Literature DB >> 24788367

Binary role of an ylide in formation of a terminal methylidene complex of niobium.

Keith Searles1, Karlijn Keijzer, Chun-Hsing Chen, Mu-Hyun Baik, Daniel J Mindiola.   

Abstract

The first structurally characterized niobium(v) complex possessing a terminal methylidene ligand is reported in high yield from the reaction of [(Ar'O)2Nb(CH3)2Cl] (Ar' = (2,6-CHPh2)2-4-tBu-C6H2) and two equivalents of H2CPPh3.

Entities:  

Year:  2014        PMID: 24788367     DOI: 10.1039/c4cc01404a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  [4-tert-Butyl-2,6-bis-(di-phenyl-meth-yl)phenolato-κO]dieth-yl(tetra-hydro-furan-κO)aluminium.

Authors:  Mikhail E Minyaev; Ilya E Nifant'ev; Andrei V Churakov; Andrei V Shlyahtin
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-01-26
  1 in total

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