| Literature DB >> 24806829 |
Feng Luo1, Cong Bin Fan, Ming Biao Luo, Xiao Liu Wu, Yan Zhu, Shou Zhi Pu, Wen-Yuan Xu, Guo-Cong Guo.
Abstract
We demonstrate herein a promising pathway towards low-energy CO2 capture and release triggered by UV and visible light. A photosensitive diarylethene ligand was used to construct a photochromic diarylethene metal-organic framework (DMOF). A local photochromic reaction originating from the framework movement induced by the photoswitchable diarylethene unit resulted in record CO2-desorption capacity of 75% under static irradiation and 76% under dynamic irradiation.Entities:
Keywords: carbon dioxide capture/release; diarylethene ligands; metal-organic frameworks; photochromism; photoswitching
Year: 2014 PMID: 24806829 DOI: 10.1002/anie.201311124
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336