Literature DB >> 24796716

The Bu4NI-catalyzed alfa-acyloxylation of ketones with benzylic alcohols.

Songjin Guo1, Jin-Tao Yu, Qiang Dai, Haitao Yang, Jiang Cheng.   

Abstract

The Bu4NI-catalyzed reaction of ketones with benzylic alcohols was achieved, leading to alfa-acyloxycarbonyl compounds in moderate to good yields. This metal-free procedure featured the employment of facilely and commercially available starting materials and TBHP as a clean oxidant with high atom economy.

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Year:  2014        PMID: 24796716     DOI: 10.1039/c4cc01652a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

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Journal:  Beilstein J Org Chem       Date:  2015-01-20       Impact factor: 2.883

2.  α-Acetoxyarone synthesis via iodine-catalyzed and tert-butyl hydroperoxide-mediateded self-intermolecular oxidative coupling of aryl ketones.

Authors:  Liquan Tan; Cui Chen; Weibing Liu
Journal:  Beilstein J Org Chem       Date:  2017-06-06       Impact factor: 2.883

3.  Synthesis of N-Heteroarenemethyl Esters via C-C Bond Cleavage of Acyl Cyanides Under Transition Metal-Free Conditions.

Authors:  Miao Lai; Fangyao Su; Jingyi Hu; Mengzhuo Wang; Mingqin Zhao; Ganlin Zhang
Journal:  Front Chem       Date:  2022-01-27       Impact factor: 5.221

Review 4.  Structural derivatization strategies of natural phenols by semi-synthesis and total-synthesis.

Authors:  Ding Lin; Senze Jiang; Ailian Zhang; Tong Wu; Yongchang Qian; Qingsong Shao
Journal:  Nat Prod Bioprospect       Date:  2022-03-07
  4 in total

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