Literature DB >> 24824200

Ruthenium-catalyzed cyclization of ketoxime acetates with DMF for synthesis of symmetrical pyridines.

Mi-Na Zhao1, Rong-Rong Hui, Zhi-Hui Ren, Yao-Yu Wang, Zheng-Hui Guan.   

Abstract

A novel ruthenium-catalyzed cyclization of ketoxime carboxylates with N,N-dimethylformamide (DMF) for the synthesis of tetrasubstituted symmetrical pyridines has been developed. A methyl carbon on DMF performed as a source of a one carbon synthon. And NaHSO3 plays a role in the reaction.

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Year:  2014        PMID: 24824200     DOI: 10.1021/ol501183z

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Beyond a solvent: triple roles of dimethylformamide in organic chemistry.

Authors:  Majid M Heravi; Mahdieh Ghavidel; Leyla Mohammadkhani
Journal:  RSC Adv       Date:  2018-08-03       Impact factor: 4.036

Review 2.  Recent Uses of N,N-Dimethylformamide and N,N-Dimethylacetamide as Reagents.

Authors:  Jean Le Bras; Jacques Muzart
Journal:  Molecules       Date:  2018-08-03       Impact factor: 4.411

  2 in total

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