| Literature DB >> 24817209 |
Ying Wang1, Mårten S G Ahlquist.
Abstract
Two possible reactive sites (the oxo site and the Ru site) for water on a high-valent ruthenium(V) oxo complex were examined. Our results suggest that the reaction on the ruthenium (via a seven coordinate intermediate) has both a lower barrier and a product with a lower free energy than the product of addition at the oxo.Entities:
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Year: 2014 PMID： 24817209 DOI： 10.1039/c4cp01183j
Source DB: PubMed Journal: Phys Chem Chem Phys ISSN： 1463-9076 Impact factor: 3.676