Literature DB >> 24816428

Selective preparation of diamondoid phosphonates.

Andrey A Fokin1, Raisa I Yurchenko, Boryslav A Tkachenko, Natalie A Fokina, Maria A Gunawan, Didier Poinsot, Jeremy E P Dahl, Robert M K Carlson, Michael Serafin, Hélène Cattey, Jean-Cyrille Hierso, Peter R Schreiner.   

Abstract

We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]tetramantane, and [1(2,3)4]pentamantane. The reactions of the corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.

Entities:  

Year:  2014        PMID： 24816428     DOI： 10.1021/jo500793m

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Experimental measurement of the diamond nucleation landscape reveals classical and nonclassical features.

Authors:  Matthew A Gebbie; Hitoshi Ishiwata; Patrick J McQuade; Vaclav Petrak; Andrew Taylor; Christopher Freiwald; Jeremy E Dahl; Robert M K Carlson; Andrey A Fokin; Peter R Schreiner; Zhi-Xun Shen; Milos Nesladek; Nicholas A Melosh
Journal:  Proc Natl Acad Sci U S A       Date:  2018-08-01       Impact factor: 11.205

2.  Opening of the Diamondoid Cage upon Ionization Probed by Infrared Spectra of the Amantadine Cation Solvated by Ar, N2 , and H2 O.

Authors:  Martin Andreas Robert George; Otto Dopfer
Journal:  Chemistry       Date:  2022-06-20       Impact factor: 5.020

3.  Synthesis and Structural Properties of Adamantane-Substituted Amines and Amides Containing an Additional Adamantane, Azaadamantane or Diamantane Moiety.

Authors:  Maxime Bonsir; Alan R Kennedy; Yves Geerts
Journal:  ChemistryOpen       Date:  2022-03-04       Impact factor: 2.630
  3 in total

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