Literature DB >> 24820402

An unexpected role of the monodentate ligand in photocatalytic hydrogen production of the pentadentate ligand-based cobalt complexes.

Jingfan Xie1, Qianxiong Zhou, Chao Li, Weibo Wang, Yuanjun Hou, Baowen Zhang, Xuesong Wang.   

Abstract

The dissociation of one pyridine of a pentadentate ligand (N4Py) from the Co centre was found to be responsible for the formation of a Co(III) hydride species, an indispensable intermediate for photocatalytic proton reduction.

Entities:  

Year:  2014        PMID： 24820402     DOI： 10.1039/c4cc01471e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported RuII complexes: comparison to bimetallic analogs.

Authors:  Sungho V Park; John F Berry
Journal:  Dalton Trans       Date:  2017-07-18       Impact factor: 4.390

2.  Recent Developments in Hydrogen Evolving Molecular Cobalt(II)-Polypyridyl Catalysts.

Authors:  N Queyriaux; R T Jane; J Massin; V Artero; M Chavarot-Kerlidou
Journal:  Coord Chem Rev       Date:  2015-12-01       Impact factor: 22.315

3.  Bioinspired design of redox-active ligands for multielectron catalysis: effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water.

Authors:  Jonah W Jurss; Rony S Khnayzer; Julien A Panetier; Karim A El Roz; Eva M Nichols; Martin Head-Gordon; Jeffrey R Long; Felix N Castellano; Christopher J Chang
Journal:  Chem Sci       Date:  2015-06-09       Impact factor: 9.825

4.  Enhancing H2 evolution performance of an immobilised cobalt catalyst by rational ligand design.

Authors:  Janina Willkomm; Nicoleta M Muresan; Erwin Reisner
Journal:  Chem Sci       Date:  2015-02-02       Impact factor: 9.825

5.  Dual cobalt-copper light-driven catalytic reduction of aldehydes and aromatic ketones in aqueous media.

Authors:  Arnau Call; Carla Casadevall; Ferran Acuña-Parés; Alicia Casitas; Julio Lloret-Fillol
Journal:  Chem Sci       Date:  2017-06-01       Impact factor: 9.825

6.  Importance of Metal-Ion Exchange for the Biological Activity of Coordination Complexes of the Biomimetic Ligand N4Py.

Authors:  Arjan Geersing; Nathalie Ségaud; Monique G P van der Wijst; Marianne G Rots; Gerard Roelfes
Journal:  Inorg Chem       Date:  2018-06-19       Impact factor: 5.165

7.  Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation.

Authors:  Debashis Basu; Shivnath Mazumder; Jens Niklas; Habib Baydoun; Dakshika Wanniarachchi; Xuetao Shi; Richard J Staples; Oleg Poluektov; H Bernhard Schlegel; Cláudio N Verani
Journal:  Chem Sci       Date:  2016-02-02       Impact factor: 9.825
  7 in total

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