Literature DB >> 24816302

A crystalline porous coordination polymer decorated with nitroxyl radicals catalyzes aerobic oxidation of alcohols.

Liangchun Li1, Ryotaro Matsuda, Iku Tanaka, Hiroshi Sato, Prakash Kanoo, Hyung Joon Jeon, Maw Lin Foo, Atsushi Wakamiya, Yasujiro Murata, Susumu Kitagawa.   

Abstract

A porous coordination polymer (PCP) has been synthesized employing an organic ligand in which a stable free radical, isoindoline nitroxide, is incorporated. The crystalline PCP possesses one-dimensional channels decorated with the nitroxyl catalytic sites. When O2 gas or air was used as the oxidant, this PCP was verified to be an efficient, recyclable, and widely applicable catalyst for selective oxidation of various alcohols to the corresponding aldehydes or ketones.

Entities:  

Year:  2014        PMID: 24816302     DOI: 10.1021/ja5019095

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  3 in total

1.  Solvent-vapour-assisted pathways and the role of pre-organization in solid-state transformations of coordination polymers.

Authors:  James S Wright; Iñigo J Vitórica-Yrezábal; Harry Adams; Stephen P Thompson; Adrian H Hill; Lee Brammer
Journal:  IUCrJ       Date:  2015-02-26       Impact factor: 4.769

2.  Crystal structure of bis-(μ-2-benzoyl-benzoato-κ(2) O:O')bis-[bis-(2,2'-bi-pyridine-κ(2) N,N')manganese(II)] bis-(perchlorate).

Authors:  Ibrahim Kani
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-12-16

3.  Enhancing the photo-efficacy of an organic visible-light-activated chromophore (alizarin red S) on zinc oxide with a Ag-Na electrolyte to photo-transform aromatic and aliphatic alcohols.

Authors:  Timothy M Underwood; Ross S Robinson
Journal:  RSC Adv       Date:  2019-08-05       Impact factor: 4.036

  3 in total

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