Hierarchical molecular self-assemblies: construction and advantages.

Hierarchical molecular self-assembly offers many exotic and complicated nanostructures which are of interest in nanotechnology and material science. In the past decade, various strategies leading to hierarchical molecular self-assemblies have been developed. In this review we summarize the recent advances in the creation and application of solution-based self-assembled nanostructures that involve more than one level of arrangement of building blocks. The strategies for construction hierarchical self-assembled structures and the advantages brought up by these assemblies are focused on. The following contents are included: (1) general approaches to fabricate hierarchical self-assembly, including self-assemblies based on supramolecules and specially designed block copolymers; (2) the advantages brought about by the hierarchical self-assembly, including the fabrication of special self-assembled structures, rich responsiveness to external stimuli, and the materials' performance.