
H4B	1.1705	0.8504	0.4085	0.127*
H4C	1.1806	0.9019	0.4607	0.127*
P2	0.82325 (12)	0.84464 (12)	0.67885 (9)	0.0458 (5)
C5	0.8325 (5)	0.8140 (5)	0.7491 (3)	0.052 (2)
H5A	0.8454	0.8521	0.7774	0.063*
H5B	0.7865	0.7741	0.7608	0.063*
C6	0.8872 (5)	0.7907 (5)	0.7513 (4)	0.060 (2)
H6A	0.8666	0.7438	0.7332	0.073*
H6B	0.9276	0.8235	0.7273	0.073*
C7	0.9152 (7)	0.7866 (6)	0.8102 (4)	0.084 (3)
H7A	0.9484	0.7690	0.8054	0.100*
H7B	0.9417	0.8345	0.8265	0.100*
C8	0.8628 (8)	0.7430 (8)	0.8497 (6)	0.128 (5)
H8A	0.8282	0.7584	0.8534	0.192*
H8B	0.8843	0.7458	0.8872	0.192*
H8C	0.8395	0.6944	0.8360	0.192*
C9	0.7468 (5)	0.8566 (6)	0.6880 (4)	0.067 (3)
H9A	0.7334	0.8661	0.6499	0.081*
H9B	0.7070	0.8119	0.7022	0.081*
C10	0.7566 (6)	0.9112 (6)	0.7261 (5)	0.076 (3)
H10A	0.7946	0.9564	0.7111	0.092*
H10B	0.7718	0.9030	0.7640	0.092*
C11	0.6882 (6)	0.9169 (7)	0.7346 (5)	0.091 (4)
H11A	0.7004	0.9594	0.7575	0.109*
H11B	0.6716	0.9226	0.6965	0.109*
C12	0.6287 (7)	0.8531 (8)	0.7646 (6)	0.112 (4)
H12A	0.6145	0.8111	0.7412	0.168*
H12B	0.5886	0.8604	0.7697	0.168*
H12C	0.6448	0.8469	0.8023	0.168*
C13	0.7867 (5)	0.7657 (5)	0.6361 (3)	0.057 (2)
H13A	0.8213	0.7496	0.6333	0.068*
H13B	0.7444	0.7285	0.6555	0.068*
C14	0.7669 (7)	0.7768 (6)	0.5752 (4)	0.083 (3)
H14A	0.8080	0.8173	0.5574	0.100*
H14B	0.7289	0.7883	0.5779	0.100*
C15	0.7423 (8)	0.7115 (7)	0.5360 (6)	0.108 (4)
H15A	0.7055	0.6695	0.5562	0.130*
H15B	0.7214	0.7180	0.5006	0.130*
C16	0.7988 (13)	0.6998 (12)	0.5209 (9)	0.200 (9)
H16A	0.8423	0.7450	0.5175	0.300*
H16B	0.7884	0.6751	0.4840	0.300*
H16C	0.8042	0.6715	0.5507	0.300*
I3	0.6667	0.3333	0.63630 (3)	0.0468 (2)
I4	0.79161 (4)	0.44159 (5)	0.79251 (3)	0.0826 (3)
Cu3	0.67703 (7)	0.41066 (7)	0.72971 (4)	0.0649 (3)
Cu4	0.6667	0.3333	0.82528 (8)	0.0834 (7)
P3	0.69157 (19)	0.51440 (17)	0.70139 (16)	0.0875 (9)
C17	0.6509 (10)	0.5582 (10)	0.7297 (6)	0.065 (6)	0.55 (2)
H17A	0.6674	0.6028	0.7086	0.078*	0.55 (2)
H17B	0.5996	0.5292	0.7237	0.078*	0.55 (2)
C18	0.6656 (10)	0.5741 (11)	0.7941 (6)	0.070 (6)	0.55 (2)
H18A	0.7157	0.6093	0.7998	0.084*	0.55 (2)
H18B	0.6558	0.5308	0.8147	0.084*	0.55 (2)
C17A	0.6452 (14)	0.5360 (11)	0.7697 (12)	0.075 (8)	0.45 (2)
H17C	0.5938	0.5041	0.7687	0.090*	0.45 (2)
H17D	0.6633	0.5284	0.8064	0.090*	0.45 (2)
C18A	0.6621 (12)	0.6124 (10)	0.7656 (8)	0.075 (8)	0.45 (2)
H18C	0.6428	0.6224	0.7308	0.090*	0.45 (2)
H18D	0.7127	0.6470	0.7700	0.090*	0.45 (2)
C19	0.6189 (8)	0.6031 (8)	0.8202 (6)	0.140 (6)
H19A	0.5706	0.5712	0.8063	0.168*	0.55 (2)
H19B	0.6181	0.5956	0.8622	0.168*	0.55 (2)
H19C	0.5690	0.5661	0.8168	0.168*	0.45 (2)
H19D	0.6401	0.5969	0.8556	0.168*	0.45 (2)
C20	0.6311 (10)	0.6757 (9)	0.8125 (8)	0.158 (7)
H20A	0.6784	0.7096	0.8259	0.237*
H20B	0.5963	0.6811	0.8347	0.237*
H20C	0.6267	0.6839	0.7717	0.237*
C21	0.6658 (7)	0.5116 (13)	0.6206 (13)	0.083 (8)	0.66 (5)
H21A	0.6829	0.5598	0.6060	0.100*	0.66 (5)
H21B	0.6868	0.4894	0.5971	0.100*	0.66 (5)
C21A	0.6529 (13)	0.5238 (13)	0.6461 (14)	0.054 (10)	0.34 (5)
H21C	0.6448	0.5630	0.6559	0.065*	0.34 (5)
H21D	0.6886	0.5416	0.6152	0.065*	0.34 (5)
C22	0.5843 (6)	0.4680 (7)	0.6172 (6)	0.118 (5)
H22A	0.5651	0.4974	0.6314	0.141*	0.66 (5)
H22B	0.5677	0.4273	0.6433	0.141*	0.66 (5)
H22C	0.5493	0.4789	0.6335	0.141*	0.34 (5)
H22D	0.5754	0.4245	0.6369	0.141*	0.34 (5)
C23	0.5541 (11)	0.4406 (10)	0.5560 (6)	0.167 (7)
H23A	0.5619	0.4013	0.5462	0.201*
H23B	0.5027	0.4219	0.5568	0.201*
C24	0.5850 (14)	0.4942 (13)	0.5108 (10)	0.265 (14)
H24A	0.5850	0.5367	0.5232	0.397*
H24B	0.5574	0.4763	0.4755	0.397*
H24C	0.6334	0.5052	0.5035	0.397*
C25	0.7827 (6)	0.5870 (6)	0.6999 (5)	0.092 (4)
H25A	0.7832	0.6305	0.6881	0.110*
H25B	0.8025	0.5944	0.7392	0.110*
C26	0.8288 (7)	0.5735 (6)	0.6590 (5)	0.095 (4)
H26A	0.8146	0.5751	0.6189	0.114*
H26B	0.8214	0.5260	0.6661	0.114*
C27	0.9069 (8)	0.6276 (8)	0.6663 (7)	0.131 (5)
H27A	0.9120	0.6747	0.6697	0.157*	0.52 (2)
H27B	0.9235	0.6176	0.7027	0.157*	0.52 (2)
H27C	0.9164	0.6458	0.7061	0.157*	0.48 (2)
H27D	0.9358	0.6056	0.6583	0.157*	0.48 (2)
C28	0.9527 (12)	0.6291 (13)	0.6191 (9)	0.094 (8)	0.52 (2)
H28A	0.9389	0.6421	0.5831	0.141*	0.52 (2)
H28B	0.9479	0.5826	0.6149	0.141*	0.52 (2)
H28C	1.0016	0.6636	0.6279	0.141*	0.52 (2)
C28A	0.9243 (16)	0.6854 (13)	0.6252 (11)	0.112 (11)	0.48 (2)
H28D	0.9752	0.7174	0.6249	0.168*	0.48 (2)
H28E	0.9007	0.7111	0.6369	0.168*	0.48 (2)
H28F	0.9086	0.6660	0.5866	0.168*	0.48 (2)
P4	0.6667	0.3333	0.92200 (18)	0.0867 (17)
C29	0.5817 (6)	0.3008 (6)	0.9553 (4)	0.083 (3)
H29A	0.5870	0.2997	0.9974	0.099*
H29B	0.5647	0.3339	0.9470	0.099*
C30	0.5275 (6)	0.2290 (7)	0.9353 (5)	0.089 (3)
H30A	0.5448	0.1960	0.9429	0.107*
H30B	0.5213	0.2303	0.8933	0.107*
C31	0.4572 (8)	0.2019 (8)	0.9642 (6)	0.120 (5)
H31A	0.4392	0.2340	0.9553	0.144*
H31B	0.4639	0.2028	1.0064	0.144*
C32	0.4027 (9)	0.1280 (9)	0.9464 (7)	0.146 (6)
H32A	0.4021	0.1242	0.9045	0.219*
H32B	0.3563	0.1179	0.9599	0.219*
H32C	0.4143	0.0944	0.9634	0.219*
I5	0.3333	0.6667	1.02038 (4)	0.0597 (3)
I6	0.46756 (4)	0.71941 (4)	0.86390 (2)	0.0751 (2)
Cu5	0.38394 (7)	0.75018 (7)	0.92661 (4)	0.0679 (3)
Cu6	0.3333	0.6667	0.83068 (7)	0.0725 (6)
P5	0.3333	0.6667	0.73393 (16)	0.0726 (14)
C33	0.3336 (7)	0.5928 (6)	0.7002 (4)	0.084 (3)
H33A	0.2866	0.5508	0.7054	0.101*
H33B	0.3410	0.6021	0.6584	0.101*
C34	0.3888 (6)	0.5754 (6)	0.7225 (4)	0.078 (3)
H34A	0.4357	0.6180	0.7198	0.093*
H34B	0.3794	0.5622	0.7636	0.093*
C35	0.3894 (7)	0.5163 (7)	0.6896 (6)	0.100 (4)
H35A	0.4016	0.5302	0.6489	0.120*
H35B	0.3421	0.4741	0.6907	0.120*
C36	0.4433 (9)	0.4988 (8)	0.7158 (7)	0.137 (6)
H36A	0.4908	0.5385	0.7099	0.206*
H36B	0.4390	0.4570	0.6972	0.206*
H36C	0.4343	0.4900	0.7571	0.206*
P6	0.44960 (17)	0.86037 (17)	0.95844 (12)	0.0738 (8)
C37	0.5201 (11)	0.9100 (9)	0.9053 (11)	0.083 (7)	0.58 (2)
H37A	0.5443	0.8827	0.8994	0.100*	0.58 (2)
H37B	0.4963	0.9078	0.8686	0.100*	0.58 (2)
C38	0.5771 (10)	0.9853 (10)	0.9127 (8)	0.104 (9)	0.58 (2)
H38A	0.6072	0.9904	0.9460	0.125*	0.58 (2)
H38B	0.5566	1.0161	0.9184	0.125*	0.58 (2)
C37A	0.5427 (12)	0.9222 (13)	0.9340 (8)	0.053 (7)	0.42 (2)
H37C	0.5649	0.9628	0.9604	0.064*	0.42 (2)
H37D	0.5700	0.8976	0.9357	0.064*	0.42 (2)
C38A	0.5447 (8)	0.9479 (12)	0.8736 (8)	0.065 (8)	0.42 (2)
H38C	0.5133	0.9679	0.8708	0.078*	0.42 (2)
H38D	0.5274	0.9079	0.8465	0.078*	0.42 (2)
C39	0.6193 (8)	1.0038 (8)	0.8566 (7)	0.139 (6)
H39A	0.6362	0.9711	0.8468	0.167*	0.58 (2)
H39B	0.5950	1.0105	0.8235	0.167*	0.58 (2)
H39C	0.6436	0.9767	0.8511	0.167*	0.42 (2)
H39D	0.6135	1.0179	0.8175	0.167*	0.42 (2)
C40	0.6744 (11)	1.0712 (10)	0.8831 (9)	0.192 (8)
H40A	0.6562	1.1036	0.8869	0.288*
H40B	0.7162	1.0924	0.8587	0.288*
H40C	0.6866	1.0617	0.9212	0.288*
C41	0.4796 (6)	0.8673 (6)	1.0326 (5)	0.076 (3)
H41A	0.5023	0.9171	1.0446	0.091*
H41B	0.4382	0.8403	1.0576	0.091*
C42	0.5304 (7)	0.8411 (7)	1.0420 (5)	0.092 (4)
H42A	0.5768	0.8759	1.0263	0.110*
H42B	0.5138	0.7967	1.0207	0.110*
C43	0.5390 (7)	0.8284 (8)	1.1070 (5)	0.104 (4)
H43A	0.4924	0.7960	1.1236	0.125*
H43B	0.5684	0.8061	1.1104	0.125*
C44	0.5728 (8)	0.8966 (8)	1.1404 (7)	0.126 (5)
H44A	0.6206	0.9272	1.1263	0.188*
H44B	0.5744	0.8868	1.1813	0.188*
H44C	0.5453	0.9201	1.1354	0.188*
C45	0.4063 (7)	0.9125 (7)	0.9600 (5)	0.089 (3)
H45A	0.4410	0.9610	0.9717	0.106*
H45B	0.3906	0.9148	0.9206	0.106*
C46	0.3447 (6)	0.8859 (6)	0.9992 (5)	0.080 (3)
H46A	0.3610	0.8878	1.0392	0.096*
H46B	0.3119	0.8360	0.9899	0.096*
C47	0.3053 (7)	0.9252 (7)	0.9964 (6)	0.093 (4)
H47A	0.2896	0.9242	0.9564	0.112*
H47B	0.3376	0.9749	1.0068	0.112*
C48	0.2412 (8)	0.8957 (8)	1.0362 (6)	0.110 (4)
H48A	0.2140	0.8445	1.0321	0.164*
H48B	0.2118	0.9158	1.0257	0.164*
H48C	0.2568	0.9077	1.0761	0.164*

	U11	U22	U33	U12	U13	U23
I1	0.0568 (3)	0.0457 (3)	0.0341 (2)	0.0268 (3)	0.0013 (2)	−0.0033 (2)
I2	0.0474 (3)	0.0474 (3)	0.0255 (4)	0.02371 (16)	0.000	0.000
Cu1	0.0470 (6)	0.0423 (5)	0.0341 (5)	0.0175 (5)	0.0006 (4)	−0.0003 (4)
Cu2	0.0528 (6)	0.0528 (6)	0.0253 (7)	0.0264 (3)	0.000	0.000
P1	0.0528 (14)	0.0528 (14)	0.0278 (16)	0.0264 (7)	0.000	0.000
C1	0.072 (5)	0.060 (5)	0.036 (4)	0.033 (4)	0.001 (4)	−0.005 (3)
C2	0.064 (5)	0.061 (5)	0.041 (4)	0.032 (4)	0.005 (4)	−0.003 (4)
C3	0.096 (7)	0.077 (6)	0.061 (5)	0.054 (5)	−0.005 (5)	−0.005 (4)
C4	0.089 (7)	0.100 (7)	0.085 (6)	0.062 (6)	0.001 (5)	−0.004 (5)
P2	0.0462 (12)	0.0488 (13)	0.0381 (10)	0.0205 (11)	0.0013 (9)	0.0029 (9)
C5	0.062 (5)	0.052 (5)	0.042 (4)	0.028 (4)	0.004 (4)	0.010 (3)
C6	0.081 (6)	0.049 (5)	0.049 (4)	0.031 (4)	−0.011 (4)	−0.001 (4)
C7	0.109 (7)	0.083 (6)	0.070 (6)	0.056 (6)	−0.017 (5)	−0.002 (5)
C8	0.133 (9)	0.121 (9)	0.116 (8)	0.054 (7)	−0.019 (7)	0.013 (7)
C9	0.067 (6)	0.084 (6)	0.056 (5)	0.042 (5)	0.005 (4)	0.010 (4)
C10	0.075 (6)	0.072 (6)	0.084 (6)	0.038 (5)	0.014 (5)	0.000 (5)
C11	0.078 (6)	0.114 (8)	0.079 (6)	0.046 (6)	0.008 (5)	0.006 (6)
C12	0.104 (8)	0.132 (9)	0.114 (8)	0.071 (7)	−0.010 (6)	0.005 (7)
C13	0.053 (5)	0.057 (5)	0.046 (4)	0.017 (4)	−0.005 (4)	0.004 (4)
C14	0.096 (7)	0.072 (6)	0.052 (5)	0.019 (5)	−0.020 (5)	−0.004 (4)
C15	0.117 (8)	0.087 (7)	0.094 (7)	0.031 (6)	−0.036 (6)	−0.016 (6)
C16	0.209 (13)	0.190 (12)	0.183 (12)	0.087 (9)	0.004 (9)	−0.038 (9)
I3	0.0580 (3)	0.0580 (3)	0.0245 (4)	0.02900 (17)	0.000	0.000
I4	0.0915 (6)	0.1065 (6)	0.0383 (3)	0.0409 (5)	−0.0148 (3)	−0.0186 (3)
Cu3	0.0853 (9)	0.0761 (8)	0.0342 (5)	0.0410 (7)	−0.0001 (5)	−0.0056 (5)
Cu4	0.1118 (12)	0.1118 (12)	0.0266 (9)	0.0559 (6)	0.000	0.000
P3	0.090 (2)	0.0643 (19)	0.104 (2)	0.0353 (17)	−0.0179 (18)	−0.0260 (17)
C17	0.072 (9)	0.070 (9)	0.060 (8)	0.040 (7)	0.006 (7)	0.000 (7)
C18	0.073 (9)	0.066 (9)	0.057 (8)	0.024 (7)	−0.004 (7)	−0.011 (7)
C17A	0.083 (11)	0.070 (11)	0.079 (11)	0.043 (8)	0.014 (8)	0.004 (8)
C18A	0.078 (11)	0.066 (11)	0.076 (11)	0.033 (8)	0.006 (8)	0.009 (8)
C19	0.122 (9)	0.163 (10)	0.105 (8)	0.049 (7)	0.021 (7)	−0.042 (7)
C20	0.138 (10)	0.200 (11)	0.128 (9)	0.078 (8)	0.019 (7)	0.018 (8)
C21	0.094 (10)	0.075 (10)	0.073 (11)	0.037 (7)	0.005 (7)	0.019 (7)
C21A	0.060 (13)	0.057 (12)	0.042 (12)	0.027 (9)	0.005 (8)	−0.012 (8)
C22	0.109 (8)	0.109 (8)	0.136 (9)	0.055 (7)	−0.019 (7)	0.008 (7)
C23	0.171 (11)	0.176 (11)	0.138 (10)	0.074 (8)	−0.036 (8)	0.026 (8)
C24	0.260 (16)	0.269 (17)	0.266 (17)	0.133 (11)	0.001 (10)	−0.017 (10)
C25	0.096 (7)	0.081 (7)	0.099 (7)	0.046 (6)	0.000 (6)	−0.019 (5)
C26	0.098 (7)	0.077 (7)	0.092 (7)	0.031 (6)	−0.006 (6)	−0.010 (5)
C27	0.121 (9)	0.119 (9)	0.133 (9)	0.045 (7)	0.009 (7)	0.001 (7)
C28	0.094 (11)	0.098 (12)	0.093 (11)	0.051 (8)	0.006 (8)	−0.017 (8)
C28A	0.119 (14)	0.112 (14)	0.106 (14)	0.059 (10)	0.003 (9)	−0.010 (9)
P4	0.116 (3)	0.116 (3)	0.028 (2)	0.0581 (14)	0.000	0.000
C29	0.101 (7)	0.104 (7)	0.032 (4)	0.043 (6)	0.009 (4)	0.011 (4)
C30	0.097 (7)	0.103 (7)	0.058 (5)	0.044 (6)	0.000 (5)	0.019 (5)
C31	0.128 (9)	0.116 (8)	0.094 (7)	0.045 (7)	−0.010 (7)	0.008 (6)
C32	0.155 (10)	0.142 (9)	0.120 (9)	0.059 (7)	0.011 (7)	0.019 (7)
I5	0.0761 (5)	0.0761 (5)	0.0270 (4)	0.0380 (2)	0.000	0.000
I6	0.0866 (5)	0.1004 (5)	0.0381 (3)	0.0465 (4)	0.0095 (3)	−0.0011 (3)
Cu5	0.0833 (9)	0.0823 (9)	0.0354 (5)	0.0393 (8)	0.0014 (6)	−0.0012 (5)
Cu6	0.0944 (10)	0.0944 (10)	0.0285 (9)	0.0472 (5)	0.000	0.000
P5	0.095 (2)	0.095 (2)	0.0269 (18)	0.0477 (11)	0.000	0.000
C33	0.089 (7)	0.099 (7)	0.058 (6)	0.042 (6)	0.005 (5)	−0.005 (5)
C34	0.092 (7)	0.090 (7)	0.059 (5)	0.052 (5)	0.002 (5)	−0.004 (5)
C35	0.092 (7)	0.102 (7)	0.102 (7)	0.046 (6)	0.003 (6)	−0.009 (6)
C36	0.150 (10)	0.131 (9)	0.140 (9)	0.078 (8)	0.012 (7)	−0.006 (7)
P6	0.080 (2)	0.0772 (19)	0.0680 (17)	0.0421 (17)	0.0089 (14)	0.0044 (14)
C37	0.085 (10)	0.073 (10)	0.091 (11)	0.039 (8)	−0.008 (8)	−0.004 (8)
C38	0.102 (12)	0.103 (12)	0.103 (12)	0.048 (9)	−0.009 (8)	−0.003 (8)
C37A	0.046 (10)	0.059 (10)	0.049 (9)	0.022 (7)	0.005 (7)	0.003 (7)
C38A	0.060 (10)	0.075 (11)	0.060 (10)	0.033 (8)	0.010 (7)	0.005 (8)
C39	0.133 (9)	0.143 (9)	0.149 (9)	0.074 (7)	0.027 (7)	0.053 (7)
C40	0.195 (12)	0.209 (12)	0.180 (11)	0.106 (9)	−0.007 (8)	0.041 (9)
C41	0.078 (6)	0.070 (6)	0.080 (6)	0.037 (5)	−0.009 (5)	−0.017 (5)
C42	0.104 (7)	0.077 (6)	0.102 (7)	0.051 (6)	−0.014 (6)	−0.016 (5)
C43	0.097 (7)	0.120 (8)	0.099 (7)	0.058 (6)	−0.011 (6)	−0.013 (6)
C44	0.113 (8)	0.143 (9)	0.134 (9)	0.074 (7)	−0.023 (7)	−0.043 (7)
C45	0.103 (7)	0.092 (7)	0.081 (6)	0.056 (6)	0.013 (5)	0.008 (5)
C46	0.093 (7)	0.084 (6)	0.069 (6)	0.050 (5)	0.011 (5)	0.006 (5)
C47	0.096 (7)	0.095 (7)	0.098 (7)	0.055 (6)	0.002 (6)	0.002 (6)
C48	0.117 (8)	0.123 (8)	0.101 (7)	0.068 (7)	0.006 (6)	0.010 (6)

I1—Cu1i	2.6578 (11)	C22—H22C	0.9900
I1—Cu2	2.7032 (7)	C22—H22D	0.9900
I1—Cu1	2.7137 (11)	C23—C24	1.470 (10)
I2—Cu1	2.7161 (12)	C23—H23A	0.9900
I2—Cu1ii	2.7161 (11)	C23—H23B	0.9900
I2—Cu1i	2.7161 (12)	C24—H24A	0.9800
Cu1—P2	2.240 (2)	C24—H24B	0.9800
Cu1—I1ii	2.6578 (11)	C24—H24C	0.9800
Cu1—Cu1ii	2.7535 (17)	C25—C26	1.526 (16)
Cu1—Cu1i	2.7535 (17)	C25—H25A	0.9900
Cu1—Cu2	2.7702 (15)	C25—H25B	0.9900
Cu2—P1	2.244 (4)	C26—C27	1.534 (18)
Cu2—I1i	2.7032 (7)	C26—H26A	0.9900
Cu2—I1ii	2.7033 (7)	C26—H26B	0.9900
Cu2—Cu1ii	2.7701 (15)	C27—C28	1.480 (10)
Cu2—Cu1i	2.7702 (15)	C27—C28A	1.481 (10)
P1—C1	1.812 (9)	C27—H27A	0.9900
P1—C1i	1.812 (9)	C27—H27B	0.9900
P1—C1ii	1.812 (9)	C27—H27C	0.9900
C1—C2	1.520 (12)	C27—H27D	0.9900
C1—H1A	0.9900	C28—H28A	0.9800
C1—H1B	0.9900	C28—H28B	0.9800
C2—C3	1.530 (13)	C28—H28C	0.9800
C2—H2A	0.9900	C28A—H28D	0.9800
C2—H2B	0.9900	C28A—H28E	0.9800
C3—C4	1.559 (15)	C28A—H28F	0.9800
C3—H3A	0.9900	P4—C29iv	1.809 (11)
C3—H3B	0.9900	P4—C29	1.809 (11)
C4—H4A	0.9800	P4—C29iii	1.809 (11)
C4—H4B	0.9800	C29—C30	1.500 (16)
C4—H4C	0.9800	C29—H29A	0.9900
P2—C13	1.805 (9)	C29—H29B	0.9900
P2—C5	1.819 (8)	C30—C31	1.509 (18)
P2—C9	1.841 (10)	C30—H30A	0.9900
C5—C6	1.527 (13)	C30—H30B	0.9900
C5—H5A	0.9900	C31—C32	1.52 (2)
C5—H5B	0.9900	C31—H31A	0.9900
C6—C7	1.525 (12)	C31—H31B	0.9900
C6—H6A	0.9900	C32—H32A	0.9800
C6—H6B	0.9900	C32—H32B	0.9800
C7—C8	1.410 (17)	C32—H32C	0.9800
C7—H7A	0.9900	I5—Cu5v	2.7081 (13)
C7—H7B	0.9900	I5—Cu5vi	2.7081 (13)
C8—H8A	0.9800	I5—Cu5	2.7081 (13)
C8—H8B	0.9800	I6—Cu5vi	2.6841 (15)
C8—H8C	0.9800	I6—Cu5	2.6872 (14)
C9—C10	1.421 (13)	I6—Cu6	2.6909 (9)
C9—H9A	0.9900	Cu5—P6	2.239 (4)
C9—H9B	0.9900	Cu5—I6v	2.6841 (15)
C10—C11	1.583 (15)	Cu5—Cu6	2.7490 (18)
C10—H10A	0.9900	Cu5—Cu5vi	2.777 (2)
C10—H10B	0.9900	Cu5—Cu5v	2.777 (2)
C11—C12	1.528 (17)	Cu6—P5	2.252 (4)
C11—H11A	0.9900	Cu6—I6vi	2.6910 (9)
C11—H11B	0.9900	Cu6—I6v	2.6911 (9)
C12—H12A	0.9800	Cu6—Cu5v	2.7491 (18)
C12—H12B	0.9800	Cu6—Cu5vi	2.7491 (18)
C12—H12C	0.9800	P5—C33v	1.809 (11)
C13—C14	1.536 (12)	P5—C33	1.809 (11)
C13—H13A	0.9900	P5—C33vi	1.809 (11)
C13—H13B	0.9900	C33—C34	1.534 (15)
C14—C15	1.554 (16)	C33—H33A	0.9900
C14—H14A	0.9900	C33—H33B	0.9900
C14—H14B	0.9900	C34—C35	1.518 (16)
C15—C16	1.43 (2)	C34—H34A	0.9900
C15—H15A	0.9900	C34—H34B	0.9900
C15—H15B	0.9900	C35—C36	1.543 (19)
C16—H16A	0.9800	C35—H35A	0.9900
C16—H16B	0.9800	C35—H35B	0.9900
C16—H16C	0.9800	C36—H36A	0.9800
I3—Cu3iii	2.6994 (13)	C36—H36B	0.9800
I3—Cu3	2.6994 (13)	C36—H36C	0.9800
I3—Cu3iv	2.6995 (13)	P6—C45	1.823 (12)
I4—Cu3	2.6909 (15)	P6—C41	1.826 (11)
I4—Cu3iii	2.6923 (15)	P6—C37	1.85 (2)
I4—Cu4	2.6956 (11)	P6—C37A	1.89 (2)
Cu3—P3	2.240 (4)	C37—C38	1.507 (10)
Cu3—I4iv	2.6924 (15)	C37—H37A	0.9900
Cu3—Cu4	2.7400 (19)	C37—H37B	0.9900
Cu3—Cu3iii	2.771 (2)	C38—C39	1.535 (10)
Cu3—Cu3iv	2.771 (2)	C38—H38A	0.9900
Cu4—P4	2.251 (5)	C38—H38B	0.9900
Cu4—I4iii	2.6955 (10)	C37A—C38A	1.508 (10)
Cu4—I4iv	2.6958 (10)	C37A—H37C	0.9900
Cu4—Cu3iii	2.7398 (19)	C37A—H37D	0.9900
Cu4—Cu3iv	2.7399 (19)	C38A—C39	1.530 (10)
P3—C21A	1.61 (3)	C38A—H38C	0.9900
P3—C17	1.739 (17)	C38A—H38D	0.9900
P3—C25	1.836 (13)	C39—C40	1.502 (10)
P3—C21	1.96 (3)	C39—H39A	0.9900
P3—C17A	2.07 (3)	C39—H39B	0.9900
C17—C18	1.538 (10)	C39—H39C	0.9900
C17—H17A	0.9900	C39—H39D	0.9900
C17—H17B	0.9900	C40—H40A	0.9800
C18—C19	1.575 (10)	C40—H40B	0.9800
C18—H18A	0.9900	C40—H40C	0.9800
C18—H18B	0.9900	C41—C42	1.509 (15)
C17A—C18A	1.534 (10)	C41—H41A	0.9900
C17A—H17C	0.9900	C41—H41B	0.9900
C17A—H17D	0.9900	C42—C43	1.567 (17)
C18A—C19	1.538 (10)	C42—H42A	0.9900
C18A—H18C	0.9900	C42—H42B	0.9900
C18A—H18D	0.9900	C43—C44	1.515 (18)
C19—C20	1.492 (9)	C43—H43A	0.9900
C19—H19A	0.9900	C43—H43B	0.9900
C19—H19B	0.9900	C44—H44A	0.9800
C19—H19C	0.9900	C44—H44B	0.9800
C19—H19D	0.9900	C44—H44C	0.9800
C20—H20A	0.9800	C45—C46	1.489 (15)
C20—H20B	0.9800	C45—H45A	0.9900
C20—H20C	0.9800	C45—H45B	0.9900
C21—C22	1.556 (9)	C46—C47	1.501 (15)
C21—H21A	0.9900	C46—H46A	0.9900
C21—H21B	0.9900	C46—H46B	0.9900
C21A—C22	1.544 (10)	C47—C48	1.533 (17)
C21A—H21C	0.9900	C47—H47A	0.9900
C21A—H21D	0.9900	C47—H47B	0.9900
C22—C23	1.559 (9)	C48—H48A	0.9800
C22—H22A	0.9900	C48—H48B	0.9800
C22—H22B	0.9900	C48—H48C	0.9800
Cu1i—I1—Cu2	62.22 (3)	C23—C22—H22A	108.5
Cu1i—I1—Cu1	61.67 (4)	C21A—C22—H22B	103.0
Cu2—I1—Cu1	61.51 (3)	C21—C22—H22B	108.5
Cu1—I2—Cu1ii	60.91 (4)	C23—C22—H22B	108.5
Cu1—I2—Cu1i	60.91 (4)	H22A—C22—H22B	107.5
Cu1ii—I2—Cu1i	60.91 (4)	C21A—C22—H22C	102.1
P2—Cu1—I1ii	109.25 (7)	C21—C22—H22C	128.9
P2—Cu1—I1	105.70 (7)	C23—C22—H22C	102.1
I1ii—Cu1—I1	112.56 (4)	H22A—C22—H22C	22.3
P2—Cu1—I2	104.61 (6)	H22B—C22—H22C	90.3
I1ii—Cu1—I2	112.94 (4)	C21A—C22—H22D	102.1
I1—Cu1—I2	111.18 (4)	C21—C22—H22D	100.6
P2—Cu1—Cu1ii	146.32 (8)	C23—C22—H22D	102.1
I1ii—Cu1—Cu1ii	60.17 (4)	H22A—C22—H22D	122.3
I1—Cu1—Cu1ii	107.80 (3)	H22B—C22—H22D	14.8
I2—Cu1—Cu1ii	59.544 (18)	H22C—C22—H22D	104.8
P2—Cu1—Cu1i	141.32 (8)	C24—C23—C22	114.0 (18)
I1ii—Cu1—Cu1i	109.43 (3)	C24—C23—H23A	108.7
I1—Cu1—Cu1i	58.17 (4)	C22—C23—H23A	108.7
I2—Cu1—Cu1i	59.544 (18)	C24—C23—H23B	108.7
Cu1ii—Cu1—Cu1i	60.0	C22—C23—H23B	108.7
P2—Cu1—Cu2	146.10 (7)	H23A—C23—H23B	107.6
I1ii—Cu1—Cu2	59.70 (2)	C23—C24—H24A	109.5
I1—Cu1—Cu2	59.06 (2)	C23—C24—H24B	109.5
I2—Cu1—Cu2	109.15 (4)	H24A—C24—H24B	109.5
Cu1ii—Cu1—Cu2	60.20 (2)	C23—C24—H24C	109.5
Cu1i—Cu1—Cu2	60.20 (2)	H24A—C24—H24C	109.5
P1—Cu2—I1i	107.40 (3)	H24B—C24—H24C	109.5
P1—Cu2—I1	107.40 (3)	C26—C25—P3	112.7 (8)
I1i—Cu2—I1	111.47 (3)	C26—C25—H25A	109.1
P1—Cu2—I1ii	107.40 (3)	P3—C25—H25A	109.1
I1i—Cu2—I1ii	111.46 (3)	C26—C25—H25B	109.1
I1—Cu2—I1ii	111.46 (3)	P3—C25—H25B	109.1
P1—Cu2—Cu1ii	144.98 (3)	H25A—C25—H25B	107.8
I1i—Cu2—Cu1ii	58.08 (3)	C25—C26—C27	112.1 (11)
I1—Cu2—Cu1ii	107.62 (5)	C25—C26—H26A	109.2
I1ii—Cu2—Cu1ii	59.43 (3)	C27—C26—H26A	109.2
P1—Cu2—Cu1i	144.98 (3)	C25—C26—H26B	109.2
I1i—Cu2—Cu1i	59.43 (3)	C27—C26—H26B	109.2
I1—Cu2—Cu1i	58.09 (3)	H26A—C26—H26B	107.9
I1ii—Cu2—Cu1i	107.62 (5)	C28—C27—C28A	67.7 (15)
Cu1ii—Cu2—Cu1i	59.60 (4)	C28—C27—C26	114.9 (16)
P1—Cu2—Cu1	144.98 (3)	C28A—C27—C26	107.6 (18)
I1i—Cu2—Cu1	107.62 (5)	C28—C27—H27A	108.5
I1—Cu2—Cu1	59.43 (3)	C28A—C27—H27A	46.1
I1ii—Cu2—Cu1	58.09 (3)	C26—C27—H27A	108.5
Cu1ii—Cu2—Cu1	59.60 (4)	C28—C27—H27B	108.5
Cu1i—Cu2—Cu1	59.60 (4)	C28A—C27—H27B	141.0
C1—P1—C1i	102.6 (3)	C26—C27—H27B	108.5
C1—P1—C1ii	102.6 (3)	H27A—C27—H27B	107.5
C1i—P1—C1ii	102.6 (3)	C28—C27—H27C	133.1
C1—P1—Cu2	115.7 (3)	C28A—C27—H27C	110.2
C1i—P1—Cu2	115.7 (3)	C26—C27—H27C	110.2
C1ii—P1—Cu2	115.6 (3)	H27A—C27—H27C	67.0
C2—C1—P1	114.9 (6)	H27B—C27—H27C	42.4
C2—C1—H1A	108.5	C28—C27—H27D	43.5
P1—C1—H1A	108.5	C28A—C27—H27D	110.2
C2—C1—H1B	108.5	C26—C27—H27D	110.2
P1—C1—H1B	108.5	H27A—C27—H27D	139.8
H1A—C1—H1B	107.5	H27B—C27—H27D	69.8
C1—C2—C3	112.2 (8)	H27C—C27—H27D	108.5
C1—C2—H2A	109.2	C27—C28—H28A	109.5
C3—C2—H2A	109.2	C27—C28—H28B	109.5
C1—C2—H2B	109.2	C27—C28—H28C	109.5
C3—C2—H2B	109.2	C27—C28A—H28D	109.5
H2A—C2—H2B	107.9	C27—C28A—H28E	109.5
C2—C3—C4	111.2 (9)	H28D—C28A—H28E	109.5
C2—C3—H3A	109.4	C27—C28A—H28F	109.5
C4—C3—H3A	109.4	H28D—C28A—H28F	109.5
C2—C3—H3B	109.4	H28E—C28A—H28F	109.5
C4—C3—H3B	109.4	C29iv—P4—C29	103.0 (4)
H3A—C3—H3B	108.0	C29iv—P4—C29iii	103.0 (4)
C3—C4—H4A	109.5	C29—P4—C29iii	103.0 (4)
C3—C4—H4B	109.5	C29iv—P4—Cu4	115.3 (3)
H4A—C4—H4B	109.5	C29—P4—Cu4	115.3 (3)
C3—C4—H4C	109.5	C29iii—P4—Cu4	115.3 (3)
H4A—C4—H4C	109.5	C30—C29—P4	113.9 (8)
H4B—C4—H4C	109.5	C30—C29—H29A	108.8
C13—P2—C5	102.6 (4)	P4—C29—H29A	108.8
C13—P2—C9	101.6 (5)	C30—C29—H29B	108.8
C5—P2—C9	103.2 (4)	P4—C29—H29B	108.8
C13—P2—Cu1	114.7 (3)	H29A—C29—H29B	107.7
C5—P2—Cu1	114.3 (3)	C29—C30—C31	113.3 (11)
C9—P2—Cu1	118.3 (4)	C29—C30—H30A	108.9
C6—C5—P2	114.0 (6)	C31—C30—H30A	108.9
C6—C5—H5A	108.8	C29—C30—H30B	108.9
P2—C5—H5A	108.8	C31—C30—H30B	108.9
C6—C5—H5B	108.8	H30A—C30—H30B	107.7
P2—C5—H5B	108.8	C30—C31—C32	114.0 (14)
H5A—C5—H5B	107.6	C30—C31—H31A	108.7
C7—C6—C5	117.4 (8)	C32—C31—H31A	108.7
C7—C6—H6A	108.0	C30—C31—H31B	108.7
C5—C6—H6A	108.0	C32—C31—H31B	108.7
C7—C6—H6B	108.0	H31A—C31—H31B	107.6
C5—C6—H6B	108.0	C31—C32—H32A	109.5
H6A—C6—H6B	107.2	C31—C32—H32B	109.5
C8—C7—C6	114.2 (11)	H32A—C32—H32B	109.5
C8—C7—H7A	108.7	C31—C32—H32C	109.5
C6—C7—H7A	108.7	H32A—C32—H32C	109.5
C8—C7—H7B	108.7	H32B—C32—H32C	109.5
C6—C7—H7B	108.7	Cu5v—I5—Cu5vi	61.70 (4)
H7A—C7—H7B	107.6	Cu5v—I5—Cu5	61.69 (5)
C7—C8—H8A	109.5	Cu5vi—I5—Cu5	61.69 (5)
C7—C8—H8B	109.5	Cu5vi—I6—Cu5	62.27 (6)
H8A—C8—H8B	109.5	Cu5vi—I6—Cu6	61.52 (4)
C7—C8—H8C	109.5	Cu5—I6—Cu6	61.48 (4)
H8A—C8—H8C	109.5	P6—Cu5—I6v	106.29 (9)
H8B—C8—H8C	109.5	P6—Cu5—I6	107.47 (9)
C10—C9—P2	115.5 (8)	I6v—Cu5—I6	112.44 (5)
C10—C9—H9A	108.4	P6—Cu5—I5	106.98 (8)
P2—C9—H9A	108.4	I6v—Cu5—I5	111.68 (5)
C10—C9—H9B	108.4	I6—Cu5—I5	111.58 (5)
P2—C9—H9B	108.4	P6—Cu5—Cu6	145.00 (9)
H9A—C9—H9B	107.5	I6v—Cu5—Cu6	59.37 (3)
C9—C10—C11	113.3 (10)	I6—Cu5—Cu6	59.33 (3)
C9—C10—H10A	108.9	I5—Cu5—Cu6	108.02 (5)
C11—C10—H10A	108.9	P6—Cu5—Cu5vi	145.35 (11)
C9—C10—H10B	108.9	I6v—Cu5—Cu5vi	108.36 (5)
C11—C10—H10B	108.9	I6—Cu5—Cu5vi	58.81 (5)
H10A—C10—H10B	107.7	I5—Cu5—Cu5vi	59.15 (2)
C12—C11—C10	113.4 (11)	Cu6—Cu5—Cu5vi	59.66 (3)
C12—C11—H11A	108.9	P6—Cu5—Cu5v	144.26 (10)
C10—C11—H11A	108.9	I6v—Cu5—Cu5v	58.92 (5)
C12—C11—H11B	108.9	I6—Cu5—Cu5v	108.26 (5)
C10—C11—H11B	108.9	I5—Cu5—Cu5v	59.15 (2)
H11A—C11—H11B	107.7	Cu6—Cu5—Cu5v	59.66 (3)
C11—C12—H12A	109.5	Cu5vi—Cu5—Cu5v	60.0
C11—C12—H12B	109.5	P5—Cu6—I6	106.70 (4)
H12A—C12—H12B	109.5	P5—Cu6—I6vi	106.70 (4)
C11—C12—H12C	109.5	I6—Cu6—I6vi	112.10 (3)
H12A—C12—H12C	109.5	P5—Cu6—I6v	106.70 (4)
H12B—C12—H12C	109.5	I6—Cu6—I6v	112.10 (3)
C14—C13—P2	112.4 (7)	I6vi—Cu6—I6v	112.09 (3)
C14—C13—H13A	109.1	P5—Cu6—Cu5	144.32 (3)
P2—C13—H13A	109.1	I6—Cu6—Cu5	59.19 (4)
C14—C13—H13B	109.1	I6vi—Cu6—Cu5	108.98 (6)
P2—C13—H13B	109.1	I6v—Cu6—Cu5	59.12 (4)
H13A—C13—H13B	107.9	P5—Cu6—Cu5v	144.32 (3)
C13—C14—C15	112.9 (10)	I6—Cu6—Cu5v	108.98 (6)
C13—C14—H14A	109.0	I6vi—Cu6—Cu5v	59.11 (4)
C15—C14—H14A	109.0	I6v—Cu6—Cu5v	59.19 (4)
C13—C14—H14B	109.0	Cu5—Cu6—Cu5v	60.68 (6)
C15—C14—H14B	109.0	P5—Cu6—Cu5vi	144.32 (3)
H14A—C14—H14B	107.8	I6—Cu6—Cu5vi	59.12 (4)
C16—C15—C14	112.2 (14)	I6vi—Cu6—Cu5vi	59.19 (4)
C16—C15—H15A	109.2	I6v—Cu6—Cu5vi	108.98 (6)
C14—C15—H15A	109.2	Cu5—Cu6—Cu5vi	60.68 (6)
C16—C15—H15B	109.2	Cu5v—Cu6—Cu5vi	60.68 (6)
C14—C15—H15B	109.2	C33v—P5—C33	102.6 (4)
H15A—C15—H15B	107.9	C33v—P5—C33vi	102.5 (4)
C15—C16—H16A	109.5	C33—P5—C33vi	102.6 (4)
C15—C16—H16B	109.5	C33v—P5—Cu6	115.7 (4)
H16A—C16—H16B	109.5	C33—P5—Cu6	115.7 (3)
C15—C16—H16C	109.5	C33vi—P5—Cu6	115.7 (3)
H16A—C16—H16C	109.5	C34—C33—P5	115.8 (8)
H16B—C16—H16C	109.5	C34—C33—H33A	108.3
Cu3iii—I3—Cu3	61.76 (5)	P5—C33—H33A	108.3
Cu3iii—I3—Cu3iv	61.76 (5)	C34—C33—H33B	108.3
Cu3—I3—Cu3iv	61.76 (5)	P5—C33—H33B	108.3
Cu3—I4—Cu3iii	61.96 (5)	H33A—C33—H33B	107.4
Cu3—I4—Cu4	61.15 (4)	C35—C34—C33	113.0 (10)
Cu3iii—I4—Cu4	61.13 (5)	C35—C34—H34A	109.0
P3—Cu3—I4	105.29 (10)	C33—C34—H34A	109.0
P3—Cu3—I4iv	105.90 (11)	C35—C34—H34B	109.0
I4—Cu3—I4iv	112.59 (5)	C33—C34—H34B	109.0
P3—Cu3—I3	109.23 (10)	H34A—C34—H34B	107.8
I4—Cu3—I3	111.73 (5)	C34—C35—C36	110.6 (11)
I4iv—Cu3—I3	111.68 (5)	C34—C35—H35A	109.5
P3—Cu3—Cu4	142.84 (10)	C36—C35—H35A	109.5
I4—Cu3—Cu4	59.51 (3)	C34—C35—H35B	109.5
I4iv—Cu3—Cu4	59.50 (3)	C36—C35—H35B	109.5
I3—Cu3—Cu4	107.93 (5)	H35A—C35—H35B	108.1
P3—Cu3—Cu3iii	145.57 (12)	C35—C36—H36A	109.5
I4—Cu3—Cu3iii	59.04 (5)	C35—C36—H36B	109.5
I4iv—Cu3—Cu3iii	108.47 (5)	H36A—C36—H36B	109.5
I3—Cu3—Cu3iii	59.12 (2)	C35—C36—H36C	109.5
Cu4—Cu3—Cu3iii	59.62 (3)	H36A—C36—H36C	109.5
P3—Cu3—Cu3iv	146.15 (11)	H36B—C36—H36C	109.5
I4—Cu3—Cu3iv	108.51 (5)	C45—P6—C41	102.1 (5)
I4iv—Cu3—Cu3iv	58.99 (5)	C45—P6—C37	101.0 (8)
I3—Cu3—Cu3iv	59.12 (2)	C41—P6—C37	114.8 (8)
Cu4—Cu3—Cu3iv	59.62 (3)	C45—P6—C37A	105.8 (8)
Cu3iii—Cu3—Cu3iv	60.0	C41—P6—C37A	90.5 (7)
P4—Cu4—I4iii	106.43 (4)	C37—P6—C37A	24.4 (7)
P4—Cu4—I4	106.43 (4)	C45—P6—Cu5	115.5 (5)
I4iii—Cu4—I4	112.33 (4)	C41—P6—Cu5	114.4 (4)
P4—Cu4—I4iv	106.43 (4)	C37—P6—Cu5	108.3 (6)
I4iii—Cu4—I4iv	112.33 (4)	C37A—P6—Cu5	124.0 (8)
I4—Cu4—I4iv	112.33 (4)	C38—C37—P6	124.2 (15)
P4—Cu4—Cu3iii	144.28 (3)	C38—C37—H37A	106.3
I4iii—Cu4—Cu3iii	59.34 (4)	P6—C37—H37A	106.3
I4—Cu4—Cu3iii	59.37 (4)	C38—C37—H37B	106.3
I4iv—Cu4—Cu3iii	109.29 (7)	P6—C37—H37B	106.3
P4—Cu4—Cu3iv	144.27 (3)	H37A—C37—H37B	106.4
I4iii—Cu4—Cu3iv	59.37 (4)	C37—C38—C39	104.7 (14)
I4—Cu4—Cu3iv	109.29 (7)	C37—C38—H38A	110.8
I4iv—Cu4—Cu3iv	59.34 (4)	C39—C38—H38A	110.8
Cu3iii—Cu4—Cu3iv	60.75 (6)	C37—C38—H38B	110.8
P4—Cu4—Cu3	144.27 (3)	C39—C38—H38B	110.8
I4iii—Cu4—Cu3	109.29 (7)	H38A—C38—H38B	108.9
I4—Cu4—Cu3	59.34 (4)	C38A—C37A—P6	111.7 (14)
I4iv—Cu4—Cu3	59.38 (4)	C38A—C37A—H37C	109.3
Cu3iii—Cu4—Cu3	60.75 (6)	P6—C37A—H37C	109.3
Cu3iv—Cu4—Cu3	60.75 (6)	C38A—C37A—H37D	109.3
C21A—P3—C17	77.3 (15)	P6—C37A—H37D	109.3
C21A—P3—C25	106.9 (10)	H37C—C37A—H37D	107.9
C17—P3—C25	99.5 (8)	C37A—C38A—C39	111.2 (15)
C21A—P3—C21	22.1 (11)	C37A—C38A—H38C	109.4
C17—P3—C21	99.2 (11)	C39—C38A—H38C	109.4
C25—P3—C21	100.5 (6)	C37A—C38A—H38D	109.4
C21A—P3—C17A	103.4 (17)	C39—C38A—H38D	109.4
C17—P3—C17A	29.8 (7)	H38C—C38A—H38D	108.0
C25—P3—C17A	105.3 (8)	C40—C39—C38A	134.3 (18)
C21—P3—C17A	125.3 (12)	C40—C39—C38	89.6 (15)
C21A—P3—Cu3	123.4 (9)	C38A—C39—C38	45.9 (11)
C17—P3—Cu3	127.0 (7)	C40—C39—H39A	113.7
C25—P3—Cu3	115.5 (4)	C38A—C39—H39A	96.8
C21—P3—Cu3	111.1 (9)	C38—C39—H39A	113.7
C17A—P3—Cu3	99.9 (6)	C40—C39—H39B	113.7
C18—C17—P3	112.9 (12)	C38A—C39—H39B	83.1
C18—C17—H17A	109.0	C38—C39—H39B	113.7
P3—C17—H17A	109.0	H39A—C39—H39B	111.0
C18—C17—H17B	109.0	C40—C39—H39C	103.6
P3—C17—H17B	109.0	C38A—C39—H39C	103.6
H17A—C17—H17B	107.8	C38—C39—H39C	112.9
C17—C18—C19	111.2 (12)	H39A—C39—H39C	10.3
C17—C18—H18A	109.4	H39B—C39—H39C	119.0
C19—C18—H18A	109.4	C40—C39—H39D	103.6
C17—C18—H18B	109.4	C38A—C39—H39D	103.6
C19—C18—H18B	109.4	C38—C39—H39D	135.2
H18A—C18—H18B	108.0	H39A—C39—H39D	99.9
C18A—C17A—P3	109.1 (14)	H39B—C39—H39D	22.2
C18A—C17A—H17C	109.9	H39C—C39—H39D	105.3
P3—C17A—H17C	109.9	C39—C40—H40A	109.5
C18A—C17A—H17D	109.9	C39—C40—H40B	109.5
P3—C17A—H17D	109.9	H40A—C40—H40B	109.5
H17C—C17A—H17D	108.3	C39—C40—H40C	109.5
C17A—C18A—C19	90.4 (14)	H40A—C40—H40C	109.5
C17A—C18A—H18C	113.6	H40B—C40—H40C	109.5
C19—C18A—H18C	113.6	C42—C41—P6	114.3 (8)
C17A—C18A—H18D	113.6	C42—C41—H41A	108.7
C19—C18A—H18D	113.6	P6—C41—H41A	108.7
H18C—C18A—H18D	110.8	C42—C41—H41B	108.7
C20—C19—C18A	89.4 (13)	P6—C41—H41B	108.7
C20—C19—C18	125.6 (15)	H41A—C41—H41B	107.6
C18A—C19—C18	41.6 (10)	C41—C42—C43	112.8 (11)
C20—C19—H19A	105.9	C41—C42—H42A	109.0
C18A—C19—H19A	101.5	C43—C42—H42A	109.0
C18—C19—H19A	105.9	C41—C42—H42B	109.0
C20—C19—H19B	105.9	C43—C42—H42B	109.0
C18A—C19—H19B	142.8	H42A—C42—H42B	107.8
C18—C19—H19B	105.9	C44—C43—C42	111.3 (12)
H19A—C19—H19B	106.3	C44—C43—H43A	109.4
C20—C19—H19C	113.7	C42—C43—H43A	109.4
C18A—C19—H19C	113.7	C44—C43—H43B	109.4
C18—C19—H19C	108.5	C42—C43—H43B	109.4
H19A—C19—H19C	15.3	H43A—C43—H43B	108.0
H19B—C19—H19C	91.2	C43—C44—H44A	109.5
C20—C19—H19D	113.7	C43—C44—H44B	109.5
C18A—C19—H19D	113.7	H44A—C44—H44B	109.5
C18—C19—H19D	79.4	C43—C44—H44C	109.5
H19A—C19—H19D	126.0	H44A—C44—H44C	109.5
H19B—C19—H19D	29.1	H44B—C44—H44C	109.5
H19C—C19—H19D	111.0	C46—C45—P6	115.1 (8)
C19—C20—H20A	109.5	C46—C45—H45A	108.5
C19—C20—H20B	109.5	P6—C45—H45A	108.5
H20A—C20—H20B	109.5	C46—C45—H45B	108.5
C19—C20—H20C	109.5	P6—C45—H45B	108.5
H20A—C20—H20C	109.5	H45A—C45—H45B	107.5
H20B—C20—H20C	109.5	C45—C46—C47	114.9 (10)
C22—C21—P3	107.2 (14)	C45—C46—H46A	108.5
C22—C21—H21A	110.3	C47—C46—H46A	108.5
P3—C21—H21A	110.3	C45—C46—H46B	108.5
C22—C21—H21B	110.3	C47—C46—H46B	108.5
P3—C21—H21B	110.3	H46A—C46—H46B	107.5
H21A—C21—H21B	108.5	C46—C47—C48	113.8 (11)
C22—C21A—P3	127.9 (19)	C46—C47—H47A	108.8
C22—C21A—H21C	105.3	C48—C47—H47A	108.8
P3—C21A—H21C	105.3	C46—C47—H47B	108.8
C22—C21A—H21D	105.3	C48—C47—H47B	108.8
P3—C21A—H21D	105.3	H47A—C47—H47B	107.7
H21C—C21A—H21D	106.0	C47—C48—H48A	109.5
C21A—C22—C21	28.5 (10)	C47—C48—H48B	109.5
C21A—C22—C23	139.8 (18)	H48A—C48—H48B	109.5
C21—C22—C23	115.0 (17)	C47—C48—H48C	109.5
C21A—C22—H22A	84.4	H48A—C48—H48C	109.5
C21—C22—H22A	108.5	H48B—C48—H48C	109.5
Cu1i—I1—Cu1—P2	−141.25 (7)	I4—Cu3—P3—C17A	−89.2 (9)
Cu2—I1—Cu1—P2	146.80 (7)	I4iv—Cu3—P3—C17A	30.3 (9)
Cu1i—I1—Cu1—I1ii	99.56 (4)	I3—Cu3—P3—C17A	150.7 (9)
Cu2—I1—Cu1—I1ii	27.61 (3)	Cu4—Cu3—P3—C17A	−29.8 (9)
Cu1i—I1—Cu1—I2	−28.30 (4)	Cu3iii—Cu3—P3—C17A	−146.2 (9)
Cu2—I1—Cu1—I2	−100.25 (4)	Cu3iv—Cu3—P3—C17A	87.8 (9)
Cu1i—I1—Cu1—Cu1ii	35.178 (18)	C21A—P3—C17—C18	−178.8 (18)
Cu2—I1—Cu1—Cu1ii	−36.77 (3)	C25—P3—C17—C18	−73.5 (16)
Cu2—I1—Cu1—Cu1i	−71.95 (3)	C21—P3—C17—C18	−175.9 (15)
Cu1i—I1—Cu1—Cu2	71.95 (3)	C17A—P3—C17—C18	30.7 (17)
Cu1ii—I2—Cu1—P2	−147.60 (9)	Cu3—P3—C17—C18	58.8 (17)
Cu1i—I2—Cu1—P2	141.49 (9)	P3—C17—C18—C19	−171.3 (13)
Cu1ii—I2—Cu1—I1ii	−28.89 (4)	C21A—P3—C17A—C18A	−63 (2)
Cu1i—I2—Cu1—I1ii	−99.80 (3)	C17—P3—C17A—C18A	−33.8 (17)
Cu1ii—I2—Cu1—I1	98.76 (3)	C25—P3—C17A—C18A	49 (2)
Cu1i—I2—Cu1—I1	27.86 (4)	C21—P3—C17A—C18A	−67 (2)
Cu1i—I2—Cu1—Cu1ii	−70.907 (16)	Cu3—P3—C17A—C18A	168.6 (18)
Cu1ii—I2—Cu1—Cu1i	70.907 (16)	P3—C17A—C18A—C19	179.1 (15)
Cu1ii—I2—Cu1—Cu2	35.453 (8)	C17A—C18A—C19—C20	−175.6 (19)
Cu1i—I2—Cu1—Cu2	−35.454 (8)	C17A—C18A—C19—C18	31.7 (14)
Cu1i—I1—Cu2—P1	144.67 (3)	C17—C18—C19—C20	−76 (2)
Cu1—I1—Cu2—P1	−144.26 (3)	C17—C18—C19—C18A	−42.1 (17)
Cu1i—I1—Cu2—I1i	27.29 (4)	C21A—P3—C21—C22	−55 (2)
Cu1—I1—Cu2—I1i	98.36 (5)	C17—P3—C21—C22	−62.2 (18)
Cu1i—I1—Cu2—I1ii	−97.95 (5)	C25—P3—C21—C22	−163.8 (15)
Cu1—I1—Cu2—I1ii	−26.88 (4)	C17A—P3—C21—C22	−46 (2)
Cu1i—I1—Cu2—Cu1ii	−34.60 (4)	Cu3—P3—C21—C22	73.5 (18)
Cu1—I1—Cu2—Cu1ii	36.47 (4)	C17—P3—C21A—C22	−103 (3)
Cu1—I1—Cu2—Cu1i	71.07 (5)	C25—P3—C21A—C22	161 (3)
Cu1i—I1—Cu2—Cu1	−71.07 (5)	C21—P3—C21A—C22	85 (3)
P2—Cu1—Cu2—P1	5.30 (15)	C17A—P3—C21A—C22	−88 (3)
I1ii—Cu1—Cu2—P1	−74.04 (4)	Cu3—P3—C21A—C22	23 (4)
I1—Cu1—Cu2—P1	76.24 (4)	P3—C21A—C22—C21	−99 (4)
I2—Cu1—Cu2—P1	180.0	P3—C21A—C22—C23	−135 (3)
Cu1ii—Cu1—Cu2—P1	−144.816 (9)	P3—C21—C22—C21A	42 (3)
Cu1i—Cu1—Cu2—P1	144.815 (9)	P3—C21—C22—C23	−162.5 (15)
P2—Cu1—Cu2—I1i	−175.92 (13)	C21A—C22—C23—C24	−30 (4)
I1ii—Cu1—Cu2—I1i	104.743 (17)	C21—C22—C23—C24	−48 (3)
I1—Cu1—Cu2—I1i	−104.973 (17)	C21A—P3—C25—C26	−80.9 (17)
I2—Cu1—Cu2—I1i	−1.22 (4)	C17—P3—C25—C26	−160.4 (10)
Cu1ii—Cu1—Cu2—I1i	33.97 (4)	C21—P3—C25—C26	−59.1 (14)
Cu1i—Cu1—Cu2—I1i	−36.40 (4)	C17A—P3—C25—C26	169.6 (11)
P2—Cu1—Cu2—I1	−70.94 (13)	Cu3—P3—C25—C26	60.5 (10)
I1ii—Cu1—Cu2—I1	−150.28 (3)	P3—C25—C26—C27	−169.4 (10)
I2—Cu1—Cu2—I1	103.76 (4)	C25—C26—C27—C28	−165.3 (16)
Cu1ii—Cu1—Cu2—I1	138.94 (4)	C25—C26—C27—C28A	−92.2 (17)
Cu1i—Cu1—Cu2—I1	68.57 (4)	I4iii—Cu4—P4—C29iv	29.3 (5)
P2—Cu1—Cu2—I1ii	79.34 (13)	I4—Cu4—P4—C29iv	−90.7 (5)
I1—Cu1—Cu2—I1ii	150.28 (3)	I4iv—Cu4—P4—C29iv	149.3 (5)
I2—Cu1—Cu2—I1ii	−105.96 (4)	Cu3iii—Cu4—P4—C29iv	−30.6 (5)
Cu1ii—Cu1—Cu2—I1ii	−70.78 (4)	Cu3iv—Cu4—P4—C29iv	89.4 (5)
Cu1i—Cu1—Cu2—I1ii	−141.14 (4)	Cu3—Cu4—P4—C29iv	−150.6 (5)
P2—Cu1—Cu2—Cu1ii	150.12 (15)	I4iii—Cu4—P4—C29	−90.7 (5)
I1ii—Cu1—Cu2—Cu1ii	70.78 (4)	I4—Cu4—P4—C29	149.3 (5)
I1—Cu1—Cu2—Cu1ii	−138.94 (4)	I4iv—Cu4—P4—C29	29.3 (5)
I2—Cu1—Cu2—Cu1ii	−35.184 (9)	Cu3iii—Cu4—P4—C29	−150.6 (5)
Cu1i—Cu1—Cu2—Cu1ii	−70.369 (17)	Cu3iv—Cu4—P4—C29	−30.6 (5)
P2—Cu1—Cu2—Cu1i	−139.51 (15)	Cu3—Cu4—P4—C29	89.4 (5)
I1ii—Cu1—Cu2—Cu1i	141.14 (4)	I4iii—Cu4—P4—C29iii	149.3 (5)
I1—Cu1—Cu2—Cu1i	−68.57 (4)	I4—Cu4—P4—C29iii	29.3 (5)
I2—Cu1—Cu2—Cu1i	35.185 (9)	I4iv—Cu4—P4—C29iii	−90.7 (5)
Cu1ii—Cu1—Cu2—Cu1i	70.369 (17)	Cu3iii—Cu4—P4—C29iii	89.4 (5)
I1i—Cu2—P1—C1	101.6 (3)	Cu3iv—Cu4—P4—C29iii	−150.6 (5)
I1—Cu2—P1—C1	−18.4 (3)	Cu3—Cu4—P4—C29iii	−30.6 (5)
I1ii—Cu2—P1—C1	−138.4 (3)	C29iv—P4—C29—C30	−72.3 (11)
Cu1ii—Cu2—P1—C1	160.4 (3)	C29iii—P4—C29—C30	−179.1 (8)
Cu1i—Cu2—P1—C1	40.4 (3)	Cu4—P4—C29—C30	54.3 (9)
Cu1—Cu2—P1—C1	−79.6 (3)	P4—C29—C30—C31	178.9 (9)
I1i—Cu2—P1—C1i	−18.4 (3)	C29—C30—C31—C32	−177.6 (12)
I1—Cu2—P1—C1i	−138.4 (3)	Cu5vi—I6—Cu5—P6	144.84 (10)
I1ii—Cu2—P1—C1i	101.6 (3)	Cu6—I6—Cu5—P6	−144.27 (10)
Cu1ii—Cu2—P1—C1i	40.4 (3)	Cu5vi—I6—Cu5—I6v	−98.53 (5)
Cu1i—Cu2—P1—C1i	−79.6 (3)	Cu6—I6—Cu5—I6v	−27.64 (4)
Cu1—Cu2—P1—C1i	160.4 (3)	Cu5vi—I6—Cu5—I5	27.86 (5)
I1i—Cu2—P1—C1ii	−138.4 (3)	Cu6—I6—Cu5—I5	98.75 (5)
I1—Cu2—P1—C1ii	101.6 (3)	Cu5vi—I6—Cu5—Cu6	−70.89 (4)
I1ii—Cu2—P1—C1ii	−18.4 (3)	Cu6—I6—Cu5—Cu5vi	70.89 (4)
Cu1ii—Cu2—P1—C1ii	−79.6 (3)	Cu5vi—I6—Cu5—Cu5v	−35.39 (2)
Cu1i—Cu2—P1—C1ii	160.4 (3)	Cu6—I6—Cu5—Cu5v	35.50 (4)
Cu1—Cu2—P1—C1ii	40.4 (3)	Cu5v—I5—Cu5—P6	143.73 (12)
C1i—P1—C1—C2	66.6 (9)	Cu5vi—I5—Cu5—P6	−145.04 (12)
C1ii—P1—C1—C2	172.8 (6)	Cu5v—I5—Cu5—I6v	27.81 (5)
Cu2—P1—C1—C2	−60.3 (7)	Cu5vi—I5—Cu5—I6v	99.05 (4)
P1—C1—C2—C3	171.1 (6)	Cu5v—I5—Cu5—I6	−98.99 (4)
C1—C2—C3—C4	175.1 (8)	Cu5vi—I5—Cu5—I6	−27.75 (5)
I1ii—Cu1—P2—C13	94.7 (3)	Cu5v—I5—Cu5—Cu6	−35.619 (10)
I1—Cu1—P2—C13	−26.7 (3)	Cu5vi—I5—Cu5—Cu6	35.619 (10)
I2—Cu1—P2—C13	−144.2 (3)	Cu5v—I5—Cu5—Cu5vi	−71.238 (19)
Cu1ii—Cu1—P2—C13	159.4 (3)	Cu5vi—I5—Cu5—Cu5v	71.238 (19)
Cu1i—Cu1—P2—C13	−85.0 (3)	Cu5vi—I6—Cu6—P5	−143.97 (3)
Cu2—Cu1—P2—C13	30.7 (4)	Cu5—I6—Cu6—P5	143.95 (3)
I1ii—Cu1—P2—C5	−147.2 (3)	Cu5vi—I6—Cu6—I6vi	−27.51 (5)
I1—Cu1—P2—C5	91.4 (3)	Cu5—I6—Cu6—I6vi	−99.59 (7)
I2—Cu1—P2—C5	−26.0 (3)	Cu5vi—I6—Cu6—I6v	99.57 (7)
Cu1ii—Cu1—P2—C5	−82.4 (4)	Cu5—I6—Cu6—I6v	27.49 (5)
Cu1i—Cu1—P2—C5	33.1 (4)	Cu5vi—I6—Cu6—Cu5	72.08 (6)
Cu2—Cu1—P2—C5	148.8 (3)	Cu5vi—I6—Cu6—Cu5v	35.98 (5)
I1ii—Cu1—P2—C9	−25.4 (4)	Cu5—I6—Cu6—Cu5v	−36.09 (5)
I1—Cu1—P2—C9	−146.8 (4)	Cu5—I6—Cu6—Cu5vi	−72.08 (6)
I2—Cu1—P2—C9	95.8 (4)	P6—Cu5—Cu6—P5	1.1 (2)
Cu1ii—Cu1—P2—C9	39.4 (4)	I6v—Cu5—Cu6—P5	75.00 (5)
Cu1i—Cu1—P2—C9	154.9 (3)	I6—Cu5—Cu6—P5	−75.12 (5)
Cu2—Cu1—P2—C9	−89.4 (4)	I5—Cu5—Cu6—P5	180.0
C13—P2—C5—C6	67.1 (8)	Cu5vi—Cu5—Cu6—P5	−144.596 (12)
C9—P2—C5—C6	172.5 (7)	Cu5v—Cu5—Cu6—P5	144.597 (12)
Cu1—P2—C5—C6	−57.7 (7)	P6—Cu5—Cu6—I6	76.21 (17)
P2—C5—C6—C7	161.1 (8)	I6v—Cu5—Cu6—I6	150.11 (4)
C5—C6—C7—C8	56.1 (14)	I5—Cu5—Cu6—I6	−104.88 (5)
C13—P2—C9—C10	173.1 (8)	Cu5vi—Cu5—Cu6—I6	−69.48 (6)
C5—P2—C9—C10	67.0 (9)	Cu5v—Cu5—Cu6—I6	−140.29 (5)
Cu1—P2—C9—C10	−60.3 (8)	P6—Cu5—Cu6—I6vi	−178.84 (17)
P2—C9—C10—C11	−177.4 (8)	I6v—Cu5—Cu6—I6vi	−104.93 (2)
C9—C10—C11—C12	65.7 (14)	I6—Cu5—Cu6—I6vi	104.95 (2)
C5—P2—C13—C14	174.2 (8)	I5—Cu5—Cu6—I6vi	0.07 (5)
C9—P2—C13—C14	67.6 (8)	Cu5vi—Cu5—Cu6—I6vi	35.47 (6)
Cu1—P2—C13—C14	−61.3 (8)	Cu5v—Cu5—Cu6—I6vi	−35.33 (5)
P2—C13—C14—C15	174.3 (9)	P6—Cu5—Cu6—I6v	−73.90 (17)
C13—C14—C15—C16	−70.2 (18)	I6—Cu5—Cu6—I6v	−150.11 (4)
Cu3iii—I4—Cu3—P3	−146.42 (11)	I5—Cu5—Cu6—I6v	105.00 (5)
Cu4—I4—Cu3—P3	142.92 (11)	Cu5vi—Cu5—Cu6—I6v	140.41 (5)
Cu3iii—I4—Cu3—I4iv	98.66 (5)	Cu5v—Cu5—Cu6—I6v	69.60 (5)
Cu4—I4—Cu3—I4iv	28.00 (4)	P6—Cu5—Cu6—Cu5v	−143.5 (2)
Cu3iii—I4—Cu3—I3	−27.96 (5)	I6v—Cu5—Cu6—Cu5v	−69.60 (5)
Cu4—I4—Cu3—I3	−98.62 (5)	I6—Cu5—Cu6—Cu5v	140.29 (5)
Cu3iii—I4—Cu3—Cu4	70.66 (4)	I5—Cu5—Cu6—Cu5v	35.403 (12)
Cu4—I4—Cu3—Cu3iii	−70.66 (4)	Cu5vi—Cu5—Cu6—Cu5v	70.81 (2)
Cu3iii—I4—Cu3—Cu3iv	35.35 (2)	P6—Cu5—Cu6—Cu5vi	145.7 (2)
Cu4—I4—Cu3—Cu3iv	−35.31 (4)	I6v—Cu5—Cu6—Cu5vi	−140.41 (5)
Cu3iii—I3—Cu3—P3	144.02 (13)	I6—Cu5—Cu6—Cu5vi	69.48 (6)
Cu3iv—I3—Cu3—P3	−144.71 (13)	I5—Cu5—Cu6—Cu5vi	−35.404 (12)
Cu3iii—I3—Cu3—I4	27.94 (5)	Cu5v—Cu5—Cu6—Cu5vi	−70.81 (2)
Cu3iv—I3—Cu3—I4	99.20 (4)	I6—Cu6—P5—C33v	−37.2 (4)
Cu3iii—I3—Cu3—I4iv	−99.18 (4)	I6vi—Cu6—P5—C33v	−157.2 (4)
Cu3iv—I3—Cu3—I4iv	−27.91 (5)	I6v—Cu6—P5—C33v	82.8 (4)
Cu3iii—I3—Cu3—Cu4	−35.632 (10)	Cu5—Cu6—P5—C33v	22.9 (4)
Cu3iv—I3—Cu3—Cu4	35.634 (10)	Cu5v—Cu6—P5—C33v	142.9 (4)
Cu3iv—I3—Cu3—Cu3iii	71.27 (2)	Cu5vi—Cu6—P5—C33v	−97.1 (4)
Cu3iii—I3—Cu3—Cu3iv	−71.27 (2)	I6—Cu6—P5—C33	82.8 (5)
Cu3—I4—Cu4—P4	−144.01 (3)	I6vi—Cu6—P5—C33	−37.2 (5)
Cu3iii—I4—Cu4—P4	144.00 (3)	I6v—Cu6—P5—C33	−157.2 (5)
Cu3—I4—Cu4—I4iii	99.89 (7)	Cu5—Cu6—P5—C33	142.9 (5)
Cu3iii—I4—Cu4—I4iii	27.89 (5)	Cu5v—Cu6—P5—C33	−97.1 (5)
Cu3—I4—Cu4—I4iv	−27.91 (5)	Cu5vi—Cu6—P5—C33	22.9 (5)
Cu3iii—I4—Cu4—I4iv	−99.90 (7)	I6—Cu6—P5—C33vi	−157.2 (4)
Cu3—I4—Cu4—Cu3iii	71.99 (6)	I6vi—Cu6—P5—C33vi	82.8 (4)
Cu3—I4—Cu4—Cu3iv	35.97 (5)	I6v—Cu6—P5—C33vi	−37.2 (4)
Cu3iii—I4—Cu4—Cu3iv	−36.02 (5)	Cu5—Cu6—P5—C33vi	−97.1 (4)
Cu3iii—I4—Cu4—Cu3	−71.99 (6)	Cu5v—Cu6—P5—C33vi	22.9 (4)
P3—Cu3—Cu4—P4	0.5 (2)	Cu5vi—Cu6—P5—C33vi	142.9 (4)
I4—Cu3—Cu4—P4	74.87 (5)	C33v—P5—C33—C34	77.5 (12)
I4iv—Cu3—Cu4—P4	−74.93 (5)	C33vi—P5—C33—C34	−176.4 (8)
I3—Cu3—Cu4—P4	180.000 (2)	Cu6—P5—C33—C34	−49.4 (10)
Cu3iii—Cu3—Cu4—P4	144.581 (12)	P5—C33—C34—C35	−176.0 (9)
Cu3iv—Cu3—Cu4—P4	−144.578 (12)	C33—C34—C35—C36	−177.2 (11)
P3—Cu3—Cu4—I4iii	−179.43 (18)	I6v—Cu5—P6—C45	21.6 (4)
I4—Cu3—Cu4—I4iii	−105.10 (2)	I6—Cu5—P6—C45	142.2 (4)
I4iv—Cu3—Cu4—I4iii	105.10 (2)	I5—Cu5—P6—C45	−97.8 (4)
I3—Cu3—Cu4—I4iii	0.03 (5)	Cu6—Cu5—P6—C45	81.1 (4)
Cu3iii—Cu3—Cu4—I4iii	−35.39 (5)	Cu5vi—Cu5—P6—C45	−157.8 (4)
Cu3iv—Cu3—Cu4—I4iii	35.45 (5)	Cu5v—Cu5—P6—C45	−37.4 (5)
P3—Cu3—Cu4—I4	−74.33 (18)	I6v—Cu5—P6—C41	139.7 (4)
I4iv—Cu3—Cu4—I4	−149.80 (4)	I6—Cu5—P6—C41	−99.7 (4)
I3—Cu3—Cu4—I4	105.13 (5)	I5—Cu5—P6—C41	20.3 (4)
Cu3iii—Cu3—Cu4—I4	69.71 (5)	Cu6—Cu5—P6—C41	−160.8 (4)
Cu3iv—Cu3—Cu4—I4	140.55 (5)	Cu5vi—Cu5—P6—C41	−39.6 (5)
P3—Cu3—Cu4—I4iv	75.47 (18)	Cu5v—Cu5—P6—C41	80.7 (4)
I4—Cu3—Cu4—I4iv	149.80 (4)	I6v—Cu5—P6—C37	−90.7 (8)
I3—Cu3—Cu4—I4iv	−105.07 (5)	I6—Cu5—P6—C37	29.9 (8)
Cu3iii—Cu3—Cu4—I4iv	−140.49 (5)	I5—Cu5—P6—C37	149.8 (8)
Cu3iv—Cu3—Cu4—I4iv	−69.65 (5)	Cu6—Cu5—P6—C37	−31.3 (8)
P3—Cu3—Cu4—Cu3iii	−144.0 (2)	Cu5vi—Cu5—P6—C37	89.9 (8)
I4—Cu3—Cu4—Cu3iii	−69.71 (5)	Cu5v—Cu5—P6—C37	−149.8 (8)
I4iv—Cu3—Cu4—Cu3iii	140.49 (5)	I6v—Cu5—P6—C37A	−111.7 (7)
I3—Cu3—Cu4—Cu3iii	35.419 (12)	I6—Cu5—P6—C37A	8.8 (7)
Cu3iv—Cu3—Cu4—Cu3iii	70.84 (2)	I5—Cu5—P6—C37A	128.8 (7)
P3—Cu3—Cu4—Cu3iv	145.1 (2)	Cu6—Cu5—P6—C37A	−52.3 (8)
I4—Cu3—Cu4—Cu3iv	−140.55 (5)	Cu5vi—Cu5—P6—C37A	68.9 (8)
I4iv—Cu3—Cu4—Cu3iv	69.65 (5)	Cu5v—Cu5—P6—C37A	−170.8 (7)
I3—Cu3—Cu4—Cu3iv	−35.422 (11)	C45—P6—C37—C38	61 (2)
Cu3iii—Cu3—Cu4—Cu3iv	−70.84 (2)	C41—P6—C37—C38	−48 (2)
I4—Cu3—P3—C21A	157.5 (17)	C37A—P6—C37—C38	−43 (2)
I4iv—Cu3—P3—C21A	−83.0 (17)	Cu5—P6—C37—C38	−177.2 (19)
I3—Cu3—P3—C21A	37.4 (17)	P6—C37—C38—C39	−176.6 (16)
Cu4—Cu3—P3—C21A	−143.2 (17)	C45—P6—C37A—C38A	−64.0 (19)
Cu3iii—Cu3—P3—C21A	100.5 (17)	C41—P6—C37A—C38A	−166.7 (18)
Cu3iv—Cu3—P3—C21A	−25.5 (17)	C37—P6—C37A—C38A	18 (2)
I4—Cu3—P3—C17	−102.9 (7)	Cu5—P6—C37A—C38A	73.0 (19)
I4iv—Cu3—P3—C17	16.6 (7)	P6—C37A—C38A—C39	173.9 (15)
I3—Cu3—P3—C17	137.0 (7)	C37A—C38A—C39—C40	−52 (3)
Cu4—Cu3—P3—C17	−43.6 (8)	C37A—C38A—C39—C38	−36.0 (18)
Cu3iii—Cu3—P3—C17	−159.9 (7)	C37—C38—C39—C40	−169.9 (19)
Cu3iv—Cu3—P3—C17	74.1 (7)	C37—C38—C39—C38A	21.7 (16)
I4—Cu3—P3—C25	23.1 (5)	C45—P6—C41—C42	−168.3 (9)
I4iv—Cu3—P3—C25	142.6 (4)	C37—P6—C41—C42	−60.0 (12)
I3—Cu3—P3—C25	−97.0 (4)	C37A—P6—C41—C42	−62.0 (12)
Cu4—Cu3—P3—C25	82.5 (5)	Cu5—P6—C41—C42	66.2 (10)
Cu3iii—Cu3—P3—C25	−33.9 (5)	P6—C41—C42—C43	−164.3 (9)
Cu3iv—Cu3—P3—C25	−159.9 (4)	C41—C42—C43—C44	−65.7 (15)
I4—Cu3—P3—C21	136.8 (7)	C41—P6—C45—C46	−62.1 (10)
I4iv—Cu3—P3—C21	−103.8 (7)	C37—P6—C45—C46	179.3 (11)
I3—Cu3—P3—C21	16.6 (7)	C37A—P6—C45—C46	−156.1 (10)
Cu4—Cu3—P3—C21	−163.9 (7)	Cu5—P6—C45—C46	62.7 (10)
Cu3iii—Cu3—P3—C21	79.7 (7)	P6—C45—C46—C47	−174.7 (9)
Cu3iv—Cu3—P3—C21	−46.3 (7)	C45—C46—C47—C48	178.7 (11)